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Chemcial Industry and Engineering 2008, Vol. 25 Issue (4) :335-339    DOI:
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Effect of K,Zr on the MoS_2/C Catalyst for the Synthesis of Ethyl Acetate from the Dehydrogenation of Ethanol
WANG Da-lin,YUAN Fa-lin,JIANG Hao-xi(1.Key Laboratory of Green Chemistry Technology,R&D Center for Petrochemical Technology,Tianjin University,Tianjin 300072,China;2.Shandong Haihua Co.Ltd.,Weifang 262737,Shandong Province,China)
(1.Key Laboratory of Green Chemistry Technology,R&D Center for Petrochemical Technology,Tianjin University,Tianjin 300072,China;2.Shandong Haihua Co.Ltd.,Weifang 262737,Shandong Province,China

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Abstract The effect of K and Zr on the performance of MoS_2/C catalyst for the synthesis of ethyl acetate from the dehydrogenation of ethanol were study by XRD,XPS and catalyst activity measurement.The results show that the addition of K restrained the dehydration of ethanol to produce the ethylene and increased the united selectivity;Zr increased the conversion of ethanol;the simultaneous addition of K and Zr increased both of conversion of ethanol and united selectivity;the addition of Zr and K-Zr considerably influence the valence of Mo in the catalyst.
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Received 2008-07-15; published 2008-07-15
Cite this article:   
WANG Da-lin,YUAN Fa-lin,JIANG Hao-xi.Effect of K,Zr on the MoS_2/C Catalyst for the Synthesis of Ethyl Acetate from the Dehydrogenation of Ethanol[J]  Chemcial Industry and Engineering, 2008,V25(4): 335-339
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