Optimization of heterogeneous Fenton treatment of organic complexes in electroplating wastewater based on response surface methodology

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Abstract In order to improve the catalytic efficiency and optimize the operating conditions of heterogeneous Fenton process for electroplating wastewater treatment, a supported fly ash heterogeneous Fenton catalyst was prepared by using phthalic acid and hydrochloric acid as the buffer solution. And the effect of factors, such as catalyst dosage, initial pH value and H₂O₂ dosage on the catalytic efficiency of organic complexes in electroplating wastewater were investigated, respectively. On the basis of single factor experiments, the Box-Behnken Design response surface methodology was used to optimize the experimental design, the optimized conditions and the interaction between multiple factors were obtained by model construction and variance analysis, and then the accuracy of the model was verified. The results show that the order of influence of various factors on the removal rate of COD_Cr in electroplating wastewater is as follows: initial pH value>catalyst dosage>H₂O₂ concentration, and the significant interaction occurred between initial pH value and H₂O₂ concentration. Moreover, the optimal reaction conditions are as follows: catalyst dosage 16.86 g·L^-1, initial pH value 3.49, H₂O₂ concentration 50.6 mmol·L^-1. Furthermore, the average actual value of COD_Cr removal rate is 94.2%, which the relative error only 0.95% compared with predicted value. Therefore, it is feasible to optimize heterogeneous Fenton degradation of organic complexes in electroplating wastewater by response surface methodology.

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	ZHAO Jin
	CHENG Yu
	JIANG Tianxiang
	CAO Junrui

Keywords： response surface method heterogeneous Fenton electroplating wastewater buffer solution fly ash organic complex

Received 2022-12-26;

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ZHAO Jin, CHENG Yu, JIANG Tianxiang, CAO Junrui.Optimization of heterogeneous Fenton treatment of organic complexes in electroplating wastewater based on response surface methodology[J] Chemcial Industry and Engineering, 2023,V40(4): 129-136

[1] 汪兴, 赵子龙, 张小山, 等. 制备条件对生物炭载铁催化剂催化破络Ni-EDTA性能及活性组分浸出的影响[J]. 化工进展, 2022, 41(9):4831-4839 WANG Xing, ZHAO Zilong, ZHANG Xiaoshan, et al. Effect of preparation conditions on catalytic performance of biocarbon supported iron catalyst for breaking Ni-EDTA and leaching of active components[J]. Chemical Industry and Engineering Progress, 2022, 41(9):4831-4839(in Chinese)
[2] 杨世迎, 薛艺超, 王满倩. 络合态重金属废水处理:基于高级氧化技术的解络合机制[J]. 化学进展, 2019, 31(8):1187-1198 YANG Shiying, XUE Yichao, WANG Manqian. Complexed heavy metal wastewater treatment:De complexation mechanisms based on advanced oxidation processes[J]. Progress in Chemistry, 2019, 31(8):1187-1198(in Chinese)
[3] QIN Q, LIU Y, LI X, et al. Enhanced heterogeneous Fenton-like degradation of methylene blue by reduced CuFe₂O₄[J]. RSC Advances, 2018, 8(2):1071-1077
[4] DU J, ZHANG B, LI J, et al. Decontamination of heavy metal complexes by advanced oxidation processes:A review[J]. Chinese Chemical Letters, 2020, 31(10):2575-2582
[5] XIN S, LIU G, MA X, et al. High efficiency heterogeneous Fenton-like catalyst biochar modified CuFeO₂ for the degradation of tetracycline:Economical synthesis, catalytic performance and mechanism[J]. Applied Catalysis B:Environmental, 2021, doi:10.1016/j.apcatb.2020.119386
[6] GAO C, CHEN S, QUAN X, et al. Enhanced Fenton-like catalysis by iron-based metal organic frameworks for degradation of organic pollutants[J]. Journal of Catalysis, 2017, 356:125-132
[7] LI R, GAO Y, JIN X, et al. Fenton-like oxidation of 2, 4-DCP in aqueous solution using iron-based nanoparticles as the heterogeneous catalyst[J]. Journal of Colloid and Interface Science, 2015, 438:87-93
[8] CHONG S, ZHANG G, ZHANG N, et al. Preparation of FeCeO_x by ultrasonic impregnation method for heterogeneous Fenton degradation of diclofenac[J]. Ultrasonics Sonochemistry, 2016, 32:231-240
[9] MEHRABADI B A T, ESKANDARI S, KHAN U, et al. A review of preparation methods for supported metal catalysts[J]. Advances in Catalysis, 2017, 61:1-35
[10] THIRUGNANASAMBANDHAM K, SIVAKUMAR V, MARAN J P. Response surface modelling and optimization of treatment of meat industry wastewater using electrochemical treatment method[J]. Journal of the Taiwan Institute of Chemical Engineers, 2015, 46:160-167
[11] 包红旭, 李良玉, 于莉嫱, 等. 响应面优化异相芬顿提高农药废水可生化性研究[J]. 大连民族大学学报, 2020, 22(3):213-219, 233 BAO Hongxu, LI Liangyu, YU Liqiang, et al. Response surface optimization of heterogeneous Fenton to improve biodegradability of pesticide wastewater[J]. Journal of Dalian Minzu University, 2020, 22(3):213-219, 233(in Chinese)
[12] ROUDI A M, SALEM S, ABEDINI M, et al. Response surface methodology (RSM)-based prediction and optimization of the Fenton process in landfill leachate decolorization[J]. Processes, 2021, 9(12):2284
[13] 郭莹, 陈鸿汉, 张焕祯, 等. 基于Box-Behnken响应曲面法优化Fenton预处理高浓度染料中间体生产废水[J]. 环境科学研究, 2017, 30(5):775-783 GUO Ying, CHEN Honghan, ZHANG Huanzhen, et al. Optimization of Fenton pre-treatment of high concentration dye intermediate wastewater based on box-behnken response surface methodology[J]. Research of Environmental Sciences, 2017, 30(5):775-783(in Chinese)
[14] DUESTERBERG C K, MYLON S E, WAITE T D. pH effects on iron-catalyzed oxidation using Fenton's reagent[J]. Environmental Science & Technology, 2008, 42(22):8522-8527
[15] KANG Y, HWANG K Y. Effects of reaction conditions on the oxidation efficiency in the Fenton process[J]. Water Research, 2000, 34(10):2786-2790
[16] DENG Y, ENGLEHARDT J D. Treatment of landfill leachate by the Fenton process[J]. Water Research, 2006, 40(20):3683-3694
[17] 邵天元, 李新宝, 张宝锋, 等. 电芬顿法处理重金属络合物Ni-EDTA的研究[J]. 环境科学学报, 2015, 35(3):745-749 SHAO Tianyuan, LI Xinbao, ZHANG Baofeng, et al. Removal of Ni-EDTA by electro-Fenton process[J]. Acta Scientiae Circumstantiae, 2015, 35(3):745-749(in Chinese)
[18] 王哲, 张思思, 黄国和, 等. 高炉水淬渣对电镀废水中重金属和COD吸附的响应面优化[J]. 化工进展, 2016, 35(11):3669-3676 WANG Zhe, ZHANG Sisi, HUANG Guohe, et al. Application of response surface methodology to optimize adsorption conditions for heavy metals and COD in electroplating waste water by water-quenched blast furnace slag[J]. Chemical Industry and Engineering Progress, 2016, 35(11):3669-3676(in Chinese)
[19] 袁菊红, 胡绵好. 响应面法优化烧烤竹炭对水中磷的吸附条件[J]. 化工环保, 2015, 35(2):116-120 YUAN Juhong, HU Mianhao. Condition optimization for adsorption of phosphate from water onto barbecue bamboo charcoal by response surface methodology[J]. Environmental Protection of Chemical Industry, 2015, 35(2):116-120(in Chinese)
[20] 许晓毅, 蔡岚, 吉芳英, 等. 超声/Fenton法处理毒死蜱中间体废水的工艺优化[J]. 环境科学研究, 2015, 28(11):1755-1763 XU Xiaoyi, CAI Lan, JI Fangying, et al. Process optimization of chlorpyrifos intermittent wastewater treatment by ultrasonic-combined Fenton reaction[J]. Research of Environmental Sciences, 2015, 28(11):1755-1763(in Chinese)
[21] MURALIDHAR R V, CHIRUMAMILA R R, MARCHANT R, et al. A response surface approach for the comparison of lipase production by Candida cylindracea using two different carbon sources[J]. Biochemical Engineering Journal, 2001, 9(1):17-23