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Chemcial Industry and Engineering 2024, Vol. 41 Issue (4) :20-27    DOI: 10.13353/j.issn.1004.9533.20220330
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Wavelength-dependent photoaging mechanism of organic thermochromic materials
LI Ruizhen1,2, ZHAO Zhen1, LOU Hongfei3, LI Wei1,2, LIU Dongzhi1,2, ZHOU Xueqin1,2
1. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300354, China;
2. Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300072, China;
3. PLA Army Academy of Artillery and Air Defense, Nanjing 210007, China

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Abstract Two three-component reversible thermochromic materials, with phenyl benzoate and 1-octadecanol as the solvent respectively, were employed to study the photoaging mechanism of electron-transfer-based organic thermochromic materials. Five light sources with different wavelengths were exerted to illuminate the thermochromic materials. UV light sources have a center wavelength of 254 nm, 302 nm, 365 nm and 395 nm respectively, and the visible light source is a xenon lamp with a wavelength range of 400—1000 nm. The aging progress together with the phenomenon of thermochromic materials were showed and the 1H NMR spectra of each irradiated-component were analyzed to investigate their changes by the irradiation of different light sources. The retention content of each component was evaluated to discover the different changes of thermochromic materials with the various wavelength of light sources. Our results suggest that UV-light-induced photoaging of thermochromic materials is mainly caused by the photodegradation of components, and visible-light-induced photoaging of thermochromic materials is primarily due to the loss of solvent component. As the wavelength of UV lights reduces, the photodegradation rate of phenyl benzoate and thermosensitive green dye increases, resulting in the accelerated photoaging rate of corresponding thermochromic materials; whereas the negligible degradation effect of 1-octadecanol by UV lights leads to little degradation of corresponding thermochromic material. Under the visible light, the fact that the loss of phenyl benzoate is much greater than that of 1-octadecanol shows the faster photoaging of phenyl benzoate-based thermochromic material in comparison with 1-octadecanol-based thermochromic material. In conclusion, a wavelength-dependent photoaging mechanism has been discovered for three-components thermochromic materials and this sheds a new light on the anti-photoaging strategy of organic reversible thermochromic materials.
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LI Ruizhen
ZHAO Zhen
LOU Hongfei
LI Wei
LIU Dongzhi
ZHOU Xueqin
Keywordsorganic reversible thermochromic materials   photoaging   photodegradation   aging-rate   mechanism     
Received 2022-04-29;
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LI Ruizhen, ZHAO Zhen, LOU Hongfei, LI Wei, LIU Dongzhi, ZHOU Xueqin.Wavelength-dependent photoaging mechanism of organic thermochromic materials[J]  Chemcial Industry and Engineering, 2024,V41(4): 20-27
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