水系锌离子电池有机正极材料的最新进展

摘要绿色可持续发展扩大了社会对储能系统的需求,特别是可充电电池系统。与其他电池系统相比,水系锌离子电池(AZIBs)以其固有的安全性、低成本等特点得到了人们的广泛关注。然而,以过渡金属元素为基础的传统正极材料也已经不能满足其绿色发展的需求。有机化合物因其资源可再生性、环境友好性和结构多样性已成为锌离子电池正极材料的研究热点。综述了具有不同储锌机理的有机正极材料的最新研究进展,包括导电聚合物、羰基化合物、亚胺化合物、氮氧自由基化合物、COFs/MOFs材料和三苯胺衍生物等材料,并且对有机正极材料的未来发展前景做了进一步的展望。

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	刘吉源
	马叙
	王云锋
	苟林
	徐强

关键词：水系电解液锌离子电池正极材料有机化合物研究进展

Abstract： The green sustainability has expanded the demand of energy storage systems in society, especially rechargeable battery systems. Compared with other batteries systems, aqueous zinc ion batteries (AZIBs) have gained widespread attention for their inherent safety and low cost. However, traditional cathode materials based on transition metal elements have also failed to meet the needs of the green development. Organic compounds have become a research hotspot for zinc-ion batteries cathode materials due to their resource renewability, environmental friendliness and structural diversity. This paper reviews the latest research progress of organic cathode materials with different zinc storage mechanisms, including conducting polymers, carbonyl compounds, imine compounds, nitrogen oxide radical compounds, COFs/MOFs materials and triphenylamine derivatives, and provides further prospects for the future development of organic cathode materials.

Keywords： aqueous electrolyte zinc-ion battery cathode material organic compound research progress

Received 2021-11-03;

Fund:国家自然科学基金项目(21975180)。

Corresponding Authors: 徐强,副教授,E-mail:xuqiang@tju.edu.cn。 Email: xuqiang@tju.edu.cn

About author: 刘吉源(1997-),男,硕士研究生,现从事水系锌离子电池的研究。

引用本文:

刘吉源, 马叙, 王云锋, 苟林, 徐强.水系锌离子电池有机正极材料的最新进展[J]. 化学工业与工程, 2023,40(5): 105-116

LIU Jiyuan, MA Xu, WANG Yunfeng, GOU Lin, XU Qiang.Recent advances of organic cathode materials for aqueous zinc-ion batteries[J]. Chemcial Industry and Engineering, 2023,40(5): 105-116

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