基于低共熔溶剂离子凝胶在储能方面的研究进展

摘要随着能源危机和环境污染问题的日益突显,人们对绿色、高效的储能器件的需求越来越迫切。在储能器件中选用环保安全、易于合成的绿色材料十分关键。低共熔溶剂(Deep eutectic solvent, DES)因其不易燃、不易挥发、成本低廉和可生物降解,常被用做离子凝胶的塑化剂。基于低共熔溶剂的离子凝胶由低共熔溶剂和凝胶剂(线性聚合物、聚合物网络和超分子网络等)2部分组成。其制备简单,具有的物化性能符合绿色化学的需求;另外兼有低共熔溶剂和凝胶剂的特性,可具有不同的功能(离子导电性、pH值相应性和自愈合性能等)。最后总结了基于低共熔溶剂离子凝胶在储能方面的实际应用,并对其未来发展前景进行了展望。

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	李琪琪
	李杨
	胡德计
	刘兴江
	徐强

关键词：低共熔溶剂离子凝胶储能器件

Abstract： As the energy crisis and environmental pollution problems become increasingly prominent,the demand for green and efficient energy storage devices is becoming urgent. Therefore, it is very important to select green materials which are environmentally friendliness, safe and easy to synthesize in energy storage devices. Deep eutectic solvents (DESs) are often used as plasticizers in ionic gels because of non-flammablity, non-volatility, low-cost and biodegradability. Ionic gels based on DESs are composed of DESs and gelators (linear polymers, polymer networks, supramolecular networks, etc.). They are simple to prepare, have excellent physical and chemical properties, and meet the demands of green chemistry. What is more, they take advantage of DESs and gelators, have different functions (ionic conductivity, pH-responsiveness, self-healing performance, etc.). Finally, the practical applications of deep-eutectic-solvent-based ionic gels in energy storage are summarized, and their development in the future is prospected.

Keywords： deep eutectic solvents ionic gels energy storage devices

Received 2021-10-24;

Fund:国家自然科学基金项目(21975180)。

Corresponding Authors: 徐强,副教授,E-mail:xuqiang@tju.edu.cn。 Email: xuqiang@tju.edu.cn

About author: 李琪琪(1997-),男,硕士研究生,现从事凝胶电解质方面的研究。

引用本文:

李琪琪, 李杨, 胡德计, 刘兴江, 徐强.基于低共熔溶剂离子凝胶在储能方面的研究进展[J]. 化学工业与工程, 2023,40(5): 94-104

LI Qiqi, LI Yang, HU Deji, LIU Xingjiang, XU Qiang.Research progress on deep-eutectic-solvent-based ionic gels for energy storage[J]. Chemcial Industry and Engineering, 2023,40(5): 94-104

[1] BLOMGREN G E. The development and future of lithium ion batteries[J]. Journal of the Electrochemical Society, 2016, 164(1):A5019-A5025
[2] MANTHIRAM A, YU X, WANG S. Lithium battery chemistries enabled by solid-state electrolytes[J]. Nature Reviews Materials, 2017, 2(4):1-16
[3] LI M, WANG C, CHEN Z, et al. New concepts in electrolytes[J]. Chemical Reviews, 2020, 120(14):6783-6819
[4] LIN D, LIU Y, CUI Y. Reviving the lithium metal anode for high-energy batteries[J]. Nature Nanotechnology, 2017, 12(3):194-206
[5] FORSYTH M, PORCARELLI L, WANG X, et al. Innovative electrolytes based on ionic liquids and polymers for next-generation solid-state batteries[J]. Accounts of Chemical Research, 2019, 52(3):686-694
[6] ISIK M, LONJARET T, SARDON H, et al. Cholinium-based ion gels as solid electrolytes for long-term cutaneous electrophysiology[J]. Journal of Materials Chemistry C, 2015, 3(34):8942-8948
[7] TOMÉ L C, MARRUCHO I M. Ionic liquid-based materials:A platform to design engineered CO₂ separation membranes[J]. Chemical Society Reviews, 2016, 45(10):2785-2824
[8] 岳旭东, 袁冰, 朱国强, 等. 低共熔溶剂在有机合成和萃取分离中的应用进展[J]. 化工进展, 2018, 37(7):2627-2634 YUE Xudong, YUAN Bing, ZHU Guoqiang, et al. Development in the applications of deep eutectic solvents in organic synthesis and extraction separation[J]. Chemical Industry and Engineering Progress, 2018, 37(7):2627-2634(in Chinese)
[9] BIRIA S, PATHREEKER S, GENIER F S, et al. A highly conductive and thermally stable ionic liquid gel electrolyte for calcium-ion batteries[J]. ACS Applied Polymer Materials, 2020, 2(6):2111-2118
[10] CARASEK E, BERNARDI G, MORELLI D, et al. Sustainable green solvents for microextraction techniques:Recent developments and applications[J]. Journal of Chromatography A, 2021, doi:10.1016/j.chroma.2021.461944
[11] YANG T, ZHAO L, WANG J, et al. Improving whole-cell biocatalysis by addition of deep eutectic solvents and natural deep eutectic solvents[J]. ACS Sustainable Chemistry & Engineering, 2017, 5(7):5713-5722
[12] HANSEN B B, SPITTLE S, CHEN B, et al. Deep eutectic solvents:A review of fundamentals and applications[J]. Chemical Reviews, 2021, 121(3):1232-1285
[13] LOMBA L, RIBATE M P, SANGÜESA E, et al. Deep eutectic solvents:Are they safe?[J]. Applied Sciences, 2021, doi:10.3390/app112110061
[14] ABBOTT A P, BOOTHBY D, CAPPER G, et al. Deep eutectic solvents formed between choline chloride and carboxylic acids:Versatile alternatives to ionic liquids[J]. Journal of the American Chemical Society, 2004, 126(29):9142-9147
[15] HALLETT J E, HAYLER H J, PERKIN S. Nanolubrication in deep eutectic solvents[J]. Physical Chemistry Chemical Physics:PCCP, 2020, 22(36):20253-20264
[16] CICCO L, DILAURO G, PERNA F M, et al. Advances in deep eutectic solvents and water:Applications in metal- and biocatalyzed processes, in the synthesis of APIs, and other biologically active compounds[J]. Organic & Biomolecular Chemistry, 2021, 19(12):2558-2577
[17] QIN H, HU X, WANG J, et al. Overview of acidic deep eutectic solvents on synthesis, properties and applications[J]. Green Energy & Environment, 2020, 5(1):8-21
[18] MUKHERJEE P. Green chemistry-a novel approach towards sustainability[J]. Journal of the Chilean Chemical Society, 2021, 66(1):5075-5080
[19] MOTA-MORALES J D, SÁNCHEZ-LEIJA R J, CARRANZA A, et al. Free-radical polymerizations of and in deep eutectic solvents:Green synthesis of functional materials[J]. Progress in Polymer Science, 2018, 78:139-153
[20] SÁNCHEZ-LEIJA R J, LÓPEZ-SALAS N, FIERRO J L G, et al. Deep eutectic solvents as active media for the preparation of highly conducting 3D free-standing PANI xerogels and their derived N-doped and N-, P-codoped porous carbons[J]. Carbon, 2019, 146:813-826
[21] TOMÉ L C, MECERREYES D. Emerging ionic soft materials based on deep eutectic solvents[J]. The Journal of Physical Chemistry B, 2020, 124(39):8465-8478
[22] ISIK M, RUIPEREZ F, SARDON H, et al. Innovative poly(ionic liquid)s by the polymerization of deep eutectic monomers[J]. Macromolecular Rapid Communications, 2016, 37(14):1135-1142
[23] WANG Y, CHEN W, ZHAO Q, et al. Ionicity of deep eutectic solvents by Walden plot and pulsed field gradient nuclear magnetic resonance (PFG-NMR)[J]. Physical Chemistry Chemical Physics:PCCP, 2020, 22(44):25760-25768
[24] HONG S, YUAN Y, LIU C, et al. A stretchable and compressible ion gel based on a deep eutectic solvent applied as a strain sensor and electrolyte for supercapacitors[J]. Journal of Materials Chemistry C, 2020, 8(2):550-560
[25] MUKESH C, GUPTA R, SRIVASTAVA D N, et al. Preparation of a natural deep eutectic solvent mediated self polymerized highly flexible transparent gel having super capacitive behaviour[J]. RSC Advances, 2016, 6(34):28586-28592
[26] JOOS B, VRANKEN T, MARCHAL W, et al. Eutectogels:A new class of solid composite electrolytes for Li/Li-ion batteries[J]. Chemistry of Materials, 2018, 30(3):655-662
[27] QIN H, OWYEUNG R E, SONKUSALE S R, et al. Highly stretchable and nonvolatile gelatin-supported deep eutectic solvent gel electrolyte-based ionic skins for strain and pressure sensing[J]. Journal of Materials Chemistry C, 2019, 7(3):601-608
[28] ZHANG L, JIANG D, DONG T, et al. Overview of ionogels in flexible electronics[J]. Chemical Record (New York, N Y), 2020, 20(9):948-967
[29] IQBAL S M A, MAHGOUB I, DU E, et al. Advances in healthcare wearable devices[J]. Npj Flexible Electronics, 2021, 5(1):1-14
[30] JOOS B, VOLDERS J, DA CRUZ R R, et al. Polymeric backbone eutectogels as a new generation of hybrid solid-state electrolytes[J]. Chemistry of Materials, 2020, 32(9):3783-3793
[31] LOGAN M W, LANGEVIN S, TAN B, et al. UV-cured eutectic gel polymer electrolytes for safe and robust Li-ion batteries[J]. Journal of Materials Chemistry A, 2020, 8(17):8485-8495
[32] JAUMAUX P, LIU Q, ZHOU D, et al. Deep-eutectic-solvent-based self-healing polymer electrolyte for safe and long-life lithium-metal batteries[J]. Angewandte Chemie (International Ed in English), 2020, 59(23):9134-9142
[33] ZHU Q, ZHAO D, CHENG M, et al. A new view of supercapacitors:Integrated supercapacitors[J]. Advanced Energy Materials, 2019, doi:10.1002/aenm.201901081
[34] QIN H, PANZER M J. Chemically cross-linked poly(2-hydroxyethyl methacrylate)-supported deep eutectic solvent gel electrolytes for eco-friendly supercapacitors[J]. ChemElectroChem, 2017, 4(10):2556-2562
[35] BU X, GE Y, WANG L, et al. Design of highly stretchable deep eutectic solvent-based ionic gel electrolyte with high ionic conductivity by the addition of zwitterion ion dissociators for flexible supercapacitor[J]. Polymer Engineering & Science, 2021, 61(1):154-166
[36] VOROBIOV V K, SMIRNOV M A, BOBROVA N V, et al. Chitosan-supported deep eutectic solvent as bio-based electrolyte for flexible supercapacitor[J]. Materials Letters, 2021, doi:10.1016/j.matlet.2020.128889
[37] HONG S, YUAN Y, LI P, et al. Enhancement of the nanofibrillation of birch cellulose pretreated with natural deep eutectic solvent[J]. Industrial Crops and Products, 2020, doi:10.1016/j.indcrop.2020.112677
[38] KAVAN L. Electrochemistry and dye-sensitized solar cells[J]. Current Opinion in Electrochemistry, 2017, 2(1):88-96
[39] YANG Y, ZHANG Z, GAO J, et al. Deep eutectic solvent based polymer electrolyte for dye-sensitized solar cells[J]. Journal of Inorganic Materials, 2017, doi:10.15541/jim20160184
[40] HEYDARI D M, MOHAMMADPOUR F, ZOLGHADR A R. Dye-sensitized solar cells based on deep eutectic solvent electrolytes:Insights from experiment and simulation[J]. The Journal of Physical Chemistry C, 2021, 125(28):15155-15165
[41] CAI G, WANG J, LEE P S. Next-generation multifunctional electrochromic devices[J]. Accounts of Chemical Research, 2016, 49(8):1469-1476
[42] WANG K, WANG H, LI J, et al. Super-stretchable and extreme temperature-tolerant supramolecular-polymer double-network eutectogels with ultrafast in situ adhesion and flexible electrochromic behaviour[J]. Materials Horizons, 2021, 8(9):2520-2532
[43] RONG K, ZHANG H, ZHANG H, et al. Deep eutectic solvent with Prussian blue and tungsten oxide for green and low-cost electrochromic devices[J]. ACS Applied Electronic Materials, 2019, 1(6):1038-1045
[44] DA SILVA W, BRETT C M A. Novel biosensor for acetylcholine based on acetylcholinesterase/poly(neutral red)-Deep eutectic solvent/Fe₂O₃ nanoparticle modified electrode[J]. Journal of Electroanalytical Chemistry, 2020, doi:10.1016/j.jelechem.2020.114050
[45] DA SILVA W, GHICA M E, BRETT C M A. Choline oxidase inhibition biosensor based on poly(brilliant cresyl blue)-deep eutectic solvent/carbon nanotube modified electrode for dichlorvos organophosphorus pesticide[J]. Sensors and Actuators B:Chemical, 2019, doi:10.1016/j.snb.2019.126862
[46] YANG D, ZHANG S, JIANG D. Efficient absorption of SO₂ by deep eutectic solvents formed by biobased aprotic organic compound succinonitrile and 1-ethyl-3-methylimidazolium chloride[J]. ACS Sustainable Chemistry & Engineering, 2019, 7(10):9086-9091
[47] ZHANG Y, YU T, PENG L, et al. Advancements in hydrogel-based drug sustained release systems for bone tissue engineering[J]. Frontiers in Pharmacology, 2020, doi:10.3389/fphar.2020.00622
[48] PRASAD K, MONDAL D, SHARMA M, et al. Stimuli responsive ion gels based on polysaccharides and other polymers prepared using ionic liquids and deep eutectic solvents[J]. Carbohydrate Polymers, 2018, 180:328-336
[49] BALL P. Extreme gels[J]. Nature Materials, 2018, doi:10.1038/s41563-018-0163-9
[50] LEMAOUI T, BENGUERBA Y, DARWISH A S, et al. Simultaneous dearomatization, desulfurization, and denitrogenation of diesel fuels using acidic deep eutectic solvents as extractive agents:A parametric study[J]. Separation and Purification Technology, 2021, doi:10.1016/j.seppur.2020.117861
[51] LI R, ZHANG K, CHEN G, et al. Green polymerizable deep eutectic solvent (PDES) type conductive paper for origami 3D circuits[J]. Chemical Communications (Cambridge, England), 2018, 54(18):2304-2307
[52] ADAMS D J. Scrolling for gels[J]. Chem, 2017, 3(4):529-531
[53] CUNHA S C, FERNANDES J O. Extraction techniques with deep eutectic solvents[J]. TrAC Trends in Analytical Chemistry, 2018, 105:225-239
[54] CAI T, QIU H. Application of deep eutectic solvents in chromatography:A review[J]. TrAC Trends in Analytical Chemistry, 2019, doi:10.1016/j.trac.2019.115623
[55] VELEZ C, ACEVEDO O. Simulation of deep eutectic solvents:Progress to promises[J]. WIREs Computational Molecular Science, 2022, doi:10.1002/wcms.1598
[56] TOMÉ L I N, BAIÃO V, DA SILVA W, et al. Deep eutectic solvents for the production and application of new materials[J]. Applied Materials Today, 2018, 10:30-50