Synthesis and Crystal Structure of a One-Dimensional Complex of Ag(bbte)BF

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Abstract A one-dimensional silver(I) complex,Ag(bbte)BF_4,has been formed from AgBF_4 and 1,2-bis(n-butylsulfanyl)ethane(bbte,C_(10)H_(22)S_2).The complex was characterized by elemental analysis and IR spectroscopy.The X-ray structure of Ag(bbte)BF_4 is a chain coordinative polymer involving trigonal [(��_2-S)_2,S] ligation with one S-donor bridging two adjacent Ag(I) centers while the other S-donor of the bbte ligand is non-bridging.The crystal belongs to monoclinic crystal system and P2(1)/c space group.Crystallographic data:a=0.932(1) nm,b=0.799(1) nm,c=2.181(1) nm,��=97.671(9)��,V=(1.610 8)(14) nm~3,Z=4,(d_c=)1.654 Mg/m~3,��=1.531 mm~(-1),F_((000))=808,R_1=(0.069 1),wR_2=(0.137 8).

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Received 2006-03-15; published 2006-03-15

Cite this article:

CHEN Wei~1,XIE Chuang~1,SONG Hai-bin~2,WANG Jing-kang~1.Synthesis and Crystal Structure of a One-Dimensional Complex of Ag(bbte)BF_4[J] Chemcial Industry and Engineering, 2006,V23(2): 126-129

[1]	LEHN J M.Supramolecular Chemistry,Concepts andPerspectives[M].VCH,Weinheim,1995.
[2]	KHLOBYSTOV A N,BLAKE A J,CHAMPNESS N R,etal.Supramolecular design of one-dimensional coordinationpolymers based on silver(I)complexes of aromatic nitrogen-donor ligands[J].Coord Chem Rev.2001,222:155-192
[3]	COTTON F A,WILKINSON G.Advanced inorganicchemistry(3th ed)[M].John Wiley&Sons,Inc,1972.
[4]	BLAKE A J,BROOKS N R,CHAMPNESS N R,et al.Thioether ligands as molecular rods in silver(I)coordinationnetworks:1,4-dithiane as an analogue of pyrazine[J].CrystEng Comm,2000,2:41-45.
[5]	SHAO P X,YAO X K,WANG H G,et al.The research onthe structure and extraction of silver(I)nitrate complex with1,2-bis(phenylthio)ethane[J].Acta Chim Sinica,1991,49:677-681.
[6]	CHEN W,WANG J K,LI X N,et al.cis-[1,3-bis(butylsulfanyl)propane-��2S,S��]dichloropalladium(II):meso-and rac-forms in the same crystal structure[J].ActaCryst,2004,E60:m1 656-m1 658.
[7]	SHELDRICK G M.SHELXS97 and SHELXL97[M].Germany:University of G ttingen,1997.
[8]	BRUKER.SMART,SAINT and SHELXTL[CP].USA:BRUKER AXS,Madison,Wisconsin,1998.
[9]	BLAKE J R,CHAMPNESS N R,LEVASON W,et al.Unique structure features in silver(I)dithioether complex[J].J Chem Soc Chem Commun,1995:1 277-1 278.