Waste adsorbent derived cobalt modified carbon material for bisphenol A degradation by activating peroxymonosulfate

Guide

Abstract Firstly, a carboxymethyl chitosan aerogel (CMCS) adsorbent is synthesized and applied to purify cobalt ion wastewater. Then, the waste adsorbent after adsorption of cobalt ions is modified and calcined to synthesize the nitrogen-doped carbon material loaded with cobalt nanoparticles (Co@NC-800), which is applied to activate peroxymonosulfate (PMS) to degrade bisphenol A (BPA). Combined with kinetic analysis and a variety of characterization methods, it is proved that Co nanoparticles are the main active sites. By regulating the calcination temperature, it is found that graphite nitrogen is beneficial to improve the synergistic effect of Co nanoparticles and carbon substrate, thus promoting the activation of PMS. Radical quenching experiments and electrochemical analysis confirm that sulfate radical (SO^·-₄) and hydroxyl radical (·OH) are the main functional active species in the Co@NC-800/PMS system. This study provides a new approach for the efficient utilization of wastewater solid waste to prepare catalyst materials.

	Service

	Email this article
	Add to my bookshelf
	Add to citation manager
	Email Alert
	RSS
	Articles by authors
	GUO Xu
	ZHANG Qicheng
	HE Hongwei
	ZHANG Fengbao
	FAN Xiaobin
	LI Yang

Keywords： cobalt nanoparticles peroxymonosulfate graphite nitrogen sulfate radical(SO^· -₄) hydroxyl radical(· OH)

Received 2023-04-03;

Fund:

About author:

Cite this article:

GUO Xu, ZHANG Qicheng, HE Hongwei, ZHANG Fengbao, FAN Xiaobin, LI Yang.Waste adsorbent derived cobalt modified carbon material for bisphenol A degradation by activating peroxymonosulfate[J] Chemcial Industry and Engineering, 2023,V40(6): 1-14

[1] LUO H, ZENG Y, HE D, et al. Application of iron-based materials in heterogeneous advanced oxidation processes for wastewater treatment: A review[J]. Chemical Engineering Journal, 2021, 407: 127191
[2] ROSTAM A B, TAGHIZADEH M. Advanced oxidation processes integrated by membrane reactors and bioreactors for various wastewater treatments: A critical review[J]. Journal of Environmental Chemical Engineering, 2020, 8(6): 104566
[3] WAN N W S, TEONG L C, HANAFIAH M A K M. Adsorption of dyes and heavy metal ions by chitosan composites: A review[J]. Carbohydrate Polymers, 2011, 83(4): 1446-1456
[4] 左鸣. 电镀废水处理工艺优化研究[D]. 广州: 华南理工大学, 2012 ZUO Ming. Study on optimization of electroplating wastewater treatment process[D]. Guangzhou: South China University of Technology, 2012 (in Chinese)
[5] 胡必清, 朱亚伟. 印染废水的化学法处理研究进展[J]. 印染, 2016, 42(13): 46-50 HU Biqing, ZHU Yawei. Research progress in chemical treatment of printing and dyeing wastewater[J]. China Dyeing & Finishing, 2016, 42(13): 46-50(in Chinese)
[6] 梁波, 徐金球, 关杰, 等. 生物法处理印染废水的研究进展[J]. 化工环保, 2015, 35(3): 259-266 LIANG Bo, XU Jinqiu, GUAN Jie, et al. Research progresses in treatment of dyeing wastewater by biological methods[J]. Environmental Protection of Chemical Industry, 2015, 35(3): 259-266(in Chinese)
[7] 吴建明. 壳聚糖/聚乙烯醇基纳米复合材料的制备及其在污水处理中的应用[D]. 合肥: 合肥工业大学, 2019 WU Jianming. Preparation of chitosan/PVA nanocomposites and its application in wastewater treatment[D]. Hefei: Hefei University of Technology, 2019 (in Chinese)
[8] 罗文强. 羧甲基壳聚糖吸附剂对钴离子的吸附特性研究[D]. 上海: 华东理工大学, 2018 LUO Wenqiang. Study on adsorption characteristics of carboxymethyl chitosan adsorbent for cobalt ions[D]. Shanghai: East China University of Science and Technology, 2018 (in Chinese)
[9] 王祥名, 吴松海, 王琮, 等. Cu₂(NO₃)(OH)₃催化过硫酸盐降解苯酚[J]. 化学工业与工程, 2021, 38(1): 69-78 WANG Xiangming, WU Songhai, WANG Cong, et al. Catalytic degradation of phenol by persulfate activation using Cu₂(NO₃)(OH)₃[J]. Chemical Industry and Engineering, 2021, 38(1): 69-78(in Chinese)
[10] QI Y, LI J, ZHANG Y, et al. Novel lignin-based single atom catalysts as peroxymonosulfate activator for pollutants degradation: Role of single cobalt and electron transfer pathway[J]. Applied Catalysis B: Environmental, 2021, 286: 119910
[11] WANG F, YAO J, SUN K, et al. Adsorption of dialkyl phthalate esters on carbon nanotubes[J]. Environmental Science & Technology, 2010, 44(18): 6985-6991
[12] LODERER C, WÖRLE A, FUCHS W. Influence of different mesh filter module configurations on effluent quality and long-term filtration performance[J]. Environmental Science & Technology, 2012, 46(7): 3844-3850
[13] ZANG T, WANG H, LIU Y, et al. Fe-doped biochar derived from waste sludge for degradation of rhodamine B via enhancing activation of peroxymonosulfate[J]. Chemosphere, 2020, 261: 127616
[14] DUAN X, SU C, MIAO J, et al. Insights into perovskite-catalyzed peroxymonosulfate activation: Maneuverable cobalt sites for promoted evolution of sulfate radicals[J]. Applied Catalysis B: Environmental, 2018, 220: 626-634
[15] 张未军, 齐崴, 苏荣欣, 等. 电芬顿-臭氧一体化工艺处理船舶生活污水[J]. 化学工业与工程, 2017, 34(2): 62-67 ZHANG Weijun, QI Wei, SU Rongxin, et al. Removal of COD from sewage by integrated E-Fenton and ozone[J]. Chemical Industry and Engineering, 2017, 34(2): 62-67(in Chinese)
[16] HODGES B C, CATES E L, KIM J H. Challenges and prospects of advanced oxidation water treatment processes using catalytic nanomaterials[J]. Nature Nanotechnology, 2018, 13(8): 642-650
[17] ZHOU Y, WANG X, ZHU C, et al. New insight into the mechanism of peroxymonosulfate activation by sulfur-containing minerals: Role of sulfur conversion in sulfate radical generation[J]. Water Research, 2018, 142: 208-216
[18] AL HAKIM S, JABER S, ZEIN EDDINE N, et al. Degradation of theophylline in a UV₂₅₄/PS system: Matrix effect and application to a factory effluent[J]. Chemical Engineering Journal, 2020, 380: 122478
[19] WEAVERS L K. Kinetics and mechanism of ultrasonic activation of persulfate: An in situ EPR spin trapping study[J]. Environmental Science & Technology, 2017, 51(6): 3410-3417
[20] REN Y, LIN L, MA J, et al. Sulfate radicals induced from peroxymonosulfate by magnetic ferrospinel MFe₂O₄ (M=Co, Cu, Mn, and Zn) as heterogeneous catalysts in the water[J]. Applied Catalysis B: Environmental, 2015, 165: 572-578
[21] ANIPSITAKIS G P, DIONYSIOU D D. Radical generation by the interaction of transition metals with common oxidants[J]. Environmental Science & Technology, 2004, 38(13): 3705-3712
[22] ZHANG A, HE Y, CHEN Y, et al. Degradation of organic pollutants by Co₃O₄-mediated peroxymonosulfate oxidation: Roles of high-energy{0 0 1}-exposed TiO₂ support[J]. Chemical Engineering Journal, 2018, 334: 1430-1439
[23] 周丽. 钴基高级氧化法催化降解有机污染物的研究[D]. 北京: 北京化工大学, 2022 ZHOU Li. Study on catalytic degradation of organic pollutants by cobalt-based advanced oxidation[D]. Beijing: Beijing University of Chemical Technology, 2022 (in Chinese)
[24] 曹志钦. 城市典型废弃物回收及在电芬顿处理废水中的再利用研究[D]. 天津: 天津大学, 2018 CAO Zhiqin. Study on recovery of typical municipal wastes and reuse in electro-Fenton treatment of wastewater[D]. Tianjin: Tianjin University, 2018 (in Chinese)
[25] YAO Y, ZHU M, ZHAO Z, et al. Hydrometallurgical processes for recycling spent lithium-ion batteries: A critical review[J]. ACS Sustainable Chemistry & Engineering, 2018, 6(11): 13611-13627
[26] FAN L, LUO C, LV Z, et al. Removal of Ag⁺ from water environment using a novel magnetic thiourea-chitosan imprinted Ag⁺[J]. Journal of Hazardous Materials, 2011, 194: 193-201
[27] 李姗姗. 纤维素(CMC)基重金属吸附材料制备与性能研究[D]. 辽宁大连: 大连工业大学, 2021 LI Shanshan. Preparation and properties of cellulose (CMC)-based heavy metal adsorption materials[D]. Liaoning Dalian: Dalian Polytechnic University, 2021 (in Chinese)
[28] SHEKHAWAT A, KAHU S, SARAVANAN D, et al. Tin(Ⅳ) cross-linked chitosan for the removal of As(Ⅲ)[J]. Carbohydrate Polymers, 2017, 172: 205-212
[29] PIVARČIOVÁ L, ROSSKOPFOVÁ O, GALAMBOŠ M, et al. Sorption of pertechnetate anions on chitosan[J]. Journal of Radioanalytical and Nuclear Chemistry, 2016, 308(1): 93-98
[30] HE H, LI Z, LI K, et al. Bifunctional graphene-based metal-free catalysts for oxidative coupling of amines[J]. ACS Applied Materials & Interfaces, 2019, 11(35): 31844-31850
[31] HE H, MA K, LIU H, et al. Unraveling the amine oxidative coupling activity of hierarchical porous Fe-N₄-O₁ single-atom catalysts: Oxygen atom-mediated dual reaction pathway[J]. Journal of Materials Chemistry A, 2022, 10(46): 24831-24838
[32] CHANG J, WANG G, CHANG X, et al. Interface synergism and engineering of Pd/Co@N-C for direct ethanol fuel cells[J]. Nature Communications, 2023, 14(1): 1-15
[33] TIAN W, ZHANG H, QIAN Z, et al. Bread-making synthesis of hierarchically Co@C nanoarchitecture in heteroatom doped porous carbons for oxidative degradation of emerging contaminants[J]. Applied Catalysis B: Environmental, 2018, 225: 76-83
[34] ZHANG S, WANG L, XIE T, et al. Heterointerface enhanced NiFe LDH/V-Co₄N electrocatalysts for the oxygen evolution reaction[J]. Journal of Materials Chemistry A, 2022, 10(40): 21523-21530
[35] LIU X, YU H, JI J, et al. Graphene oxide-supported three-dimensional cobalt-nickel bimetallic sponge-mediated peroxymonosulfate activation for phenol degradation[J]. ACS ES&T Engineering, 2021, 1(12): 1705-1714
[36] CAI A, HE H, ZHANG Q, et al. Synergistic effect of N-doped sp² carbon and porous structure in graphene gels toward selective oxidation of C—H bond[J]. ACS Applied Materials & Interfaces, 2021, 13(11): 13087-13096
[37] DU N, LIU Y, LI Q, et al. Peroxydisulfate activation by atomically-dispersed Fe-N_<i>x on N-doped carbon: Mechanism of singlet oxygen evolution for nonradical degradation of aqueous contaminants[J]. Chemical Engineering Journal, 2021, 413: 127545
[38] 王清, 张凤宝, 范晓彬, 等. 氮掺杂中空多孔碳材料活化过一硫酸盐催化降解双酚A[J]. 化学工业与工程, 2022, 39(6): 1-13 WANG Qing, ZHANG Fengbao, FAN Xiaobin, et al. Activation of peroxymonosulfate for bisphenol A degradation by nitrogen-doped hollow porous carbon materials[J]. Chemical Industry and Engineering, 2022, 39(6): 1-13(in Chinese)
[39] ZHAO C, MENG L, CHU H, et al. Ultrafast degradation of emerging organic pollutants via activation of peroxymonosulfate over Fe₃C/Fe@N-C-x: Singlet oxygen evolution and electron-transfer mechanisms[J]. Applied Catalysis B: Environmental, 2023, 321: 122034
[40] WANG Q, LIU X, CAI A, et al. Atomically Fe doped hollow mesoporous carbon spheres for peroxymonosulfate mediated advanced oxidation processes with a dual activation pathway[J]. Journal of Materials Chemistry A, 2022, 10(38): 20535-20544
[41] DUAN X, SU C, ZHOU L, et al. Surface controlled generation of reactive radicals from persulfate by carbocatalysis on nanodiamonds[J]. Applied Catalysis B: Environmental, 2016, 194: 7-15
[42] YANG J, LIN Y, PENG H, et al. Novel magnetic rod-like Mn-Fe oxycarbide toward peroxymonosulfate activation for efficient oxidation of butyl paraben: Radical oxidation versus singlet oxygenation[J]. Applied Catalysis B: Environmental, 2020, 268: 118549
[43] LI H, SHAN C, PAN B. Fe(Ⅲ)-doped g-C₃N₄ mediated peroxymonosulfate activation for selective degradation of phenolic compounds via high-valent iron-oxo species[J]. Environmental Science & Technology, 2018, 52(4): 2197-2205
[44] WANG J, WANG S. Effect of inorganic anions on the performance of advanced oxidation processes for degradation of organic contaminants[J]. Chemical Engineering Journal, 2021, 411: 128392
[45] ZHAO Y, HUANG B, JIANG J, et al. Polyphenol-metal network derived nanocomposite to catalyze peroxymonosulfate decomposition for dye degradation [J]. Chemosphere, 2020, 244: 125577
[46] REN W, NIE G, ZHOU P, et al. The intrinsic nature of persulfate activation and N-doping in carbocatalysis[J]. Environmental Science & Technology, 2020, 54(10): 6438-6447
[47] ZHOU Y, JIANG J, GAO Y, et al. Activation of peroxymonosulfate by benzoquinone: A novel nonradical oxidation process[J]. Environmental Science & Technology, 2015, 49(21): 12941-12950
[48] LI B, MA B, WEI M, et al. Synthesis of Co-NC catalysts from spent lithium-ion batteries for Fenton-like reaction: Generation of singlet oxygen with ~100% selectivity[J]. Carbon, 2022, 197: 76-86
[49] LIU X, WANG J, WU D, et al. N-doped carbon dots decorated 3D g-C₃N₄ for visible-light driven peroxydisulfate activation: Insights of non-radical route induced by Na⁺ doping[J]. Applied Catalysis B: Environmental, 2022, 310: 121304