Effect of B Elements on the Catalytic Combustion of Methane for Ce0.8Mg0.2BO3

化学工业与工程

Chemcial Industry and Engineering

2019, Vol. 36

Issue (2) :15-20 DOI: 10.13353/j.issn.1004.9533.20181032

Current Issue | Next Issue | Archive | Adv Search

<< | >>

Effect of B Elements on the Catalytic Combustion of Methane for Ce_0.8Mg_0.2BO₃

Xu Zhuang, Xie Yaqiong, Jin Liying, Zheng Jiandong

College of Material and Chemical Engineering, Chuzhou University, Anhui Chuzhou 239000, China

Abstract	Reference	Related Articles

Download: PDF (4971KB) HTML () Export: BibTeX or EndNote (RIS) Supporting Info

Abstract The Ce_0.8Mg_0.2BO₃(B=Cr, Mn, Fe, Co, Ni, Cu)series catalysts were prepared by co-precipitation method using NH₄HCO₃ as precipitant. The structures were characterized by XRD, BET, H₂-TPR, TG-DSC, FT-IR and SEM, and its performance catalytic on methane combustion was tested. The results show that the preparation of Ce_0.8Mg_0.2BO₃ (B=Cr, Mn, Fe, Co, Ni, Cu) catalysts with different ions by co-precipitation method can form a complete perovskite after calcination at 800℃. The catalyst Ce_0.8Mg_0.2NiO₃ shows an excellent activity for methane combustion (the conversion of 10% and 90% are obtained at 410℃ and 547℃, respectively).

	Service

	Email this article
	Add to my bookshelf
	Add to citation manager
	Email Alert
	RSS
	Articles by authors
	Xu Zhuang
	Xie Yaqiong
	Jin Liying
	Zheng Jiandong

Keywords： co-precipitation method； perovskite； catalytic combustion of methane

Received 2018-05-22;

About author:

Cite this article:

Xu Zhuang, Xie Yaqiong, Jin Liying, Zheng Jiandong.Effect of B Elements on the Catalytic Combustion of Methane for Ce_0.8Mg_0.2BO₃[J] Chemcial Industry and Engineering, 2019,V36(2): 15-20

[1] 赵春升. 全球化石能源的地理分布与中国能源安全保障的政策选择[D]. 兰州:兰州大学, 2012 Zhao Chunsheng. Geographical distribution of global fossil energy and policy options of China's energy security[D]. Lanzhou:Lanzhou University, 2012(in Chinese)
[2] 杨宇, 刘毅, 金凤君. 世界石油探明储量分布特征与空间格局演化[J]. 世界地理研究, 2014, 23(1):19-28 Yang Yu, Liu Yi, Jin Fengjun. Distribution characteristics and spatial evolution of the world proven oil reserves[J]. World Regional Studies, 2014, 23(1):19-28(in Chinese)
[3] 尹坤, 姜蕤. 煤炭燃烧的大气污染及相关解决途径分析[J]. 科技展望, 2016, 26(3):257-257 Yin Kun, Jiang Rui. Air pollution of coal combustion and related solutions[J]. Science and Technology, 2016, 26(3):257-257(in Chinese)
[4] 周肖肖. 中国环境规划对化石能源耗竭路径的影响研究[D]. 北京:中国矿业大学, 2014 Zhou Xiaoxiao. Study on the relationship between environmental regulation and fossil energy consumption path in china[D]. Beijing:China University of Mining and Technology, 2014(in Chinese)
[5] 刘晓龙. 我国进口液化天然气可持续发展战略研究[J]. 商业经济研究, 2016, (3):149-150 Liu Xiaolong. Research on the sustainable development strategy of LNG imported in China[J]. Journal of Commercial Economics, 2016, (3):149-150(in Chinese)
[6] 殷伊琳. 传统化石能源清洁化利用的现状及展望[J]. 天津化工, 2016, 30(2):1-3 Yin Yilin. The present situation and prospect of the clean use of traditional fossil energy[J]. Tianjin Chemical Industry, 2016, 30(2):1-3(in Chinese)
[7] 吴西顺, 黄文斌, 刘文超, 等. 全球天然气水合物资源潜力评价及勘查试采进展[J]. 海洋地质前沿, 2017, 33(7):63-78 Wu Xishun, Huang Wenbin, Liu Wenchao, et al. World-Wide progress of resource potential assessment, exploration and production test of natural gas hydrate[J]. Marine Geology Frontiers, 2017, 33(7):63-78(in Chinese)
[8] 汤旸. 浅谈天然气能源的市场现状[J]. 科技展望, 2016, 26(25):315-315 Tang Yang. Talking about the market status of natural gas energy[J]. Science and Technology, 2016, 26(25):315-315(in Chinese)
[9] 董庆珊, 张世红, 周琦. 催化燃烧炉的节能性分析[J]. 建筑节能, 2007, 35(6):50-53 Dong Qingshan, Zhang Shihong, Zhou Qi. The energy-saving analysis of catalytic combustion burner[J]. Construction Conserves Energy, 2007, 35(6):50-53(in Chinese)
[10] 朱鹏飞, 周毛毛, 徐壮, 等. La_0.2Ce_0.8Fe_xMn_1-xO₃催化剂的制备及其对甲烷燃烧的催化性能[J]. 合成化学, 2017, 25(12):993-996 Zhu Pengfei, Zhou Maomao, Xu Zhuang, et al. Preparation of La_0.2Ce_0.8Fe_xMn_1-xO₃ catalysts and their catalytic properties for combustion of methane[J]. Chinese Journal of Synthetic Chemistry, 2017, 25(12):993-996(in Chinese)
[11] 姚儒霖, 李东升, 吴剑桥, 等. 双钙钛矿Sr₂FeMn_1-xCo_xO₆催化剂的制备及其催化性能[J]. 合成化学, 2017, 25(3):213-217 Yao Rulin, Li Dongsheng, Wu Jianqiao, et al. Preparation and catalytic properties of double perovskite catalysts Sr₂FeMn_1-xCo_xO₆[J]. Chinese Journal of Synthetic Chemistry, 2017, 25(3):213-217(in Chinese)
[12] Zou G, Wang Z, Sun M, et al. A novel solid-gas process to synthesize LaMnO₃ perovskite with high surface area and excellent activity for methane combustion[J]. Journal of Natural Gas Chemistry, 2011, 20(3):294-298
[13] Li C, Wang W, Zhao N, et al. Structure properties and catalytic performance in methane combustion of double perovskites Sr₂Mg_1-x Mn_x MoO_6-δ[J]. Applied Catalysis B:Environmental, 2011, 102(1/2):78-84
[14] Escudero M J, Gómez de Parada I, Fuerte A, et al. Study of Sr₂Mg(Mo_0.8Nb_0.2)O_6-δ as anode material for solid oxide fuel cells using hydrocarbons as fuel[J]. Journal of Power Sources, 2013, 243:654-660
[15] 胡金燕, 储伟, 瞿芬芬. La助剂添加方式对甲烷催化燃烧用Mn/Al₂O₃催化剂的影响[J]. 合成化学, 2008, 16(2):162-165 Hu Jinyan, Chu Wei, Qu Fenfen. Effect of La promoter introducing methods on catalystic activety of Mn/Al₂O₃ in methane combustion[J]. Chinese Journal of Synthetic Chemistry, 2008, 16(2):162-165(in Chinese)
[16] 张慧敏. 稀土双钙钛矿型铝系催化剂的制备及甲烷催化燃烧性能研究[D]. 呼和浩特:内蒙古大学, 2011 Zhang Huimin. Preparation and catalytic activities of the rare-earth double perovskite-type catalysts for methane combustion[D]. Huhehaote:Inner Mogolia University, 2011(in Chinese)
[17] Li C, Wang W, Zhao N, et al. Structure properties and catalytic performance in methane combustion of double perovskites Sr₂Mg_1-x Mn_x MoO_6-δ[J]. Applied Catalysis B:Environmental, 2011, 102(1/2):78-84
[18] 郑建东, 侯豹, 魏有山, 等. 双钙钛矿催化剂LaSrFeMo_1-xCo_xO₆的制备及其催化性能研究[J]. 石油化工, 2013, 42(12):1331-1335 Zheng Jiandong, Hou Bao, Wei Youshan, et al. Preparation of double perovskite oxides LaSrFeMo_1-xCo_xO₆ and its properties in catalytic combustion of methane[J]. Petrochemical Technology, 2013, 42(12):1331-1335(in Chinese)
[19] 张军, 赵宁, 肖福魁, 等. NiMgAlO-F催化剂的物化性能及其在甲烷部分氧化制合成气中的应用[J]. 石油化工, 2010, 39(12):1319-1325 Zhang Jun, Zhao Ning, Xiao Fukui, et al. Physicochemical properties of NiMgAlO-F catalyst and its application to partial oxidation of methane[J]. Petrochemical Technology, 2010, 39(12):1319-1325(in Chinese)
[20] Yin F, Ji S, Wu P, et al. Preparation, characterization, and methane total oxidation of AAl₁₂O₁₉ and AMAl₁₁O₁₉ hexaaluminate catalysts prepared with urea combustion method[J]. Journal of Molecular Catalysis A:Chemical, 2008, 294(1/2):27-36
[21] Hu R, Ding R, Chen J. Preparation and catalytic activities of the novel double perovskite-type oxide La₂CuNiO₆ for methane combustion[J]. Catal Commun, 2012, 21(5):38-41
[22] 胡瑞生,阿山,吕宏缨,等. 焙烧温度对稀土钻系复合氧化物催化剂结构与性能的影响[J]. 分子催化, 2002,16(12):127-130 Hu Ruisheng, A Shan, Lv Hongying, et al. Effect of calcination temperature on structure and properties of rare earth diamond complex oxide catalysts[J]. Journal of Molecular Catalysis, 2002, 16(12):127-130(in Chinese)