A Comparative Study on the Synthesis of Metal Organic Frameworks MOF-5 by Different Methods

化学工业与工程

Chemcial Industry and Engineering

2018, Vol. 35

Issue (6) :7-12 DOI: 10.13353/j.issn.1004.9533.20161105

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A Comparative Study on the Synthesis of Metal Organic Frameworks MOF-5 by Different Methods

Liu Qian¹, Shen Yantong¹, Liu Botan^1,2

1. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China;
2. School of Chemical Engineering and Materials Science, Tianjin University of Science and Technology, Tianjin 300457, China

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Abstract For the preparation of metal-organic frameworks MOF-5, three different ways, hydrothermal synthesis method, direct method and direct method with adding extra H₂O₂ were used to prepare compound MOF-5 crystals. The MOF-5 crystals were characterized by X-ray diffractometer (XRD), scanning electron microscope(SEM), Fourier transform infrared spectrometer(FTIR) and thermo gravimetric analyzer (TG). The effects of different synthesis methods on the crystals structure, morphology and thermal stability of the composite were studied. The results showed that the X-ray diffraction patterns of samples of the three methods are consistent with the characteristic peaks of the MOF-5 crystals in the literatures. It means that the MOF-5 crystals can be synthesized by these methods successfully. But the other characterization results show that the crystal particle diameter synthesized by hydrothermal method is smaller and has a regular cube structure, but poorer thermal stability. As to the other two methods, the products are a kind of crystals with irregular aggregations and different properties. Furthermore, the addition of H₂O₂ is helpful to the rapid formation and dispersion of grains.

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	Liu Qian
	Shen Yantong
	Liu Botan

Keywords： metal-organic frameworks； MOF-5； hydrothermal synthesis； direct adding method； H₂O₂

Received 2016-06-01;

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Liu Qian, Shen Yantong, Liu Botan.A Comparative Study on the Synthesis of Metal Organic Frameworks MOF-5 by Different Methods[J] Chemcial Industry and Engineering, 2018,V35(6): 7-12

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