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Chemcial Industry and Engineering 2013, Vol. 30 Issue (3) :17-23    DOI:
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Synthesis of Bis-Thiourea Derivatives and Study of Their Gel Properties
 WANG  Shu-Cheng, CHAI  Wei, HUANG  Yao-Dong
School of Chemical Engineering and Technology, Tianjin University

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Abstract Two series of bisthiourea derivatives 6a—d and 7a—d were synthesized and their gelling properties were checked. The results showed that 6a—d had stronger gelation ability than 7a—d. The structures of gels were investigated using concentrationdependent SEM,1H NMR, FT-IR and XRD. It was found that intermolecular hydrogen bonds were the main driving force for the gelation. The results of XRD suggested that the dry gels of 6c had columnar hexagonal structure while 7c was layered.
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WANG Shu-Cheng
CHAI Wei
HUANG Yao-Dong
Keywordsbis-thiourea   gelation   hydrogen bonds     
Received 2012-05-09;
Corresponding Authors: 黄耀东, 电话: (022)87402150,E-mail: huangyaodong@tju.edu.cn。     Email: huangyaodong@tju.edu.cn
About author: 王书成(1986-),男,硕士研究生,主要从事有机合成方面的研究。
Cite this article:   
WANG Shu-Cheng, CHAI Wei, HUANG Yao-Dong.Synthesis of Bis-Thiourea Derivatives and Study of Their Gel Properties[J]  Chemcial Industry and Engineering, 2013,V30(3): 17-23
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