铌酸的催化应用

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化学工业与工程

化学工业与工程

2008, Vol. 25

Issue (4) :359-364 DOI:

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铌酸的催化应用

李春晶;沈健;

辽宁石油化工大学石油化工学院,辽宁石油化工大学石油化工学院抚顺113000,抚顺113000

Application of Niobic Acid in Catalysis

LI Chun-jing,SHEN Jian(Department of Petrochemical Technology,Liaoning Shihua University,Fushun 113000,Liaoning Province,China)

(Department of Petrochemical Technology,Liaoning Shihua University,Fushun 113000,Liaoning Province,China

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摘要铌酸和含铌化合物独特酸性和热稳定性,广泛的应用催化领域中。铌酸可直接作为固体催化剂,应用于水解、酯化、缩合、烷基化等反应中;铌酸也作为载体负载金属,应用于F-T合成、氧化反应和加氢等反应中;含铌化合物也可作为负载型催化剂,负载到不同类型的载体上;含铌化合物也作为助剂或光催化剂,广泛地应用于催化多种化学反应。铌类催化剂具有催化活性高、选择性好和使用寿命长等优点。研究开发新型铌类催化剂具有良好的应用前景。

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	李春晶
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关键词：铌酸含铌化合物固体催化剂载体助剂光催化剂

Abstract： Niobic acid and compounds containing niobium are applied in a wide range of catalysis fields for their unique acidic property and thermal stability.Niobic acid as a solid catalyst can be directly applied in the hydrolysis,esterification,condensation and alkylation reaction etc.Compounds containing niobium,as a supporter loaded metal,can be used in Fischer-Tropsch synthesis,hydrogenation and oxidation reactions etc.As a supported catalyst,it can be loaded to different type of catalysts.Compounds containing niobium can also be widely used in a variety of chemical reactions as assistant or photocatalysts.The niobium catalysts had high catalytic activity,selectivity and long service life,so the development of new type of niobium catalysts has a good prospect.

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Received 2008-07-15; published 2008-07-15

引用本文:

李春晶;沈健;.铌酸的催化应用[J]. 化学工业与工程, 2008,25(4): 359-364

LI Chun-jing,SHEN Jian.Application of Niobic Acid in Catalysis[J]. Chemcial Industry and Engineering, 2008,25(4): 359-364

[1]	UEKAWA N,KUDO T,MORI F,et al.Low-temeraturesynthesis of niobium oxide nanopaticles from peroxo niobicacid sol[J].Colloid Interf Sci.2003,264(2):378-384
[2]	RISTIC M,POPOVIC S,MUSIC S.Sol-gel synthesis andcharacterization of Nb2O5powders[J].Mater Lett,2004,58(21):2 658-2 663.
[3]	TANABE K.Application of niobium oxides as catalysis[J].Catal Today.1990,25(8):1-11
[4]	MAURER S M,KO E I.Structural and acidiccharacterization of niobia aerogels[J].Catal.1992,135(1):125-134
[5]	CHEN Z,IIZUKA T,TANABE K.Niobic acid as an efficientcatalyst for vapor phase esterification of ethyl alcohol withacetic acid[J].Chem Lett,1984,151(7):1 085-1 088.
[6]	ARMAROLI T,BUSCA G,CARLIN C,et al.Acid sitescharacterization of niobium phosphate catalysts and theiractivity in fructose dehydration to 5-hydroxymethyl-2-furaldehyde[J].Mol Catal A:Chem.2000,151(1):233-243
[7]	李应成,岳斌,杨为民,等.铌酸/氧化铌在多相cuihua反应中的应用[J].化学通报,2005,68(3):172-178.
[8]	SUN Q,AUROUX A,SHEN J Y.Surface acidity of niobiumphosphate and steam reforming of dimethoxymethane overCuZnO/Al2O3-NbP complex catalysts[J].Catal.2006,244(1):1-9
[9]	危春玲,陈丰秋,张欢欢,詹晓力.铌酸催化水解葡萄糖的研究[J].工业催化,2004,12(12):46-49.
[10]	金振兴,孙曙光,张庆勋.硫酸铈和磷酸处理对铌酸表面酸度及催化活性的影响[J].精细石油化工,2003,11(6):22-24.
[11]	赵华,黄丽华,曾建,谭志斗.铌酸催化合成丙酸苄酯[J].精细与专业化学品,2006,15(14):19-20.
[12]	李菊仁,吴小慧,田志新,龚健.铌酸催化合成环己酮1,2-丙二醇缩酮[J].合成化学,2002,10(1):53-55.
[13]	陈君琴,刘纯山,俞丹群,等.酸处理铌酸对合成2,5-二甲基-2,4-己二烯催化作用的研究[J].石油化工,2004,9(33):865-868.
[14]	PAOLO C,ANTONELLA G,SERENA B,et al.Niobic acidand niobium phosphate as highly acidic viable catalysts inaqueous medium:Fructose dehydration reaction[J].CatalysisToday,2006,118(3):373-378.
[15]	CARLINI C,GIUTTARI M,MARIA R G A,et al.Selectivesaccharides dehydration to 5-hydroxymethyl-2-furaldehydeby heterogeneous niobium catalysts[J].Appl Catal A.1999,183(2):295-302
[16]	CYNTHIA C,MENDES P,ELIZABETH R L.Alkylation oftoluene and anisole with 1-octen-3-ol over niobium catalysts[J].Applied Catalysis A.2004,266(1):67-72
[17]	陈浩,邓景发,蒋安仁,等.过氧铌酸催化下双氧水选择氧化环戊烯制备戊二醛[J].复旦学报(自然科学版),2002,41(6):317-324.
[18]	DECYK P.Sates of transition metal ions in modifiedmesoporous MCM-41 and in microporous ZSM-5 studied byESR spectroscopy[J].Catal Today.2006,114(2/3):142-153
[19]	WOJCIESZAK R,JASIK A,MONTEVERDI S,et al.Nickelniobia interaction in non-classical Ni/Nb2O5catalysts[J].Journal of Molecular Catalysis A:Chemical.2006,256(1-2):225-233
[20]	CAGNOLI M V,ALVAREZ A M,GALLEGOS N G,et al.M ssbauer and XPS spectroscopies studies of SMSI effect onFe/Nb2O5catalysts for the Fischer-Tropsch synthesis[J].Applied Catalysis A.2007,326(1):113-119
[21]	SCHMAL M,ARANDA D A G,SOARS R R,et al.A studyof the promoting effect of noble metal addition on niobia andniobia alumina[J].Catal Today.2000,57(3/4):169-176
[22]	ZHAO C l,ISRAL E W.Selective oxidation of propylene toacrolein over supported V2O5/Nb2O5catalysts:An in situRaman,IR,TPSR and kinetic study[J].Catalysis Today.2006,118(3/4):332-343
[23]	MARQUES P,RIBEIRO N F P,SCHMAL M,et al.SelectiveCO oxidation in the presence of H2over Pt and Pt-Sncatalysts supported on niobia[J].Power Sources.2006,158(1):504-508
[24]	KUNIMORI K,HU Z,UCHIJIMA T,et al.Rhodium-niobiainteraction in niobia-promoted Rh/SiO2catalysts:Formationof RhNbO4 on SiO2[J].Catalysis Today.1990,8(1):85-87
[25]	JASIK A,WOJCIESZAK R,MONTEVERDI S,et al.Study ofnickel catalysts supported on Al2O3,SiO2or Nb2O5oxides[J].Journal of Molecular Catalysis A:Chemical.2005,242(1-2):81-90
[26]	PARVULESCU V,CONSTANTIN C,SU B L.Liquid phaseoxidation of aromatic hydrocarbons using highly ordered Nband NbCo-MCM-41 nanoreactors[J].Mol Catal A:Chem.2003,202(1/2):171-178
	PARVULESCU V,CONSTANTIN C,SU B L.Liquid phaseoxidation of aromatic hydrocarbons using highly ordered Nband NbCo-MCM-41 nanoreactors[J].Journal of MolecularCatalysis A,2003,202(1/2):171-178.
[27]	TREJDA M,TUEL A,KUJAWA J,et al.Niobium rich SBA-15 materials-preparation,characterization and catalyticactivity[J].Microporous and Mesoporous Materials.2008,110(2/3):271-278
[28]	IVONEIDE C,BARROS L,VALDEILSON S B,et al.Effectsof niobium addition on ZSM-5 studied by thermal andspectroscopy methods[J].Microporous and MesoporousMaterials.2008,109(1/3):485-493
[29]	LI Y C,YAN S R,YUE B,et al.Selective catalytichydration of ethyleneoxide over niobium oxide supported on-αalumina[J].Applied Catalysis A:General.2004,272(1-2):305-310
[30]	李应成,闫世润,杨为民,等.载体比表面积及孔径对Nb2O5/-αAl2O3用催化剂酸性及反应性能的影响[J].石油化工,2006,35(3):221-225.
[31]	张艳红,钟顺和.SiO2负载MoVNbO复合氧化物催化剂上乙烷低温氧化制乙酸[J].催化学报,2005,26(8):719-723.
[32]	MARIA S P,RICHARD L,YOSHITAKA G.Local orderstructure and surface acidity properties of a Nb2O5/SiO2mixed oxide prepared by the sol-gel processing method[J].Journal of Solid State Chemistry,2004,177(7):2 432-2 439.
[33]	OLIVER J M,LOPEZ,NIETO J M,et al.Selective oxidationand ammoxidation of propane on a Mo-V-Te-Nb-O mixedmetal oxide catalyst:A comparative study[J].CatalysisToday,2004,96(4):241-249.
[34]	VITRY D,MORIKAWA Y,DUBOSI J L,et al.Mo-V-Te-(Nb)-O mixed metal oxides prepared by hydrothermalsynthesis for catalytic selective oxidations of propane andpropene to acrylic acid[J].Applied Catalysis A:General.2003,251(2):411-424
[35]	ROUSSEL M,BOUCHARD M,BORDES R E,et al.Oxidation of ethane to ethylene and acetic acid by MoVNbOcatalysts[J].Catal Today.2005,99(1/2):77-87
[36]	JAMAL N,Al-SAEEDI,VADIM V G.High-throughputexperimentation in multicomponent bulk mixed metal oxides:Mo-V-Sb-Nb-O system for selective oxidation of propane toacrylic acid[J].Applied Catalysis A:General.2002,237(1/2):111-120
[37]	ALEXANDRE G S,PRADO,ELAINE A,et al.Ammoniumcomplex of niobium as a precursor for the hydrothermalpreparation of cellulose acetate/Nb2O5photocatalyst[J].Journal of Molecular Catalysis A:Chemical.2005,237(1/2):115-119
[38]	ABE R,HIGASHI M,SAYAMA K,et al.Overallphotocatalytic acitivity of R3MO7and R2Ti2O7(R=Y,Gd,La;M=Nb,Ta)for water splitting into H2and O2[J].PhyChem B,2006,110(5):2 219-2 226.
[39]	郭宪吉,侯文华,陆春良,等.高比表面TiO2柱层状HLaNb2O7的制备和表征[J].化学学报,2003,61(12):1 976-1 979.