Corrosion inhibition performance of furfural derivatives in hydrochloric acid solution

Abstract It is a hot research point to prepare green corrosion inhibitors with bio-wastes as raw materials. Furfural is one of the most promising chemical platforms derived from biomass. Here, a new high-efficiency corrosion inhibitor, namely N²-(2-furylidene)-1,3,5-triazine-2,4,6-triamine (FMA), was prepared by condensation reaction of furfural and melamine. Corrosion inhibition performance of FMA in 1.0 mol·L^-1 HCl was characterized by weight loss test, electrochemical measurement and surface characterization. The static weight loss test results under room temperature condition show that the corrosion inhibition efficiency is as high as 95.14% under the condition of the FMA concentration at 200 mg·L^-1, while the temperature is up to 338 K, the corresponding corrosion inhibition efficiency remains above 90%. The electrochemical test results show that FMA is a mixed type corrosion inhibitor that mainly inhibits anode process, and its excellent corrosion inhibition performance is attributed to the ability to form an adsorption film on the surface of mild steel that obeys the Langmuir isotherm adsorption model.Scanning electron microscopy (SEM) results show that the surface of mild steel containing FMA is still smooth flat after being immersed in 1.0 mol·L^-1 HCl solution for 6 hours.

	Service

	Email this article
	Add to my bookshelf
	Add to citation manager
	Email Alert
	RSS
	Articles by authors
	SHI Xuelei
	WANG Jixiao
	GAO Min
	SONG Shuangshuang
	CONG Chang
	WU Changhao
	WANG Zhi

Keywords： corrosion biomass electrochemistry furfural furanyl Schiff base corrosion inhibitor

Received 2021-12-09;

About author:

Cite this article:

SHI Xuelei, WANG Jixiao, GAO Min, SONG Shuangshuang, CONG Chang, WU Changhao, WANG Zhi.Corrosion inhibition performance of furfural derivatives in hydrochloric acid solution[J] Chemcial Industry and Engineering, 2023,V40(5): 123-134

[1] VERMA C, EBENSO E E, BAHADUR I, et al. 5-(Phenylthio)-3H-pyrrole-4-carbonitriles as effective corrosion inhibitors for mild steel in 1 M HCl:Experimental and theoretical investigation[J]. Journal of Molecular Liquids, 2015, 212:209-218
[2] GUO L, OBOT I B, ZHENG X, et al. Theoretical insight into an empirical rule about organic corrosion inhibitors containing nitrogen, oxygen, and sulfur atoms[J]. Applied Surface Science, 2017, 406:301-306
[3] 侯道林, 杨武魁, 董社英. Starch-AA-CS三元共聚物对酸溶液中碳钢的缓蚀作用[J]. 化学工业与工程, 2022, 39(2):100-107 HOU Daolin, YANG Wukui, DONG Sheying. Corrosion inhibition of carbon steel in acid solution by starch-AA-CS terpolymer[J]. Chemical Industry and Engineering, 2022, 39(2):100-107(in Chinese)
[4] CHAUHAN D S, VERMA C, QURAISHI M A. Molecular structural aspects of organic corrosion inhibitors:Experimental and computational insights[J]. Journal of Molecular Structure, 2021, doi:10.1016/j.molstruc.2020.129374
[5] VERMA C, EBENSO E E, BAHADUR I,et al. An overview on plant extracts as environmental sustainable and green corrosion inhibitors for metals and alloys in aggressive corrosive media[J]. Journal of Molecular Liquids, 2018, 266:577-590
[6] 郑天宇, 王璐, 刘金彦, 等. 离子液体在甲醇/硫酸介质中对Q235钢表面的缓蚀性能[J]. 化工学报, 2020, 71(5):2230-2239 ZHENG Tianyu, WANG Lu, LIU Jinyan, et al. Corrosion inhibition of ionic liquids on the surface of Q235 steel in methanol/sulfuric acid medium[J]. CIESC Journal, 2020, 71(5):2230-2239(in Chinese)
[7] GHAREBA S, OMANOVIC S. Interaction of 12-aminododecanoic acid with a carbon steel surface:Towards the development of ‘green’ corrosion inhibitors[J]. Corrosion Science, 2010, 52(6):2104-2113
[8] WEI H, HEIDARSHENAS B, ZHOU L, et al. Green inhibitors for steel corrosion in acidic environment:State of art[J]. Materials Today Sustainability, 2020, doi:10.1016/j.mtsust.2020.100044
[9] SATPATI S, SUHASARIA A, GHOSAL S, et al. Amino acid and cinnamaldehyde conjugated Schiff bases as proficient corrosion inhibitors for mild steel in 1 M HCl at higher temperature and prolonged exposure:Detailed electrochemical, adsorption and theoretical study[J]. Journal of Molecular Liquids, 2021, doi:10.1016/j.molliq.2020.115077
[10] VERMA C, QURAISHI M A, ALFANTAZI A, et al. Corrosion inhibition potential of chitosan based Schiff bases:Design, performance and applications[J]. International Journal of Biological Macromolecules, 2021, 184:135-143
[11] ZHANG K, YANG W, XU B, et al. Green synthesis of novel schiff bases as eco-friendly corrosion inhibitors for mild steel in hydrochloric acid[J]. Chemistry Select, 2018, 3(44):12486-12494
[12] HAQUE J, SRIVASTAVA V, CHAUHAN D S, et al. Microwave-induced synthesis of chitosan schiff bases and their application as novel and green corrosion inhibitors:Experimental and theoretical approach[J]. ACS Omega, 2018, 3(5):5654-5668
[13] HALDHAR R, PRASAD D, BAHADUR I, et al. Investigation of plant waste as a renewable biomass source to develop efficient, economical and eco-friendly corrosion inhibitor[J]. Journal of Molecular Liquids, 2021, doi:10.1016/j.molliq.2021.116184
[14] YAN K, WU G, LAFLEUR T, et al. Production, properties and catalytic hydrogenation of furfural to fuel additives and value-added chemicals[J]. Renewable and Sustainable Energy Reviews, 2014, 38:663-676
[15] LI X, JIA P, WANG T. Furfural:A promising platform compound for sustainable production of C₄ and C₅ chemicals[J]. ACS Catalysis, 2016, 6(11):7621-7640
[16] MARISCAL R, MAIRELES-TORRES P, OJEDA M, et al. Furfural:A renewable and versatile platform molecule for the synthesis of chemicals and fuels[J]. Energy & Environmental Science, 2016, 9(4):1144-1189
[17] VERMA C, VERMA D K, EBENSO E E, et al. Sulfur and phosphorus heteroatom-containing compounds as corrosion inhibitors:An overview[J]. Heteroatom Chemistry, 2018, doi:10.1002/hc.21437
[18] 罗雪, 黄海军, 罗自萍, 等. 无患子果皮提取物的纳微米聚集体对钢的高效缓蚀[J]. 化工学报, 2020, 71(10):4760-4772 LUO Xue, HUANG Haijun, LUO Ziping, et al. High efficient corrosion inhibition of steel by nano-micro aggregates of Sapindus mukorossi Gaertn peel extracts[J]. CIESC Journal, 2020, 71(10):4760-4772(in Chinese)
[19] AL-FAKIH A M, ABDALLAH H, AZIZ M. Experimental and theoretical studies of the inhibition performance of two furan derivatives on mild steel corrosion in acidic medium[J]. Materials and Corrosion, 2018, 70:135-148
[20] LIAO L, MO S, LUO H, et al. Relationship between inhibition performance of melamine derivatives and molecular structure for mild steel in acid solution[J]. Corrosion Science, 2017, 124:167-177
[21] TONDI G, CEFARIN N, SEPPERER T, et al. Understanding the polymerization of polyfurfuryl alcohol:Ring opening and Diels-alder reactions[J]. Polymers, 2019, doi:10.3390/polym11122126
[22] BERRISSOUL A, LOUKILI E, Mechbal N, et al. Anticorrosion effect of a green sustainable inhibitor on mild steel in hydrochloric acid[J]. Journal of Colloid and Interface Science, 2020, 580:740-752
[23] SAHA S K, DUTTA A, GHOSH P, et al. Adsorption and corrosion inhibition effect of Schiff base molecules on the mild steel surface in 1 M HCl medium:A combined experimental and theoretical approach[J]. Physical Chemistry Chemical Physics:PCCP, 2015, 17(8):5679-5690
[24] LGAZ H, SAHA S K, CHAOUIKI A, et al. Exploring the potential role of pyrazoline derivatives in corrosion inhibition of mild steel in hydrochloric acid solution:Insights from experimental and computational studies[J]. Construction and Building Materials, 2020, doi:10.1016/j.conbuildmat.2019.117320
[25] YE Y, YANG D, CHEN H, et al. A high-efficiency corrosion inhibitor of N-doped citric acid-based carbon dots for mild steel in hydrochloric acid environment[J]. Journal of Hazardous Materials, 2020, doi:10.1016/j.jhazmat.2019.121019
[26] OLASUNKANMI L O, EBENSO E E. Experimental and computational studies on propanone derivatives of quinoxalin-6-yl-4, 5-dihydropyrazole as inhibitors of mild steel corrosion in hydrochloric acid[J]. Journal of Colloid and Interface Science, 2020, 561:104-116
[27] VERMA C, OLASUNKANMI L, EBENSO E, et al. Adsorption behavior of glucosamine-based, pyrimidine-fused heterocycles as green corrosion inhibitors for mild steel:Experimental and theoretical studies[J]. Journal of Physical Chemistry C, 2016, 120:11598-11611
[28] BEDAIR M A, EL-SABBAH M M B, FOUDA A S, et al. Synthesis, electrochemical and quantum chemical studies of some prepared surfactants based on azodye and Schiff base as corrosion inhibitors for steel in acid medium[J]. Corrosion Science, 2017, 128:54-72
[29] ZARROUK A, HAMMOUTI B, LAKHLIFI T, et al. New 1H-pyrrole-2, 5-dione derivatives as efficient organic inhibitors of carbon steel corrosion in hydrochloric acid medium:Electrochemical, XPS and DFT studies[J]. Corrosion Science, 2015, 90:572-584
[30] EL AATIAOUI A, KOUDAD M, CHELFI T, et al. Experimental and theoretical study of new Schiff bases based on imidazo(1, 2-a)pyridine as corrosion inhibitor of mild steel in 1M HCl[J]. Journal of Molecular Structure, 2021, doi:10.1016/j.molstruc.2020.129372
[31] YE Y, YANG D, CHEN H. A green and effective corrosion inhibitor of functionalized carbon dots[J]. Journal of Materials Science & Technology, 2019, 35(10):2243-2253
[32] GUIMARAES T A S, DA CUNHA J N, DE OLIVEIRA G A, et al. Nitrogenated derivatives of furfural as green corrosion inhibitors for mild steel in HCl solution[J]. Journal of Materials Research and Technology, 2020, 9(4):7104-7122
[33] ECH-CHIHBI E, NAHLE A, SALIM R, et al. Computational, MD simulation, SEM/EDX and experimental studies for understanding adsorption of benzimidazole derivatives as corrosion inhibitors in 1.0 M HCl solution[J]. Journal of Alloys and Compounds, 2020, doi:10.1016/j.jallcom.2020.155842
[34] KHAN G, BASIRUN W J, KAZI S N, et al. Electrochemical investigation on the corrosion inhibition of mild steel by Quinazoline Schiff base compounds in hydrochloric acid solution[J]. Journal of Colloid and Interface Science, 2017, 502:134-145
[35] BERDIMURODOV E, KHOLIKOV A, AKBAROV K, et al. Thioglycoluril derivative as a new and effective corrosion inhibitor for low carbon steel in a 1 M HCl medium:Experimental and theoretical investigation[J]. Journal of Molecular Structure, 2021, doi:10.1016/j.molstruc.2021.130165
[36] CHAUHAN D S, QURAISHI M A, NIK W B W, et al. Triazines as a potential class of corrosion inhibitors:Present scenario, challenges and future perspectives[J]. Journal of Molecular Liquids, 2021, doi:10.1016/j.molliq.2020.114747