Synthesis of Propyl Gallate Catalyzed by Resin and Process Optimization

化学工业与工程

Chemcial Industry and Engineering

2021, Vol. 38

Issue (1) :27-35 DOI: 10.13353/j.issn.1004.9533.20200319

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Synthesis of Propyl Gallate Catalyzed by Resin and Process Optimization

Dong Gang^1,2, Liu Lanxiang¹, Sun Yanlin², Li Kun¹, Zhang Wenwen¹, Liu Yiwen³, Chen Qinglong³, Zhang Hong¹

1. Research Institute of Resources Insects, Chinese Academy of Forestry, Research Center of Engineering and Technology on Characteristic Forest Resources, State Administration of Forestry and Grassland, Kunming 650223, China;
2. College of Chemical Engineering, Kunming University of Science and Technology, Kunming 650500, China;
3. Wufeng Chicheng Biotechnology CO., LTD., Research Center of Engineering and Technology on Efficient Cultivation and Intensive Processing for Gallnut of Forestry and Grassland Administration of China, Hubei Yichang 443413, China

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Abstract As a heterogeneous catalyst, cation exchange resins are widely used in organic synthesis reactions. Preparation of highly active resin catalysts for the synthesis of propyl gallate by screening of resin types, activated acid types, activated acid concentration, etc. The results showed that when the resin catalyst dosage was 4.06% of the total mass of the reaction raw materials, the reaction time was 20 h, the yield of propyl gallate was stable at about 91.0%, and the purity of propyl gallate was greater than 99.9% that measured by high performance liquid phase. The resin catalyst could be reused more than 40 times through regeneration, and its effectively reduced the problem of solving acid discharge. Compared with traditional methods, the method in this paper could better meet the new industrial requirements of high catalytic efficiency, environmental protection and economy.

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	Dong Gang
	Liu Lanxiang
	Sun Yanlin
	Li Kun
	Zhang Wenwen
	Liu Yiwen
	Chen Qinglong
	Zhang Hong

Keywords： resin； catalyst； heterogeneous； synthesis； propyl gallate

Received 2020-04-28;

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Dong Gang, Liu Lanxiang, Sun Yanlin, Li Kun, Zhang Wenwen, Liu Yiwen, Chen Qinglong, Zhang Hong.Synthesis of Propyl Gallate Catalyzed by Resin and Process Optimization[J] Chemcial Industry and Engineering, 2021,V38(1): 27-35

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