负载型纳米催化剂在炔烃选择性半加氢中的研究进展

摘要烯烃是一类重要的有机化合物,广泛用于合成药物、农药和高分子材料等。选择性半加氢反应能够有效地将炔烃转化为烯烃,具有重要的实际生产价值。近年来,负载型纳米催化剂在炔烃选择性半加氢这一领域展现了显著优势。总结了近5年负载型纳米催化剂在炔烃选择性半加氢制备烯烃的研究进展。简要介绍了炔烃半加氢反应的机理,讨论了负载型纳米催化剂对炔烃半加氢反应选择性提升的影响因素,并对典型的负载型纳米催化剂在热催化、电催化和光催化炔烃选择性半加氢反应中的研究进展进行了归纳总结。最后,对负载型纳米催化剂在炔烃半加氢反应的前景进行了展望。

	Service

	把本文推荐给朋友
	加入我的书架
	加入引用管理器
	Email Alert
	RSS
	作者相关文章
	李亚莹
	薛陈
	贾伟杰
	李小鹏
	肖琪

关键词：炔烃负载型纳米催化剂选择性半加氢

Abstract： Alkenes represent a crucial category of organic compounds, extensively utilized in the synthesis of pharmaceuticals, pesticides, and polymers. The selective semi-hydrogenation reaction serves as an effective method to transform alkynes into alkenes, bearing significant practical production value. In recent years, supported nano-catalysts have exhibited notable advantages in the domain of selective semi-hydrogenation of alkynes. This review provides a comprehensive overview of the advancements in the use of supported nano-catalysts for the selective semi-hydrogenation of alkynes over the past five years. It briefly introduces the mechanism of the alkyne semi-hydrogenation reaction, and discusses the factors influencing the enhancement of reaction selectivity by these nano-catalysts. Furthermore, it summarizes the research progress concerning typical supported nano-catalysts in thermocatalytic, electrocatalytic, and photocatalytic selective semi-hydrogenation of alkynes. Finally, it offers a forward-looking perspective on the future potential of supported nano-catalysts in alkyne semi-hydrogenation reactions.

Keywords： alkynes supported nano-catalyst selectivity semi-hydrogenation

Received 2024-08-01;

Fund:上海市科委浦江人才计划(21PJ1400400)。

Corresponding Authors: 肖琪,研究员,E-mail:qi.xiao@dhu.edu.cn。 Email: qi.xiao@dhu.edu.cn

About author: 李亚莹(1997-),女,博士研究生,现从事负载型纳米材料催化方面的研究。

引用本文:

李亚莹, 薛陈, 贾伟杰, 李小鹏, 肖琪.负载型纳米催化剂在炔烃选择性半加氢中的研究进展[J]. 化学工业与工程, 2024,41(5): 164-182

LI Yaying, XUE Chen, JIA Weijie, LI Xiaopeng, XIAO Qi.Advances of supported nano-catalysts for selective semi-hydrogenation of alkynes[J]. Chemcial Industry and Engineering, 2024,41(5): 164-182

[1] ZHANG L, ZHOU M, WANG A, et al. Selective hydrogenation over supported metal catalysts: From nanoparticles to single atoms[J]. Chemical Reviews, 2020, 120(2): 683-733
[2] ALBANI D, SHAHROKHI M, CHEN Z, et al. Selective ensembles in supported palladium sulfide nanoparticles for alkyne semi-hydrogenation[J]. Nature Communications, 2018, 9: 2634
[3] BOITIAUX J P, COSYNS J, VASUDEVAN S. Hydrogenation of highly unsaturated hydrocarbons over highly dispersed palladium catalyst[J]. Applied Catalysis, 1983, 6(1): 41-51
[4] BOITIAUX J P, COSYNS J, VASUDEVAN S. Hydrogenation of highly unsaturated hydrocarbons over highly dispersed Pd catalyst[J]. Applied Catalysis, 1985, 15(2): 317-326
[5] WANG Z, LUO Q, MAO S, et al. Fundamental aspects of alkyne semi-hydrogenation over heterogeneous catalysts[J]. Nano Research, 2022, 15(12): 10044-10062
[6] MCNEICE P, MVLLER M A, MEDLOCK J, et al. Designing a green replacement for the lindlar catalyst for alkyne semi-hydrogenation using silica-supported nickel nanoparticles modified by N-doped carbon[J]. ACS Sustainable Chemistry & Engineering, 2022, 10(30): 9787-9797
[7] NOGAMI S, SHIDA N, IGUCHI S, et al. Mechanistic insights into the electrocatalytic hydrogenation of alkynes on Pt-Pd electrocatalysts in a proton-exchange membrane reactor[J]. ACS Catalysis, 2022, 12(9): 5430-5440
[8] SANKAR M, HE Q, MORAD M, et al. Synthesis of stable ligand-free gold-palladium nanoparticles using a simple excess anion method[J]. ACS Nano, 2012, 6(8): 6600-6613
[9] VILÉ G, ALBANI D, ALMORA-BARRIOS N, et al. Advances in the design of nanostructured catalysts for selective hydrogenation[J]. ChemCatChem, 2016, 8(1): 21-33
[10] QIAO B, WANG A, YANG X, et al. Single-atom catalysis of CO oxidation using Pt₁/FeO_x[J]. Nature Chemistry, 2011, 3: 634-641
[11] MEHRABADI B A T, ESKANDARI S, KHAN U, et al. A review of preparation methods for supported metal catalysts[M]//Advances in Catalysis. Amsterdam: Elsevier, 2017: 1-35
[12] BLASER H U, MALAN C, PUGIN B, et al. Selective hydrogenation for fine chemicals: Recent trends and new developments[J]. Advanced Synthesis & Catalysis, 2003, 345(1/2): 103-151
[13] WU Q, SHEN C, LIU C. Amino acid (histidine) modified Pd/SiO₂ catalyst with high activity for selective hydrogenation of acetylene[J]. Applied Surface Science, 2023, 607: 154976
[14] ZOU S, LOU B, YANG K, et al. Grafting nanometer metal/oxide interface towards enhanced low-temperature acetylene semi-hydrogenation[J]. Nature Communications, 2021, 12: 5770
[15] JIANG X, TANG L, DONG L, et al. Cu single-atom catalysts for high-selectivity electrocatalytic acetylene semihydrogenation[J]. Angewandte Chemie (International Ed in English), 2023, 62(33): e202307848
[16] TANG J, JIA K, ZHANG R, et al. Selective hydrogenation of alkyne by atomically precise Pd₆ nanocluster catalysts: Accurate construction of the coplanar and specific active sites[J]. ACS Catalysis, 2024, 14(4): 2463-2472
[17] CHEN M, KOU J, MA H, et al. Acceleration of the semi-hydrogenation of alkynes over an N-doped porous carbon sphere-confined ultrafine PdCu bimetallic nanoparticle catalyst[J]. Physical Chemistry Chemical Physics: PCCP, 2023, 25(5): 4201-4210
[18] MA J, XING F, SHIMIZU K I, et al. Active site tuning based on pseudo-binary alloys for low-temperature acetylene semihydrogenation[J]. Chemical Science, 2024, 15(11): 4086-4094
[19] SONG J, CAI X, CHEN Z, et al. Expedient alkyne semi-hydrogenation by using a bimetallic AgCu-C₃N₄ single atom catalyst[J]. Chemical Science, 2024, 15(27): 10577-10584
[20] LI S, LI J, WANG X, et al. Energizing co active sites via d-band center engineering in CeO₂-Co₃O₄ heterostructures: Interfacial charge transfer enabling efficient nitrate electrosynthesis[J]. Small, 2024, 20(27): 2311124
[21] LI J J, GUO Y, CHANG S, et al. Pairing d-band center of metal sites with π-orbital of alkynes for efficient electrocatalytic alkyne semi-hydrogenation[J]. Small, 2023, 19(5): 2205845
[22] BOLARINWA AYODELE O, VINATI S, BARBORINI E, et al. Selectivity boost in partial hydrogenation of acetylene via atomic dispersion of platinum over ceria[J]. Catalysis Science & Technology, 2020, 10(22): 7471-7475
[23] XIN H, VOJVODIC A, VOSS J, et al. Effects of d-band shape on the surface reactivity of transition-metal alloys[J]. Physical Review B, 2014, 89(11): 115114
[24] YU T, DING R, QUAN F, et al. Ag improves the performance of the oxygen evolution reaction by lowering the D-band center of the active site Ni[J]. International Journal of Hydrogen Energy, 2024, 51: 935-944
[25] WANG L, TIAN W, ZHANG W, et al. Boosting oxygen electrocatalytic performance of Cu atom by engineering the d-band center via secondary heteroatomic phosphorus modulation[J]. Applied Catalysis B: Environmental, 2023, 338: 123043
[26] SONG Z, CHENG C, WANG C, et al. Interstitial modification of palladium nanocubes with nitrogen atoms promotes aqueous electrocatalytic alkyne semihydrogenation[J]. ACS Materials Letters, 2023, 5(11): 3068-3073
[27] MAO S, ZHAO B, WANG Z, et al. Tuning the catalytic performance for the semi-hydrogenation of alkynols by selectively poisoning the active sites of Pd catalysts[J]. Green Chemistry, 2019, 21(15): 4143-4151
[28] WANG Y, ZHANG Y, WANG B, et al. The influence of spatial scale of active sites on the catalytic performance: Probing into C₂H₂ semi-hydrogenation on the Cu and S-modified Cu catalysts[J]. Fuel, 2022, 315: 123180
[29] LI Z, JI S, LIU Y, et al. Well-defined materials for heterogeneous catalysis: From nanoparticles to isolated single-atom sites[J]. Chemical Reviews, 2020, 120(2): 623-682
[30] GUO Y, WANG M, ZHU Q, et al. Ensemble effect for single-atom, small cluster and nanoparticle catalysts[J]. Nature Catalysis, 2022, 5: 766-776
[31] YANG B, LIU K, MA Y, et al. Incorporation of Pd single-atom sites in perovskite with an excellent selectivity toward photocatalytic semihydrogenation of alkynes[J]. Angewandte Chemie (International Ed in English), 2024: e202410394
[32] KUO C, LU Y, KOVARIK L, et al. Structure sensitivity of acetylene semi-hydrogenation on Pt single atoms and subnanometer clusters[J]. ACS Catalysis, 2019, 9(12): 11030-11041
[33] CHEN Z, CHEN Y, SHI L, et al. Directional construction of the highly stable active-site ensembles at sub-2 nm to enhance catalytic activity and selectivity[J]. Advanced Materials, 2024, 36(35): e2405733
[34] GAO R, XU J, WANG J, et al. Pd/Fe₂O₃ with electronic coupling single-site Pd-Fe pair sites for low-temperature semihydrogenation of alkynes[J]. Journal of the American Chemical Society, 2022, 144(1): 573-581
[35] LI J, SUO W, HUANG Y, et al. Mesoporous α-Al₂O₃-supported PdCu bimetallic nanoparticle catalyst for the selective semi-hydrogenation of alkynes[J]. Journal of Colloid and Interface Science, 2023, 652: 1053-1062
[36] LIU K, QIN R, ZHOU L, et al. Cu₂O-supported atomically dispersed Pd catalysts for semihydrogenation of terminal alkynes: Critical role of oxide supports[J]. CCS Chemistry, 2019, 1(2): 207-214
[37] HE Y, FAN J, FENG J, et al. Pd nanoparticles on hydrotalcite as an efficient catalyst for partial hydrogenation of acetylene: Effect of support acidic and basic properties[J]. Journal of Catalysis, 2015, 331: 118-127
[38] PASUPULETY N, DAOUS M A, AL-ZAHRANI A A, et al. Alumina-boron catalysts for oxidative dehydrogenation of ethylbenzene to styrene: Influence of alumina-boron composition and method of preparation on catalysts properties[J]. Chinese Journal of Catalysis, 2019, 40(11): 1758-1765
[39] YANG Z, LI Y, CAO Y, et al. Al₂O₃ microrods supported Pd catalysts for semi-hydrogenation of acetylene: Acidic properties tuned reaction kinetics behaviors[J]. Chemical Engineering Journal, 2022, 445: 136681
[40] WU Y, LU X, CUI P, et al. Enhancing alkyne semi-hydrogenation through engineering metal-support interactions of Pd on oxides[J]. Nano Research, 2024, 17(5): 3707-3713
[41] XIONG J, MAO S, LUO Q, et al. Mediating trade-off between activity and selectivity in alkynes semi-hydrogenation via a hydrophilic polar layer[J]. Nature Communications, 2024, 15: 1228
[42] YURPALOVA D V, AFONASENKO T N, PROSVIRIN I P, et al. Selective hydrogenation of acetylene over Pd-Co/C catalysts: The modifying effect of cobalt[J]. Catalysts, 2023, 13(4): 739
[43] GLUHOI A C, BAKKER J W, NIEUWENHUYS B E. Gold, still a surprising catalyst: Selective hydrogenation of acetylene to ethylene over Au nanoparticles[J]. Catalysis Today, 2010, 154(1/2): 13-20
[44] TAKETOSHI A, HARUTA M. Size- and structure-specificity in catalysis by gold clusters[J]. Chemistry Letters, 2014, 43(4): 380-387
[45] SONG X, PAN W, SHAO F, et al. Effect of the Al₂O₃ crystal phase on the supported Pd performance of semihydrogenation alkynes[J]. Industrial & Engineering Chemistry Research, 2023, 62(51): 21942-21949
[46] ZHOU H, LI B, ZHANG Y, et al. Au³⁺ species boost the catalytic performance of Au/ZnO for the semi-hydrogenation of acetylene[J]. ACS Applied Materials & Interfaces, 2021, 13(34): 40429-40440
[47] BENAVIDEZ A D, BURTON P D, NOGALES J L, et al. Improved selectivity of carbon-supported palladium catalysts for the hydrogenation of acetylene in excess ethylene[J]. Applied Catalysis A: General, 2014, 482: 108-115
[48] MA L, JIANG P, WANG K, et al. Phosphorus and nitrogen-doped palladium nanomaterials support on coral-like carbon materials as the catalyst for semi-hydrogenation of phenylacetylene and mechanism study[J]. Journal of Alloys and Compounds, 2021, 868: 159047
[49] ZONG L, FAN K, WU W, et al. Anchoring single copper atoms to microporous carbon spheres as high-performance electrocatalyst for oxygen reduction reaction[J]. Advanced Functional Materials, 2021, 31(41): 2104864
[50] LI J, JIAO L, WEGENER E, et al. Evolution pathway from iron compounds to Fe₁(II)-N₄ sites through gas-phase iron during pyrolysis[J]. Journal of the American Chemical Society, 2020, 142(3): 1417-1423
[51] LI S, YUE G, LI H, et al. Pd single atom stabilized on multiscale porous hollow carbon fibers for phenylacetylene semi-hydrogenation reaction[J]. Chemical Engineering Journal, 2023, 454: 140031
[52] LIU J, JIAO M, MEI B, et al. Carbon-supported divacancy-anchored platinum single-atom electrocatalysts with superhigh Pt utilization for the oxygen reduction reaction[J]. Angewandte Chemie (International Ed in English), 2019, 58(4): 1163-1167
[53] WANG X, JIA Y, MAO X, et al. Edge-rich Fe-N₄ active sites in defective carbon for oxygen reduction catalysis[J]. Advanced Materials, 2020, 32(16): e2000966
[54] HUANG F, DENG Y, CHEN Y, et al. Anchoring Cu₁ species over nanodiamond-graphene for semi-hydrogenation of acetylene[J]. Nature Communications, 2019, 10: 4431
[55] MA M, CHENG X, SHI Z, et al. Role of N in transition-metal-nitrides for anchoring platinum-group metal atoms toward single-atom catalysis[J]. Small Methods, 2022, 6(7): 2200295
[56] LI X, LI X. Efficient electronic state regulation engineering on Pd single atom by the defect engineering of the BN support for acetylene semi-hydrogenation[J]. Molecular Catalysis, 2024, 564: 114324
[57] CHAN C, MAHADI A H, LI M, et al. Interstitial modification of palladium nanoparticles with boron atoms as a green catalyst for selective hydrogenation[J]. Nature Communications, 2014, 5: 5787
[58] BVCHELE S, CHEN Z, FAKO E, et al. Carrier-induced modification of palladium nanoparticles on porous boron nitride for alkyne semi-hydrogenation[J]. Angewandte Chemie (International Ed in English), 2020, 59(44): 19639-19644
[59] ZHAO E, LI M, XU B, et al. Transfer hydrogenation with a carbon-nitride-supported palladium single-atom photocatalyst and water as a proton source[J]. Angewandte Chemie (International Ed in English), 2022, 61(40): e202207410
[60] JIA T, MENG D, DUAN R, et al. Single-atom nickel on carbon nitride photocatalyst achieves semihydrogenation of alkynes with water protons via monovalent nickel[J]. Angewandte Chemie (International Ed in English), 2023, 62(9): e202216511
[61] LI X, PAN Y, YI H, et al. Mott-schottky effect leads to alkyne semihydrogenation over Pd-Nanocube@N-doped carbon[J]. ACS Catalysis, 2019, 9(5): 4632-4641
[62] HU Y, ZHANG S, ZHANG Z, et al. Enhancing photocatalytic-transfer semi-hydrogenation of alkynes over Pd/C₃N₄ through dual regulation of nitrogen defects and the mott-schottky effect[J]. Advanced Materials, 2023, 35(41): e2304130
[63] LIU L, CORMA A. Confining isolated atoms and clusters in crystalline porous materials forcatalysis[J]. Nature Reviews Materials, 2021, 6: 244-263
[64] GUO Q, WANG Z, FENG X, et al. Generation and stabilization of a dinickel catalyst in a metal-organic framework for selective hydrogenation reactions[J]. Angewandte Chemie, 2023, 135(35): 2306905
[65] SHEN Y, PAN T, WU P, et al. Regulating electronic status of platinum nanoparticles by metal-organic frameworks for selective catalysis[J]. CCS Chemistry, 2021, 3(5): 1607-1614
[66] YANG D, GATES B C. Catalysis by metal organic frameworks: Perspective and suggestions for future research[J]. ACS Catalysis, 2019, 9(3): 1779-1798
[67] GANAI A, SARKAR P. Unraveling the role of single-atom catalysts immobilized onto metal-organic frameworks in selective acetylene hydrogenation: An implementation of the active site isolation strategy[J]. The Journal of Physical Chemistry C, 2024, 128(19): 7913-7925
[68] MANCUSO J L, MROZ A M, LE K, et al. Electronic structure modeling of metal-organic frameworks[J]. Chemical Reviews, 2020, 120(16): 8641-8715
[69] CHEN Y, GAO R, JI S, et al. Atomic-level modulation of electronic density at cobalt single-atom sites derived from metal-organic frameworks: Enhanced oxygen reduction performance[J]. Angewandte Chemie (International Ed in English), 2021, 60(6): 3212-3221
[70] HU Y, DAI L, LIU D, et al. Progress & prospect of metal-organic frameworks (MOFs) for enzyme immobilization (enzyme/MOFs)[J]. Renewable and Sustainable Energy Reviews, 2018, 91: 793-801
[71] CHOE K, ZHENG F, WANG H, et al. Fast and selective semihydrogenation of alkynes by palladium nanoparticles sandwiched in metal-organic frameworks[J]. Angewandte Chemie (International Ed in English), 2020, 59(9): 3650-3657
[72] VERMA R, TYAGI R, VOORA V K, et al. Black gold-based "antenna-reactor" to activate non-plasmonic nickel: Photocatalytic hydrodechlorination and hydrogenation reactions[J]. ACS Catalysis, 2023, 13(11): 7395-7406
[73] JIA T, MENG D, JI H, et al. Visible-light-driven semihydrogenation of alkynes via proton reduction over carbon nitride supported nickel[J]. Applied Catalysis B: Environmental, 2022, 304: 121004
[74] HU X, WANG G, QIN C, et al. Ligandless nickel-catalyzed transfer hydrogenation of alkenes and alkynes using water as the hydrogen donor[J]. Organic Chemistry Frontiers, 2019, 6(15): 2619-2623
[75] FOUCHER A C, NGAN H T, SHIRMAN T, et al. Influence of Pd concentration in Au-Pd nanoparticles for the hydrogenation of alkynes[J]. ACS Applied Nano Materials, 2023, 6(24): 22927-22938
[76] ALAMI M, HAMZE A, PROVOT O. Hydrostannation of alkynes[J]. ACS Catalysis, 2019, 9(4): 3437-3466
[77] WANG B, LANTERNA A E, SCAIANO J C. Mechanistic insights on the semihydrogenation of alkynes over different nanostructured photocatalysts[J]. ACS Catalysis, 2021, 11(7): 4230-4238
[78] SHIBUYA M, OKAMOTO M, FUJITA S, et al. Boron-catalyzed double hydrofunctionalization reactions of unactivated alkynes[J]. ACS Catalysis, 2018, 8(5): 4189-4193
[79] KANG Z, WANG Y, LIU B, et al. Experimental study and modeling of the liquid phase hydrogenation of acetylene[J]. Chemical Engineering Journal, 2024, 491: 151755
[80] GLYZDOVA D V, AFONASENKO T N, KHRAMOV E V, et al. Liquid-phase acetylene hydrogenation over Ag-modified Pd/Sibunit catalysts: Effect of Pd to Ag molar ratio[J]. Applied Catalysis A: General, 2020, 600: 117627
[81] ZHU S, LV Z, JIA X, et al. Pd nanoflakes epitaxially grown on defect MoS₂ nanosheets for enhanced nitroarenes hydrogenation to anilines[J]. Applied Catalysis B: Environment and Energy, 2024, 351: 123958
[82] ZHU Q, LU X, JI S, et al. Fully exposed cobalt nanoclusters anchored on nitrogen-doped carbon synthesized by a host-guest strategy for semi-hydrogenation of phenylacetylene[J]. Journal of Catalysis, 2022, 405: 499-507
[83] LONG W, BRUNELLI N A, DIDAS S A, et al. Aminopolymer-silica composite-supported Pd catalysts for selective hydrogenation of alkynes[J]. ACS Catalysis, 2013, 3(8): 1700-1708
[84] XING Y, SU Y, LI L, et al. Air-stable and reusable porous silica-supported ultrafine Ni_x-NiO nanoparticles for semi-hydrogenation of alkynes[J]. Applied Surface Science, 2024, 654: 159411
[85] ZHAO L, QIN X, ZHANG X, et al. A magnetically separable Pd single-atom catalyst for efficient selective hydrogenation of phenylacetylene[J]. Advanced Materials, 2022, 34(20): e2110455
[86] ZHANG L, LIN J, LIU Z, et al. Non-noble metal-based catalysts for acetylene semihydrogenation: From thermocatalysis to sustainable catalysis[J]. Science China Chemistry, 2023, 66(7): 1963-1974
[87] LI N, WENG S, MCCUE A J, et al. Metal-organic framework-derived Ni-S/C catalysts for selective alkyne hydrogenation[J]. ACS Applied Materials & Interfaces, 2023, 15(41): 48135-48146
[88] XU J, HUANG W, LI R, et al. Potassium regulating electronic state of zirconia supported palladium catalyst and hydrogen spillover for improved acetylene hydrogenation[J]. Journal of Colloid and Interface Science, 2024, 655: 584-593
[89] HUANG R, XIA M, ZHANG Y, et al. Acetylene hydrogenation to ethylene by water at low temperature on a Au/α-MoC catalyst[J]. Nature Catalysis, 2023, 6: 1005-1015
[90] LI Z, ZHANG J, TIAN J, et al. Decoupling active sites enables low-temperature semihydrogenation of acetylene[J]. ACS Catalysis, 2024, 14(3): 1514-1524
[91] ZHAO Y, BOZKURT Ö D, KURTO?LU-ÖZTULUM S F, et al. Atomically dispersed zeolite-supported rhodium complex: Selective and stable catalyst for acetylene semi-hydrogenation[J]. Journal of Catalysis, 2024, 429: 115196
[92] LV J, WANG D, GUO X, et al. Selective hydrogenation of phenylacetylene over high-energy facets exposed nanotubular alumina supported palladium catalysts[J]. Catalysis Communications, 2023, 181: 106715
[93] DELIMA R S, STANKOVIC M D, MACLEOD B P, et al. Selective hydrogenation of furfural using a membrane reactor[J]. Energy & Environmental Science, 2022, 15(1): 215-224
[94] WAN Q, ZHANG J, LIU X, et al. Metal-support interaction triggered d-p orbital hybridization for efficient electrocatalytic semi-hydrogenation of alkynes[J]. Journal of Materials Chemistry A, 2024, 12(19): 11625-11634
[95] LIN X, HU F, LI Q, et al. Electron divergence of Cu^δ- and Pd^δ+ in Cu₃Pd alloy-based heterojunctions boosts concerted C≡C bond binding and the Volmer step for alkynol semihydrogenation[J]. Journal of the American Chemical Society, 2024, 146(27): 18451-18458
[96] WANG G, LI Y, ZHU W, et al. Efficient electrocatalytic alkyne semi-hydrogenation and deuteration using Pd/PANI catalysts supported on nickel foam[J]. Chemical Engineering Journal, 2024, 489: 151271
[97] TAN Q, LI L, LI Y, et al. Tandem electrocatalytic alkyne semihydrogenation over bicomponent catalysts through hydrogen spillover[J]. Angewandte Chemie (International Ed in English), 2024, 63(15): e202400483
[98] LING Y, WU Y, WANG C, et al. Selenium vacancy promotes transfer semihydrogenation of alkynes from water electrolysis[J]. ACS Catalysis, 2021, 11(15): 9471-9478
[99] LUO D, XIE Z, CHEN S, et al. Enhancing electrocatalytic semihydrogenation of alkynes via weakening alkene adsorption over electron-depleted Cu nanowires[J]. ACS Nanoscience Au, 2024, doi: 10.1021/acsnanoscienceau.4c00030
[100] REN Q, HAO L, YANG J, et al. Promoting electrocatalytic semihydrogenation of alkynols to alkenols over a bimetallic CuAu alloy catalyst[J]. ACS Catalysis, 2024, 14(8): 5675-5684
[101] LIN X, LI Q, XIA S, et al. Enrichment of polarized alkynes over negatively charged Pt for efficient electrocatalytic semihydrogenation[J]. ACS Catalysis, 2024, 14(4): 2173-2180
[102] CHEN F, LI L, CHENG C, et al. Ethylene electrosynthesis from low-concentrated acetylene via concave-surface enriched reactant and improved mass transfer[J]. Nature Communications, 2024, 15: 5914
[103] WANG Z, LI C, PENG G, et al. Highly selective acetylene-to-ethylene electroreduction over Cd-decorated Cu catalyst with efficiently inhibited carbon-carbon coupling[J]. Angewandte Chemie (International Ed in English), 2024, 63(19): e202400122
[104] SONG X, SHAO F, ZHAO Z, et al. Single-atom Ni-modified Al₂O₃-supported Pd for mild-temperature semi-hydrogenation of alkynes[J]. ACS Catalysis, 2022, 12(24): 14846-14855
[105] LI M, ZHANG N, LONG R, et al. PdPt alloy nanocatalysts supported on TiO₂: Maneuvering metal-hydrogen interactions for light-driven and water-donating selective alkyne semihydrogenation[J]. Small, 2017, 13(23): 1604173
[106] YU H, XING J, CHEN Z, et al. Unidirectional suppression of hydrogen oxidation on oxidized platinum clusters[J]. Nature Communications, 2013, 4: 2500
[107] SU K, WANG Y, ZHANG C, et al. Tuning the Pt species on Nb₂O₅ by support-induced modification in the photocatalytic transfer hydrogenation of phenylacetylene[J]. Applied Catalysis B: Environmental, 2021, 298: 120554
[108] WANG Z, WANG H, SHI Y, et al. CuPd alloy decorated SnNb₂O₆ nanosheets as a multifunctional photocatalyst for semihydrogenation of phenylacetylene under visible light[J]. Chemical Engineering Journal, 2022, 429: 132018
[109] LI X, WANG R, ZHANG J, et al. Selective hydrogenation of phenylacetylene over TiO₂ supported Ni₂P nanoparticles under visible light irradiation[J]. Catalysis Science & Technology, 2023, 13(22): 6519-6526
[110] LIAN J, CHAI Y, QI Y, et al. Unexpectedly selective hydrogenation of phenylacetylene to styrene on titania supported platinum photocatalyst under 385 nm monochromatic light irradiation[J]. Chinese Journal of Catalysis, 2020, 41(4): 598-603
[111] TAN C, CAO X, WU X, et al. Recent advances in ultrathin two-dimensional nanomaterials[J]. Chemical Reviews, 2017, 117(9): 6225-6331
[112] ZHANG S, GUO S, CHEN Z, et al. Recent progress in 2D group-VA semiconductors: From theory to experiment[J]. Chemical Society Reviews, 2018, 47(3): 982-1021
[113] MATEO D, MORLANES N, MAITY P, et al. Efficient visible-light driven photothermal conversion of CO₂ to methane by nickel nanoparticles supported on Barium titanate[J]. Advanced Functional Materials, 2021, 31(8): 2008244
[114] WANG J, WANG M, LI X, et al. Bidentate ligand modification strategy on supported Ni nanoparticles for photocatalytic selective hydrogenation of alkynes[J]. Applied Catalysis B: Environmental, 2022, 313: 121449
[115] GUO Y, HUANG Y, ZENG B, et al. Photo-thermo semi-hydrogenation of acetylene on Pd₁/TiO₂ single-atom catalyst[J]. Nature Communications, 2022, 13: 2648