二氧化碳驱油技术中CO<sub>2</sub>膨胀液体黏度研究进展

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摘要全球变暖日益引起各国关注,CO₂ (Carbon dioxide)被认为是最主要的温室气体,我国已向国际社会做出了"双碳"庄严承诺。CO₂-EOR (CO₂ enhanced oil recovery)技术将捕集来的CO₂注入油藏中不仅可以使原油膨胀,降低原油黏度,增强原油流动性从而提升驱油效率,同时还可以减少CO₂排放,具有非常重要的战略价值。因此,研究CO₂膨胀液体(CO₂-expanded liquids, CXLs)的机理及其传递特性对于CO₂-EOR技术的利用具有重要意义。从实验设备、实验数据以及计算模型3个方面综述了CO₂-EOR技术中涉及的CO₂膨胀液体黏度的发展现状,并对其发展趋势进行归纳。在实验设备方面,表面光散射等非接触式黏度测量方法越来越受到关注;在实验数据研究方面,CO₂-正癸烷、CO₂-正十四烷二元体系数据较为丰富,而CO₂-正构烷烃多元体系、CO₂-环烷烃、CO₂-芳香烃及CO₂-助溶剂体系的数据还比较欠缺;在计算模型方面,综述了适用于CO₂-膨胀液体黏度的Eyring半理论模型的基本原理和研究进展,对不同类型的模型计算精度进行了综合比较。

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	方媛
	高亚慧
	宫艳玲
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关键词： CO₂-膨胀液体 CO₂-EOR 黏度

Abstract： The global warming issue caused by the greenhouse effect has attracted much attention over the past few years. Carbon dioxide (CO₂) is considered the most important greenhouse gas. China has committed to the international community to reach carbon peaking and carbon neutrality goals. The CO₂-EOR (CO₂ enhanced oil recovery) technology can not only reduce CO₂ emissions, but also expand the crude oil, reduce the viscosity of the crude oil, and enhance the fluidity of the crude oil to improve the oil recovery efficiency. Therefore, a full understanding of the transfer characteristics of CO₂-expanded liquids (CXLs) is very important for the utilization of CO₂-EOR technology. This paper provides a literature review of the research on the viscosity of carbon dioxide expanded liquids systems, including the experiment equipment, experimental data, and calculation models. The non-contact viscosity measurement methods such as surface light scattering have recently attracted more attention. And, there were many available experimental data for the CO₂-n-decane and CO₂-n-tetradecane binary systems while few data for CO₂-n-alkane multi-system, CO₂-cycloalkane, CO₂-aromatic hydrocarbon, and CO₂-cosolvent systems. This paper also describes the use of Eyring’s absolute reaction theory for calculating the viscosity of CXLs.

Keywords： CO₂-expanded liquids CO₂ enhanced oil recovery viscosity

Received 2022-01-18;

Fund:国家重点研发计划项目(2016YFB0600804-3)。

Corresponding Authors: 夏淑倩,教授,E-mail:shuqianxia@tju.edu.cn。 Email: shuqianxia@tju.edu.cn

About author: 方媛(1996-),女,硕士研究生,现从事CO₂驱油技术中CO₂-原油组分黏度的实验测定及计算方面的研究。

引用本文:

方媛, 高亚慧, 宫艳玲, 夏淑倩.二氧化碳驱油技术中CO₂膨胀液体黏度研究进展[J]. 化学工业与工程, 2024,41(1): 90-102

FANG Yuan, GAO Yahui, GONG Yanling, XIA Shuqian.A review of the viscosity of carbon dioxide expanded liquids in enhanced oil recovery[J]. Chemcial Industry and Engineering, 2024,41(1): 90-102

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