负载金属沸石去除水中污染物的研究进展

摘要近年来，沸石在污水处理领域得到了广泛的应用。但由于沸石的孔径小，通道易堵塞，对污染物的去除效果不理想，其吸附能力往往达不到要求。为了进一步提高沸石的离子交换、吸附等性能，从而提高对水中污染物的去除效率，须对沸石进行处理。简述了Fe、Mn、Cu、Ag、Ce、Al、La、Zn、Na和Ti 10种金属在天然沸石上的负载方法，前9种金属的负载方法主要是浸渍法，最后1种主要是溶胶-凝胶法。综述了经10种金属负载后的天然沸石对药物、染料废水、重金属、含酚废水、氨氮和挥发性有机物等污染物的去除情况和去除机理。同时，对负载型沸石在废水处理中的进一步发展提出了一定的看法和思考。

	Service

	把本文推荐给朋友
	加入我的书架
	加入引用管理器
	Email Alert
	RSS
	作者相关文章
	徐乃姣
	冯丽娟
	王济
	李森

关键词：沸石负载方法污染物去除机理

Abstract： Zeolite has been widely used in wastewater treatment in recent years. However, because of the small pore size, easy block of the channel, unideal removal effect of pollutants,the adsorption capacity of zeolite is often not up to the requirements. In order to further improve the properties of ion exchange and adsorption of zeolite and thus improve the removal efficiency of pollutants in water, it is necessary to treat zeolite. The loading methods of Fe, Mn, Cu, Ag, Ce, Al, La, Zn, Na and Ti on natural zeolite are introduced briefly. The loading methods of the first nine metals are mainly impregnation method, and the last one is sol-gel method. The removal mechanism of natural zeolite loaded with ten metals on drugs, dye wastewater, heavy metals, phenol wastewater, ammonia nitrogen, volatile organic compounds and other pollutants is reviewed. At the same time, the further development of loaded zeolite in wastewater treatment is discussed.

Keywords： zeolite loading methods contaminant removal mechanism

Received 2020-10-19;

Fund:贵州省基础研究计划基金资助项目（黔科合基础[2017]1123）；贵州省科技合作计划基金资助项目（黔科合LH字[2016]7215）；贵州省普通高等学校青年科技人才成长项目（黔教合KY字[2021]300）。

Corresponding Authors: 冯丽娟,E-mail:feng_lijuan@163.com。 Email: feng_lijuan@163.com

About author: 徐乃姣(1995-),女,硕士研究生,现从事环境污染机理及控制技术方面的研究。

引用本文:

徐乃姣, 冯丽娟, 王济, 李森.负载金属沸石去除水中污染物的研究进展[J]. 化学工业与工程, 2021,38(5): 67-79

Xu Naijiao, Feng Lijuan, Wang Ji, Li Sen.Progress of Loading Metal on Zeolite to Remove Pollutants in Water[J]. Chemcial Industry and Engineering, 2021,38(5): 67-79

[1] 柳婷婷, 张寿庭. 我国沸石资源的分布与开发利用及发展方向[J]. 中国矿业, 2011, 20(S1):41-45 Liu Tingting, Zhang Shouting. Distribution, utilization and development directions of the zeolite resources nationwide[J]. China Mining Magazine, 2011, 20(S1):41-45(in Chinese)
[2] 党瑞. 天然及改性沸石去除水中磷的试验研究[D]. 兰州:兰州交通大学, 2015 Dang Rui. Experimental study on removing phosphorus by natural and modified zeolite[D]. Lanzhou:Lanzhou Jiatong University, 2015(in Chinese)
[3] 周元. 天然沸石负载Pt催化剂的HCHO室温催化氧化研究[D]. 昆明:昆明理工大学,2017 Zhou Yuan. Catalytic oxidation of natural zeolite supported Pt catalyst by HCHO at room temperature[D]. Kunming:Kunming University of Science and Technology, 2017(in Chinese)
[4] 朱子俊. 金属改性沸石分子筛的甲苯吸附性能研究[D]. 昆明:昆明贵金属研究所,2019 Zhu Zijun. Toluene adsorption properties of metal modified zeolite[D]. Kunming:Kunming Institute of Precious Metals, 2019(in Chinese)
[5] 贾艳明, 马慧, 王俊文, 等. 金属改性HZSM-5分子筛催化甲醇制芳烃反应性能研究[J]. 天然气化工, 2019, 44(3):7-11,26 Jia Yanming, Ma Hui, Wang Junwen, et al. Conversion of methanol to aromatics over metal-modified HZSM-5 zeolites[J]. Natural Gas Chemical Industry, 2019, 44(3):7-11,26(in Chinese)
[6] Ayoub H, Roques-Carmes T, Potier O, et al. Iron-impregnated zeolite catalyst for efficient removal of micropollutants at very low concentration from Meurthe river[J]. Environmental Science and Pollution Research, 2018, 25(35):34950-34967
[7] Yan Y, Jiang S, Zhang H, et al. Preparation of novel Fe-ZSM-5 zeolite membrane catalysts for catalytic wet peroxide oxidation of phenol in a membrane reactor[J]. Chemical Engineering Journal, 2015, 259:243-251
[8] Tan P. Active phase, catalytic activity, and induction period of Fe/zeolite material in nonoxidative aromatization of methane[J]. Journal of Catalysis, 2016, 338:21-29
[9] 李大群, 蒋进元, 周岳溪, 等. 载铁沸石催化H₂O₂降解阳离子红X-GRL染料废水[J]. 环境工程技术学报, 2013, 3(5):391-397 Li Daqun, Jiang Jinyuan, Zhou Yuexi, et al. Degradation of cationic red X-GRL dye wastewater with H₂O₂ catalyzed by Fe-containing zeolite[J]. Journal of Environmental Engineering Technology, 2013, 3(5):391-397(in Chinese)
[10] 张舒. 负载型过渡金属氧化物催化剂在海水烟气脱硫中的应用基础研究[D]. 山东青岛:中国海洋大学, 2011 Zhang Shu. The fundamental study on supported transition metal oxides catalyst for seawater flue gas desulfurization application[D]. Shandong Qingdao:Ocean University of China, 2011(in Chinese)
[11] 何昭露, 刘真意, 罗诚, 等. 铁改性斜发沸石的制备及吸附Sb(Ⅲ)效果研究[J]. 非金属矿, 2018, 41(4):13-16 He Zhaolu, Liu Zhenyi, Luo Cheng, et al. Preparation of iron modified clinoptilolite and its adsorption results of Sb(Ⅲ)[J]. Non-Metallic Mines, 2018, 41(4):13-16(in Chinese)
[12] 刘爱平, 黄阳, 王维清, 等. 铁改性斜发沸石的制备及吸附Sb(Ⅴ)效果研究[J]. 矿物岩石, 2018, 38(2):7-12 Liu Aiping, Huang Yang, Wang Weiqing, et al. Preparation of iron mdified clinoptilolite and its adsorption results on Sb(Ⅴ)[J]. Journal of Mineralogy and Petrology, 2018, 38(2):7-12(in Chinese)
[13] 马江雁. 锰氧化物改性沸石(MOCZ)对罗丹明B和4-氯苯酶的吸附研究[D]. 郑州:郑州大学, 2010 Ma Jiangyan. Study of biosorption of rhodamine B and p-chlorophenol from the aqueous solutions by manga-nese oxide coated zeolite (MOCZ)[D]. Zhengzhou:Zhengzhou University, 2010(in Chinese)
[14] deMello M I S, Sobrinho E V, daSilva V L S T, et al. V or Mn zeolite catalysts for the oxidative desulfurization of diesel fractions using dibenzothiophene as a probe molecule:Preliminary study[J]. Molecular Catalysis, 2020, 482:1-9
[15] 赵波, 尹琳, 卢保奇, 等. Cu-丝光沸石/臭氧催化-坡缕石联用工艺降解染料污水的初步研究[J]. 中国非金属矿工业导刊, 2004,(5):48-49,65 Zhao Bo, Yin Lin, Lu Baoqi, et al. A preliminary study on the degradation of dye wastewater by cu-mercerite/ozone-catalyzed palygorskite[J]. China Non-Metallic Mining Industry Herald, 2004,(5):48-49,65(in Chinese)
[16] Brazlauskas M, Kitrys S. Synthesis and properties of CuO/zeolite sandwich type adsorbent-catalysts[J]. Chinese Journal of Catalysis, 2008, 29(1):25-30
[17] 李菲菲, 桂兴华, 刘道胜, 等. 乙烯在丝光沸石和改性丝光沸石孔道内的吸附行为[J]. 物理化学学报, 2008, 24(4):659-664 Li Feife, Gui Xinghua, Liu Daosheng, et al. Ethene adsorption on mordenite and modified mordenite[J]. Acta Physico-Chimica Sinica, 2008, 24(4):659-664(in Chinese)
[18] 朱云华, 丁磊, 钟梅英, 等. 载银沸石吸附去除水中溴离子的特性研究[J]. 硅酸盐通报, 2015, 34(7):1857-1863 Zhu Yunhua, Ding Lei, Zhong Meiying, et al. Adsorption properties of bromide from aqueous solutions using silver-loaded zeolite[J]. Bulletin of the Chinese Ceramic Society, 2015, 34(7):1857-1863(in Chinese)
[19] 刘耀兴, 郭会超, 欧阳通, 等. 水合氧化铈负载沸石对含磷废水的深度处理[J]. 集美大学学报:自然科学版, 2009, 14(2):131-136 Liu Yaoxing, Guo Huichao, Ouyang Tong, et al. Phosphorus removal using hydrous ceric oxide impregnated zeolite HCO-MZ[J]. Journal of Jimei University:Natural Science, 2009, 14(2):131-136(in Chinese)
[20] 任越中, 张嘉雯, 魏健, 等. 铈负载改性天然沸石催化臭氧氧化水中青霉素G[J]. 环境工程技术学报, 2019, 9(1):28-35 Ren Yuezhong, Zhang Jiawen, Wei Jian, et al. Catalytic ozonation of penicillin G in aqueous phase using modified natural zeolite supported cerium[J]. Journal of Environmental Engineering Technology, 2019, 9(1):28-35(in Chinese)
[21] 杨维, 李世良, 杨肖肖, 等. 沸石的载铈改性及其用于含氟水除氟的试验[J]. 沈阳建筑大学学报:自然科学版, 2013, 29(1):144-149 Yang Wei, Li Shiliang, Yang Xiaoxiao, et al. An experiment on zeolite modified by cerium and its use for fluoride removal from drinking water[J]. Journal of Shenyang Jianzhu University Natural Science, 2013, 29(1):144-149(in Chinese)
[22] 游新国, 张晓宁. Al改性沸石的制备及对含氟水的处理效果[J]. 辽宁化工, 2011, 40(3):221-224,229 You Xinguo, Zhang Xiaoning. Preparation of Al-modified zeolite and its treatment effect on fluorinated water[J]. Liaoning Chemical Industry, 2011, 40(3):221-224,229(in Chinese)
[23] 李冰川, 马志军. 载铝改性沸石除氟的热力学和动力学机理研究[J]. 硅酸盐通报, 2015, 34(2):370-375 Li Bingchuan, Ma Zhijun. Study on the thermodynamics and kinetics of removing fluoride of zeolite modified by Al(Ⅲ)[J]. Bulletin of the Chinese Ceramic Society, 2015, 34(2):370-375(in Chinese)
[24] 林海, 贾小宇, 郭丽丽. 沸石除磷复合吸附剂的制备及其性能研究[J]. 金属矿山, 2010(10):154-158 Lin Hai, Jia Xiaoyu, Guo Lili. Preparation of compounded adsorption of phosphorus removal with zeolite and its performance[J]. Metal Mine, 2010(10):154-158(in Chinese)
[25] 邓书平. 沸石负载稀土元素镧吸附处理含镉废水试验[J]. 中国非金属矿工业导刊, 2015(2):25-27 Deng Shuping. Study on adsorption treatment of wastewater containing cadmium with zeolite carried rare earth elements lanthanum[J]. China Non-Metallic Mining Industry, 2015(2):25-27(in Chinese)
[26] 崔有为, 李杰, 杜兆富. 镧、铈改性沸石对污水除磷性能和机制的比较研究[J]. 中国稀土学报, 2016, 34(4):460-468 Cui Youwei, Li Jie, Du Zhaofu. Comparative study of performance and mechanism of lanthanum and cerium modified zeolite on phosphorus removal in wastewater[J]. Journal of the Chinese Rare Earth Society, 2016, 34(4):460-468(in Chinese)
[27] 吕郭栋. 纳米氧化锌改性沸石对废水中重金属离子去除特性的研究[D]. 西安:西安建筑科技大学, 2018 Lü Guodong. Study on removal characteristics of heavy metal ions from wastewater by nano-ZnO modified zeolite[D]. Xi'an:Xi'an University of Architecture and Technology, 2018(in Chinese)
[28] 王玲玲, 郭佳莉, 肖春妹, 等. Zn²⁺改性丝光沸石对甲基橙的吸附性能研究[J]. 矿物学报, 2011, 31(2):284-290 Wang Lingling, Guo Jiali, Xiao Chunmei, et al. Methyl orange adsorption by Zn²⁺ exchanged mordenite[J]. Acta Mineralogica Sinica, 2011, 31(2):284-290(in Chinese)
[29] 程治化. 改性沸石吸附去除氨氮及再生研究[D]. 北京:北京化工大学, 2014 Cheng Zhihua. Study on ammonia nitrogen removal and regeneration by adsorption of modified zeolite[D]. Beijing:Beijing University of Chemical Technology, 2014(in Chinese)
[30] 杨敏, 柯俊锋, 何晓曼, 等. 氢氧化钠改性沸石对水中Cu²⁺的吸附特性研究[J]. 环境污染与防治, 2017, 39(3):314-318 Yang Min, Ke Junfeng, He Xiaoman, et al. Adsorption of Cu²⁺ in aqueous solution by sodium hydroxide modified zeolite[J]. Environmental Pollution and Control, 2017, 39(3):314-318(in Chinese)
[31] 方送生, 蒋引珊, 王安平, 等. TiO₂改性天然沸石的光催化性能[J]. 非金属矿, 2004, 27(1):14-16 Fang Songsheng, Jiang Yinshan, Wang Anping, et al. Photocatalysis properties of natural zeolite modified by TiO₂[J]. Non-Metallic Mines, 2004, 27(1):14-16(in Chinese)
[32] 李琰, 吕静, 李春静, 等. 沸石负载TiO₂光催化剂的制备及光催化降解染料废水的研究[J]. 工业水处理, 2013, 33(10):56-58 Li Yan, Lü Jing, Li Chunjing, et al. Study on the preparation of the TiO₂-loaded clinoptilolite photo-catalyst and the photo-catalytic degradation of dyes wastewater[J]. Industrial Water Treatment, 2013, 33(10):56-58(in Chinese)
[33] 吕静, 李春静, 齐广辉, 等. 沸石负载TiO₂光催化降解制药废水的研究[J]. 上海化工, 2014, 39(6):1-3 Lü Jing, Li Chunjing, Qi Guanghui, et al. Study on photocatalytic degradation of pharmaceutical wastewater with TiO₂ supported on zeolite[J]. Shanghai Chemical Industry, 2014, 39(6):1-3(in Chinese)
[34] 高睿君, 吴礼丽. 沸石分子筛负载TiO₂光催化降解硝基苯研究[J]. 安徽建筑工业学院学报:自然科学版, 2011, 19(6):88-90 Gao Ruijun, Wu Lili. Study of zeolite supported TiO₂ photocatalytic degradation of nitrobenzene in aqueous solution[J]. Journal of Anhui Institute of Architecture & Industry:Natural Science, 2011, 19(6):88-90(in Chinese)
[35] 张惠灵, 张静, 刘海波, 等. 微波诱导Fe₂O₃/沸石负载型催化剂催化氧化焦化废水的研究[J]. 环境污染与防治, 2011, 33(2):69-73,78 Zhang Huiling, Zhang Jing, Liu Haibo, et al. Microwave induced oxidation of coking wastewater with Fe₂O₃/Zeolite as composite catalyst[J]. Environmental Pollution and Control, 2011, 33(2):69-73,78(in Chinese)
[36] 刘徽, 晏井春, 陈云, 等. 改性沸石负载Fe₃O₄催化H₂O₂去除亚甲基蓝染料废水[J]. 应用化工, 2016, 45(12):2207-2211, 2216 Liu Hui, Yan Jingchun, Chen Yun, et al. Degradation of methyl blue in aqueous solution by Fe₃O₄ immobilized on modified zeolite activated H₂O₂[J]. Applied Chemical Industry, 2016, 45(12):2207-2211, 2216(in Chinese)
[37] Wu Y, Yang M, Hu S, et al. Characteristics and mechanisms of 4A zeolite supported nanoparticulate zero-valent iron as Fenton-like catalyst to degrade methylene blue[J]. Toxicological & Environmental Chemistry, 2014, 96(2):227-242
[38] Rivas F J, Beltrán F J, Frades J, et al. Oxidation of p-hydroxybenzoic acid by Fenton's reagent[J]. Water Research, 2001, 35(2):387-396
[39] 张文兵, 肖贤明, 傅家谟, 等. 过氧化氢高级氧化技术去除水中有机污染物[J]. 中国给水排水, 2002, 18(3):89-92 Zhang Wenbing, Xiao Xianming, Fu Jiamo, et al. Use of H₂O₂ advanced oxidation process for removal of organic pollutants in water[J]. China Water & Wastewater, 2002, 18(3):89-92(in Chinese)
[40] de Oliveira J S, Mazutti M A, Urquieta-González E A, et al. Preparation of mesoporous Fe₂O₃-supported ZSM-5 zeolites by carbon-templating and their evaluation as photo-Fenton catalysts to degrade organic pollutant[J]. Materials Research, 2016, 19(6):1399-1406
[41] Rache M L, García A R, Zea H R, et al. Azo-dye orange II degradation by the heterogeneous Fenton-like process using a zeolite Y-Fe catalyst-Kinetics with a model based on the Fermi's equation[J]. Applied Catalysis B:Environmental, 2014, 146:192-200
[42] Bautista P, Mohedano A F, Gilarranz M A, et al. Application of Fenton oxidation to cosmetic wastewaters treatment[J]. Journal of Hazardous Materials, 2007, 143(1/2):128-134
[43] Liu R, Chiu H M, Shiau C S, et al. Degradation and sludge production of textile dyes by Fenton and photo-Fenton processes[J]. Dyes and Pigments, 2007, 73(1):1-6
[44] Li Z, Wang L, Meng J, et al. Zeolite-supported nanoscale zero-valent iron:New findings on simultaneous adsorption of Cd(Ⅱ), Pb(Ⅱ), and As(Ⅲ) in aqueous solution and soil[J]. Journal of Hazardous Materials, 2018, 344:1-11
[45] Crini G, Peindy H, Gimbert F, et al. Removal of C.I. Basic Green 4(Malachite Green) from aqueous solutions by adsorption using cyclodextrin-based adsorbent:Kinetic and equilibrium studies[J]. Separation and Purification Technology, 2007, 53(1):97-110
[46] Kanel S R, Manning B, Charlet L, et al. Removal of arsenic(Ⅲ) from groundwater by nanoscale zero-valent iron[J]. Environmental Science & Technology, 2005, 39(5):1291-1298
[47] Bissen M, Frimmel F H. Arsenic-A review. part II:Oxidation of arsenic and its removal in water treatment[J]. Acta Hydrochimica et Hydrobiologica, 2003, 31(2):97-107
[48] Mohan D, Pittman C U. Arsenic removal from water/wastewater using adsorbents:A critical review[J]. Journal of Hazardous Materials, 2007, 142(1/2):1-53
[49] 谭万春, 喻辰雪, 胡帅飞, 等. 沸石负载Fe₃O₄光催化氧化去除水中苯酚[J]. 环境工程学报, 2014, 8(6):2353-2358 Tan Wanchun, Yu Chenxue, Hu Shuaifei, et al. Removal of phenol in wastewater using Fe₃O₄-loaded zeolite with photo-catalytic oxidation[J]. Chinese Journal of Environmental Engineering, 2014, 8(6):2353-2358(in Chinese)
[50] 陆燕勤, 朱丽, 何昭菊, 等. 沸石负载氧化铁吸附剂吸附除磷研究[J]. 环境工程, 2015, 33(4):48-52 Lu Yanqin, Zhu Li, He Zhaoju, et al. Phosphorus adsorption from wastewater by iron-oxide-coated-zeolite[J]. Environmental Engineering, 2015, 33(4):48-52(in Chinese)
[51] 张小凤, 王慧玲, 徐微, 等. 沸石的载铁改性及除氟性能分析[J]. 安徽农业大学学报, 2014, 41(4):662-668 Zhang Xiaofeng, Wang Huiling, Xu Wei, et al. Modification and fluoride-adsorption capacity of natural zeolite with Fe³⁺[J]. Journal of Anhui Agricultural University, 2014, 41(4):662-668(in Chinese)
[52] 詹艳慧, 林建伟, 王虹, 等. 四氧化三铁-沸石复合材料去除水中铵和磷酸盐研究[J]. 上海海洋大学学报, 2013, 22(3):376-383 Zhan Yanhui, Lin Jianwei, Wang Hong, et al. Removal of ammonium and phosphate from aqueous solution by magnetite/zeolite composite[J]. Journal of Shanghai University, 2013, 22(3):376-383(in Chinese)
[53] 翁晴. 改性沸石在水处理中的应用[J]. 山东化工, 2014, 43(1):54-55 Weng Qing. The application of modify zeolite in water treatment[J]. Shandong Chemical Industry, 2014, 43(1):54-55(in Chinese)
[54] 武庭瑄, 周敏, 万建新, 等. 膨润土和高岭土对四环素吸附的影响[J]. 农业环境科学学报, 2009, 28(5):914-918 Wu Tingxuan, Zhou Min, Wan Jianxin, et al. Influence of montmorillonite and kaolinite on tetracycline adsorption[J]. Journal of Agro-Environment Science, 2009, 28(5):914-918(in Chinese)
[55] 沈婷,何国富,徐慧敏. 载锰沸石的制备及对四环素去除的吸附性能[J].净水技术,2015,4(4):74-79 Shen Ting, He Guofu, Xu Huimin. Reparation of manganese oxide coated zeolite and adsorptive property of tetracycline removal[J]. Water Purification Technology, 2015, 4(4):74-79(in Chinese)
[56] 刘艳鸽. 四环素/铜/镉在载锰沸石表面的吸附行为及交互作用研究[D].陕西咸阳:西北农林科技大学,2015 Liu Yange. The adsorption behavior and interaction research of tetracycline/copper/cadmium on the surface of the Mn-oxide-coated zeolite[D]. Shaanxi Xianyang:Northwest A&F University, 2015(in Chinese)
[57] Taffarel S R, Rubio J. Removal of Mn²⁺ from aqueous solution by manganese oxide coated zeolite[J]. Minerals Engineering, 2010, 23(14):1131-1138
[58] Wu K, Liu T, Xue W, et al. Arsenic(Ⅲ) oxidation/adsorption behaviors on a new bimetal adsorbent of Mn-oxide-doped Al oxide[J]. Chemical Engineering Journal, 2012, 192:343-349
[59] Samarghandi M R, Al-Musawi T J, Mohseni-Bandpi A, et al. Adsorption of cephalexin from aqueous solution using natural zeolite and zeolite coated with manganese oxide nanoparticles[J]. Journal of Molecular Liquids, 2015, 211:431-441
[60] Saha S, Pal A. Microporous assembly of MnO₂ nanosheets for malachite green degradation[J]. Separation and Purification Technology, 2014, 134:26-36
[61] 郭华, 王军林, 张小燕, 等. 沸石负载高锰酸钾去除低浓度氨氮[J]. 环境工程学报, 2015, 9(9):4321-4325 Guo Hua, Wang Junlin, Zhang Xiaoyan, et al. Low concentration ammonia nitrogen removal by modified zeolite with potassium permanganate[J]. Chinese Journal of Environmental Engineering, 2015, 9(9):4321-4325(in Chinese)
[62] 马文婕, 陈天虎, 陈冬, 等. δ-MnO₂/沸石纳米复合材料同时去除地下水中的铁锰氨氮[J]. 环境科学, 2019, 40(10):4553-4561 Ma Wenjie, Chen Tianhu, Chen Dong, et al. Removal of Fe(Ⅱ), Mn(Ⅱ), and NH₄⁺-N by using δ-MnO₂ coated zeolite[J]. Environmental Science, 2019, 40(10):4553-4561(in Chinese)
[63] 张芙蓉, 雷行, 常冰, 等. 铝锰复合氧化物负载沸石对氨氮和磷的同步吸附特性[J]. 环境工程学报, 2017, 11(4):2163-2169 Zhang Furong, Lei Hang, Chang Bing, et al. Characteristics of simultaneous adsorption of phosphate and ammonia nitrogen onto aluminum-manganese bimetal oxide coated zeolite[J]. Chinese Journal of Environmental Engineering, 2017, 11(4):2163-2169(in Chinese)
[64] 孙艳丽, 林建伟, 黄宏, 等. 天然沸石同步去除水中氨氮和磷酸盐[J]. 环境工程学报, 2012, 6(8):2470-2476 Sun Yanli, Lin Jianwei, Huang Hong, et al. Simultaneous removal of ammonium and phosphate from aqueous solution by natural zeolite[J]. Techniques and Equipment for Environmental Pollution Control, 2012, 6(8):2470-2476(in Chinese)
[65] 姜霞, 周小宁, 丁明玉, 等. 天然沸石及改性沸石去除低浓度氨氮的研究[J]. 环境科学研究, 2008, 21(5):37-42 Jiang Xia, Zhou Xiaoning, Ding Mingyu, et al. Study on low concentration ammonia nitrogen removal by natural and modified clinoptilolites[J]. Research of Environmental Sciences, 2008, 21(5):37-42(in Chinese)
[66] Wu K, Liu T, Ma C, et al. The role of Mn oxide doping in phosphate removal by Al-based bimetal oxides:Adsorption behaviors and mechanisms[J]. Environmental Science and Pollution Research, 2014, 21(1):620-630
[67] 方火明, 邓慧萍, 商冉, 等. 二氧化锰改性沸石去除水中铅的研究[J]. 安徽农业科学, 2009, 37(15):7156-7158,7161 Fang Huoming, Deng Huiping, Shang Ran, et al. Study on the removal of Pb²⁺ in water by manganese oxide coated zeolite[J]. Journal of Anhui Agricultural Sciences, 2009, 37(15):7156-7158,7161(in Chinese)
[68] 朱保虎, 陈小敏, 杨文, 等. 改性沸石对水中微量汞的吸附性能[J]. 环境工程学报, 2016, 10(11):6261-6268 Zhu Baohu, Chen Xiaomin, Yang Wen, et al. Characterization of trace mercury adsorption by modified zeolite[J]. Chinese Journal of Environmental Engineering, 2016, 10(11):6261-6268(in Chinese)
[69] Xu R, Zhou G, Tang Y, et al. New double network hydrogel adsorbent:Highly efficient removal of Cd(Ⅱ) and Mn(Ⅱ) ions in aqueous solution[J]. Chemical Engineering Journal, 2015, 275:179-188
[70] 庞禄. 铁锰复合氧化物对重金属铬(Ⅲ)、砷(Ⅲ)吸附/氧化特征研究[D]. 重庆:西南大学, 2014 Pang Lu. Characteristics of isothermal adsorption and oxidation of Cr(Ⅲ), As(Ⅲ) ions by iron and manganese composite oxide[D]. Chongqing:Southwest University, 2014(in Chinese)
[71] 高仙, 马非, 田栋, 等. 黏土基陶粒吸附处理Cd²⁺废水[J]. 工业水处理, 2011, 31(3):49-52 Gao Xian, Ma Fei, Tian Dong, et al. Adsorption treatment of Cd²⁺wastewater with clay based ceramsite[J]. Industrial Water Treatment, 2011, 31(3):49-52(in Chinese)
[72] 邹卫华. 锰氧化物改性过滤材料对铜和铅离子的吸附研究[D]. 长沙:湖南大学, 2006 Zou Weihua. The research on adsorption of copper and lead ions from aqueous solution by manganese oxide coated lilter media[D]. Changsha:Hunan University, 2006(in Chinese)
[73] 李天昕, 矫媛媛, 吴世玲, 等. Mn-沸石催化剂的制备及其对Fenton工艺处理垃圾渗液催化氧化效果研究[J]. 应用化工, 2014(9):1626-1629 Li Tianxin, Jiao Yuanyuan, Wu Shiling, et al. Study on preparing Mn-zeolite catalyst and effect of Fenton process for leachate treatment[J]. Applied Chemical Industry, 2014(9):1626-1629(in Chinese)
[74] 周锦霞, 张永春, 郭新闻, 等. 金属盐阴离子和阳离子对乙烯络合吸附性能影响[J]. 大连理工大学学报, 2006, 46(2):175-178 Zhou Jinxia, Zhang Yongchun, Guo Xinwen, et al. Effects of anion and cation on π-complexation between ethylene and metal halides[J]. Journal of Dalian University of Technology, 2006, 46(2):175-178(in Chinese)
[75] 张科春, 刘磊, 程宇辉, 等. 乙烯、苯与Li⁺、Na⁺、K⁺形成的阳离子-π复合物结构的理论研究[J]. 化学物理学报, 2002, 15(2):93-96 Zhang Kechun, Liu Lei, Cheng Yuhui, et al. A theoretical study on the structures of the cation-π complexes formed by ethylene, benzene with Li⁺, Na⁺, and K⁺[J]. Chinese Journal of Chemical Physics, 2002, 15(2):93-96(in Chinese)
[76] 陈茂荣, 陈金毅, 张文蓉, 等. 沸石负载Cu₂O光催化剂的制备及其性能研究[J]. 武汉工程大学学报, 2009, 31(12):28-31 Chen Maorong, Chen Jinyi, Zhang Wenrong, et al. Study on preparation and performance of Cu₂O photocatalyst supported on Zeolite[J]. Journal of Wuhan Institute of Technology, 2009, 31(12):28-31(in Chinese)
[77] Ding L, Deng H, Wu C, et al. Affecting factors, equilibrium, kinetics and thermodynamics of bromide removal from aqueous solutions by MIEX resin[J]. Chemical Engineering Journal, 2012, 181/182:360-370
[78] 刘丽莉, 景有海, 欧阳通. 水合氧化铈吸附水中磷酸根特性的研究[J]. 安全与环境学报, 2007, 7(2):64-67 Liu Lili, Jing Youhai, Ouyang Tong. Adsorption characteristics of the phosphate on the hydrous ceric oxide[J]. Journal of Safety and Environment, 2007, 7(2):64-67(in Chinese)
[79] 丁爱中, 付云飞, 刘培生, 等. 载铝多孔沸石的制备及其对水中砷的吸附研究[J]. 中国科技论文在线,2011, 6(9):700-706 Ding Aizhong, Fu Yunfei, Liu Peisheng, et al. Study on preparation of porous zeolite loaded with boehmite and its adsorption of as from water[J]. Sciencepaper Online, 2011, 6(9):700-706(in Chinese)
[80] 周尊隆, 卢媛, 孙红文. 菲在不同性质黑炭上的吸附动力学和等温线研究[J]. 农业环境科学学报, 2010, 29(3):476-480 Zhou Zunlong, Lu Yuan, Sun Hongwen. Sorption kinetics and isotherms of phenanthrene in charcoals with different properties[J]. Journal of Agro-Environment Science, 2010, 29(3):476-480(in Chinese)
[81] 乌力吉扎日嘎拉, 萨嘎拉, 何秀萍, 等. ZnO/丝光沸石催化剂的制备及其光催化性能[J]. 内蒙古师范大学学报:自然科学汉文版, 2010, 39(5):535-540 Ulziijargal, Sagala, He Xiuping, et al. Studies on the preparation of ZnO/mordenite catalysts and their photocatalysis[J]. Journal of Inner Mongolia Normal University:Natural Science Edition, 2010, 39(5):535-540(in Chinese)
[82] 张志华, 窦涛, 张瑛. 沸石的碱溶液处理改性[J]. 工业催化, 2004, 12(10):49-53 Zhang Zhihua, Dou Tao, Zhang Ying. Zeolites modification through treatment in alkali solutions[J]. Industrial Catalysis, 2004, 12(10):49-53(in Chinese)
[83] Chang Y, Liu H, Zha F, et al. Adsorption of Pb(Ⅱ) by N-methylimidazole modified palygorskite[J]. Chemical Engineering Journal, 2011, 167(1):183-189
[84] Bao W, Liu L, Zou H, et al. Removal of Cu²⁺from aqueous solutions using Na-A zeolite from oil shale ash[J]. Chinese Journal of Chemical Engineering, 2013, 21(9):974-982
[85] Yang X, Yang S, Yang S, et al. Effect of pH, ionic strength and temperature on sorption of Pb(Ⅱ) on NKF-6 zeolite studied by batch technique[J]. Chemical Engineering Journal, 2011, 168(1):86-93
[86] 薛美香, 陈建琴, 林玉凤. 微波辅助改性沸石对水中铜的吸附研究[J]. 工业水处理, 2014, 34(3):36-39 Xue Meixiang, Chen Jianqin, Lin Yufeng. Study on the adsorption of copper in water by microwave-assisted modified zeolite[J]. Industrial Water Treatment, 2014, 34(3):36-39(in Chinese)
[87] 耿振香, 李江丽, 李晋平, 等. 氯化钠联合加热改性沸石处理亚甲基蓝废水的实验研究[J]. 山东化工, 2018, 47(5):153-154 Geng Zhenxiang, Li Jiangli, Li Jinping, et al. Experimental research on methylene blue wastewater treatment by the method of sodium chloride combined with heated zeolite[J]. Shandong Chemical Industry, 2018, 47(5):153-154(in Chinese)
[88] 周波, 鲍长利, 冯志兵, 等. 天然沸石负载TiO₂光催化降解敌敌畏和对硫磷[J]. 环境污染治理技术与设备, 2004, 5(6):33-35 Zhou Bo, Bao Changli, Feng Zhibing, et al. Photocatalytic degradation of dichlorvos and parathion with titanium dioxide supported on natural zeolite[J]. Techniques and Equipment for Environmental Pollution Control, 2004, 5(6):33-35(in Chinese)
[89] Gomez S, Marchena C L, Pizzio L, et al. Preparation and characterization of TiO₂/HZSM-11 zeolite for photodegradation of dichlorvos in aqueous solution[J]. Journal of Hazardous Materials, 2013, 258/259:19-26
[90] Gomez S, Marchena C L, Renzini M S, et al. In situ generated TiO₂ over zeolitic supports as reusable photocatalysts for the degradation of dichlorvos[J]. Applied Catalysis B:Environmental, 2015, 162:167-173
[91] Chen J, Eberlein L, Langford C H. Pathways of phenol and benzene photooxidation using TiO₂ supported on a zeolite[J]. Journal of Photochemistry and Photobiology A:Chemistry, 2002, 148(1/2/3):183-189
[92] Dionysiou D D, Suidan M T, Baudin I, et al. Effect of hydrogen peroxide on the destruction of organic contaminants-synergism and inhibition in a continuous-mode photocatalytic reactor[J]. Applied Catalysis B:Environmental, 2004, 50(4):259-269
[93] Hoffmann M R, Martin S T, Choi W, et al. Environmental applications of semiconductor photocatalysis[J]. Chemical Reviews, 1995, 95(1):69-96
[94] Mahalakshmi M, Vishnu Priya S, Arabindoo B, et al. Photocatalytic degradation of aqueous propoxur solution using TiO₂ and H beta zeolite-supported TiO₂[J]. Journal of Hazardous Materials, 2009, 161(1):336-343
[95] Liu X, Liu Y, Lu S, et al. Performance and mechanism into TiO₂/Zeolite composites for sulfadiazine adsorption and photodegradation[J]. Chemical Engineering Journal, 2018, 350:131-147
[96] García-Galán M J, Silvia Díaz-Cruz M, Barceló D. Identification and determination of metabolites and degradation products of sulfonamide antibiotics[J]. TrAC Trends in Analytical Chemistry, 2008, 27(11):1008-1022
[97] 王长平, 董浩, 张辉, 等. 载TiO₂海泡石粉体的研制[J]. 天津城市建设学院学报, 2002, 8(4):265-268 Wang Changping, Dong Hao, Zhang Hui, et al. Preparation of loading TiO₂ sepiolite powder[J]. Journal of Tianjin Institute of Urban Construction, 2002, 8(4):265-268(in Chinese)
[98] 高濂. 纳米氧化钛光催化材料及应用[M]. 北京:化学工业出版社, 2002
[99] 石中亮, 姚淑华, 华丽. 沸石负载TiO₂光催化降解造纸废水研究[J]. 非金属矿, 2007, 30(4):46-49 Shi Zhongliang, Yao Shuhua, Hua Li. Study on photocatalytic degradation of papermaking wastewater by TiO₂-coated natural zeolite[J]. Non-Metallic Mines, 2007, 30(4):46-49(in Chinese)
[100] 张志翔, 陈亮, 包南, 等. 丝光沸石负载二氧化钛膜光催化降解邻氯苯酚[J]. 水资源保护, 2006, 22(2):59-61,87 Zhang Zhixiang, Chen Liang, Bao Nan, et al. Photocatalytic oxidation of 2-chlorphenol using H-mordenite loaded TiO₂ film[J]. Water Resources Protection, 2006, 22(2):59-61, 87(in Chinese)