水基锌离子电池钒基正极材料研究进展

摘要锂离子电池现已得到广泛应用，但锂和钴资源的储量以及价格限制了锂离子电池的进一步发展。水系锌离子电池因其具有原材料储量丰富、价格低廉、环保等优点受到越来越多的关注，但正极材料稀少限制了其实际应用。而具有分层、三维开孔或快速离子导体结构的钒基材料是锌离子电池最有前景的正极材料。详细介绍了钒的氧化物、钒酸盐、磷酸钒盐、硫化钒以及其钒基材料在锌离子电池领域的应用，并对其未来发展进行了展望。

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	翟小亮
	柳勇
	王飞
	魏慧洁
	张万红

关键词：水基锌离子电池正极材料 V₂O₅ 硫化钒钒酸盐

Abstract： Lithium-Ion batteries have become more widespread, but the reserves and price of lithium and cobalt limited the further development of lithium-ion batteries. Rechargeable aqueous zinc-ion batteries have received more and more attention for their advantages of abundant reserves, low price and environmental benignity, but the scarcity of cathode materials limited the practical application. Vanadium-based materials with layered, 3D open channel or NASICON structure are promising cathode materials for the aqueous zinc-ion batteries. This review introduces the application of vanadium-based materials such as vanadium oxides, vanadates, phosphates, sulfide and other vanadium-based materials, and the prospect and development of vanadium-based materials in the field of rechargeable aqueous zinc-ion batteries were also forecasted.

Keywords： rechargeable aqueous zinc-ion batteries； cathode material； V₂O₅； vanadium sulfide； vanadates

Received 2019-09-16;

Fund:教育部"创新团队发展计划"滚动支持基金项目（IRT-16R21）；河南省科技厅科技攻关项目（152102410035）和（182102210297）；金属材料磨损控制与成型技术国家地方联合工程研究中心开放基金重点项目（HKDNM201807）。

Corresponding Authors: 柳勇,E-mail:liuyong209@haust.edu.cn。 Email: liuyong209@haust.edu.cn

About author: 翟小亮(1987-),男,硕士研究生,现从事水基锌离子电池方面的研究。

引用本文:

翟小亮, 柳勇, 王飞, 魏慧洁, 张万红.水基锌离子电池钒基正极材料研究进展[J]. 化学工业与工程, 2020,37(5): 37-45,79

Zhai Xiaoliang, Liu Yong, Wang Fei, Wei Huijie, Zhang Wanhong.Recent Progress of Vanadium-Based Cathode Materials for Rechargeable Aqueous Zinc-Ion Batteries[J]. Chemcial Industry and Engineering, 2020,37(5): 37-45,79

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