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Chemcial Industry and Engineering 2002, Vol. 19 Issue (6) :405-410    DOI:
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Annalysis of the Solubility of Methane in Hydrocarbon
HUA Chao 1,MA Pei-sheng 1,XIA Shu-qian 1,SHI Yun-jie 2 (1.School of Chemical Engineering Tianjin University,Tianjin 300072,China; 2.Tianjin Petrochemical Corporation Ethene Factory,Tianjin 300271,China)
(1.School of Chemical Engineering Tianjin University,Tianjin 300072,China; 2.Tianjin Petrochemical Corporation Ethene Factory,Tianjin 300271,China

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Abstract The solubility data of methane in hydrocarbons,ranging from alkanes,aromatichydrocarbons,cycloalkanes and ethenes,were researched and Henry constants were gotten by correlating the data of different pressures in the same temperature.It was proved that Henry law is applicable at the researched pressures. The effect of solvent carbon atoms and construction of hydrocarbons on methane's Henry constant has been studied in detail.The temperature coefficients of Henry constant were correlated.At the same time,a method was advanced to estimate methane Henry constants in hydrocarbons using critical volume.The above data and calculation methods are valuable for the application of liquid natural gas.
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Received 2002-11-15; published 2002-11-15
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HUA Chao 1,MA Pei-sheng 1,XIA Shu-qian 1,SHI Yun-jie 2 .Annalysis of the Solubility of Methane in Hydrocarbon[J]  Chemcial Industry and Engineering, 2002,V19(6): 405-410
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