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Chemcial Industry and Engineering 2006, Vol. 23 Issue (1) :14-17    DOI:
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Synthesis and Thermodynamic Stability of Metal Complexes of 2-Mercaptopyridine
LU Lian-ying,WANG Dun-jia,YU Zhong-shan(Department of Chemistry and Environment,Hubei Normal University,Hubei Huangshi 435002,China)
(Department of Chemistry and Environment,Hubei Normal University,Hubei Huangshi 435002,China

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Abstract In this paper,2-mercaptopridine based Pb(Ⅱ),Co(Ⅱ),Mn(Ⅱ),Zn(Ⅱ),Cd(Ⅱ),Cu(Ⅱ),Ni(Ⅱ) complexes are synthesized.The complexes are characterized by titration analysis,conductance measurement,UR and IR.The analysis shows that with different metal ions,the ratio of metal to ligand is different.The thermodynamic stability are obtained from the analysis of the TG/DTA,and their sequence are Pb(Ⅱ) complexes>Zn(Ⅱ)complexes>Cd(Ⅱ)complexes>Ni(Ⅱ)complexes>Co(Ⅱ)complexes>Mn(Ⅱ)complexes>Cu(Ⅱ)complexes.
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Received 2006-01-15; published 2006-01-15
Cite this article:   
LU Lian-ying,WANG Dun-jia,YU Zhong-shan.Synthesis and Thermodynamic Stability of Metal Complexes of 2-Mercaptopyridine[J]  Chemcial Industry and Engineering, 2006,V23(1): 14-17
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