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Chemcial Industry and Engineering 2007, Vol. 24 Issue (4) :295-298    DOI:
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Synthesis of a Triarylamine Compound as Hole Transport Material and Its Photoelectric Performance
LI Nan,WANG Shi-rong,LI Xiang-gao(Department of Fine Chemicals,School of Chemical Engineering and Technology, Tianjin University,Tianjin 300072,China)
(Department of Fine Chemicals,School of Chemical Engineering and Technology, Tianjin University,Tianjin 300072,China

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Abstract In this paper,3,5-dimethyldiphenylamine was firstly prepared by 3,5-dimethylaniline and benzenesulfonic acid sodium salt and the influence of temperature,time and the proportion of reactant on the yield of product were discussed.Then 3,5-dimethyldiphenylamine was reacted with 4,4′-diiodobiphenyl via Ulmann reaction to get N,N′-bis(3,5-dimethylphenyl)-N,N′-diphenyl-[1,1′-biphenyl]-4,4′-diamine,as hole transport material,in yield of 82.24% and in purity of 99.31%.The photoelectric test results of the device showed that the compound had good performance of hole transport.
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Received 2007-07-15; published 2007-07-15
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LI Nan,WANG Shi-rong,LI Xiang-gao.Synthesis of a Triarylamine Compound as Hole Transport Material and Its Photoelectric Performance[J]  Chemcial Industry and Engineering, 2007,V24(4): 295-298
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