Progress in the Catalyst for Synthesis of 4-tert-butyl-pyrocatechol

化学工业与工程

Chemcial Industry and Engineering

2008, Vol. 25

Issue (1) :72-75 DOI:

Article

Current Issue | Next Issue | Archive | Adv Search

<< | >>

Progress in the Catalyst for Synthesis of 4-tert-butyl-pyrocatechol

FENG Hui-sheng~1,WEI Yue-e~1,PAN Xiao-zhu~2(1.Chemical Engineering Research Center,Tianjin University,Tianjin 300072,China;2.SINOPEC Tianjin in Petrochemical Corp,Tianjin 300271,China)

(1.Chemical Engineering Research Center,Tianjin University,Tianjin 300072,China;2.SINOPEC Tianjin in Petrochemical Corp,Tianjin 300271,China

Abstract	Reference	Related Articles

Download: PDF (174KB) HTML 1KB Export: BibTeX or EndNote (RIS) Supporting Info

Abstract 4-tert-butyl-pyrocatechol is one of important organic substance.In this paper,progress in the synthesis process for 4-tert-butyl-pyrocatechol was introduced.Catalysts in three synthesis routes,the hydroxylation of 4-tert-butyl-phenol,the alkylation of pyrocatechol by tert-butyl alcohol and the alkylation of pyrocatechol by isobutene,were discussed in detail in terms of reaction conditions,catalysts,temperature,reaction time etc.At the same time green chemistry technique of the hydroxylation of 4-tert-butyl-pyrocatechol is the research focus in future.

	Service

	Email this article
	Add to my bookshelf
	Add to citation manager
	Email Alert
	RSS
	Articles by authors

Keywords��

Received 2008-01-15; published 2008-01-15

Cite this article:

FENG Hui-sheng~1,WEI Yue-e~1,PAN Xiao-zhu~2.Progress in the Catalyst for Synthesis of 4-tert-butyl-pyrocatechol[J] Chemcial Industry and Engineering, 2008,V25(1): 72-75

[1]	ʯ��,�ƺ��.��羫ϸ��Ʒ��ֲ�[M].��:��Ƽ��鱨�о��,1988.
[2]	Ԭ�ı�,��.��嶡��ڱ��ӵĺϳ�[J].��,1994,22(2):8.
[3]	PHILIP F,JOCKISCH,ROYAL O.Stabilisation of di:bromo-styrene against polymerisation-using alkyl gallate andphenothiazine or 4-tert-butyl-catechol:US,4375006-A[P].1983-02-22.
[4]	ROYAL O,YAMAMOTO.New stabilised maleimide soln.useful for modifying resins composed of maleimide stabilisere.g.4-tert butyl catechol and lower ketone(s),havingmedium to strong hydrogen bonds:JP,5331137[P].1994-02-28.
[5]	���.MTBE�Էӵ��嶡��о�[D].��:��ѧ,2000.
[6]	ZUMSTEIN S,ASSMANN E.Hydroxylation of aromaticcpds.with hydrogen peroxide:DE,2064497[P].1969-11-30.
[7]	HERMANN S,HELMUT W.Hydroxylating phenolic cpds.or their ethers using practically anhydrous peroxide with astrong acid:DE,2410758[P].1979-12-03.
[8]	HERMANN S,HELMUT W.Pyrocatechol and hydroquinoneprepn.from phenol and percarboxylic acid in anhydrousorganic solvent:DE,2658943[P].1980-06-30.
[9]	IMAMURA,JUICHI D.Benzenes or their monoethers-fromphenols or phenolic ethers,organic peracid plus specifiedcatalyst for higher yields:DE,2364181[P].1973-11-30.
[10]	YAMAMOTO M,AKIYAMA A.Production ofalkylcatechol:JP,11310543[P].1999-11-09.
[11]	DRAUZ,KARLHEINZ,KLEEMANN,et al.Process forthe production of dihydroxybenzenes:US,4533766[P].1985-08-06.
[12]	OKIHAMA,MARIKO.Method for production of catecholcompounds comprises reacting a phenol or an alkylphenolwith hydrogen peroxide in the presence of organic ironcomplex and solvent:JP,10236997[P].1998-09-08.
[13]	SAKATA HIROSHI,AKIYAMA.Method for producingalkylcatechols:JP,2002322108[P].2002-11-08.
[14]	RIEDEL D,HAEN.4-alkyl-pyrocatechols prodn-byoxidation of 4-alkyl-phenols:DE,2101992[P].1971-01-16.
[15]	DRAUZ,KARLHEINZ,KLEEMANN,et al.Process for theproduction of dihydroxybenzenes:US,4628126[P].1986-12-09.
[16]	DRAUZ,KARLHEINZ,KLEEMANN,et al.Process for theproduction of non-aqueous hydrogen peroxide solutions andtheir use:US,4686010[P].1987-08-11.
[17]	DRAUZ,KARLHEINZ,KLEEMANN.Method of preparingsubstituted dihydroxy-benzenes:US,4825011[P].1989-08-06.
[18]	JIMENEZ,MERCEDES,GARCIA C F.Hydrogen peroxide-dependent 4-t-butylphenol hydroxylation by tyrosinase:Anew catalytic activity[J].Biochim Biophys Acta,1996,129(1):33.
[19]	��ѧ��ҵ��֯��д.��ϸ��Ʒ��ȫ[M].��ѧ��ҵ��,2005.
[20]	BURK R E.Twelfth Catalyst Report[M].New York:National Research Council,1940.
[21]	��Ӣ��,��.�Ծ��Ʒ�̽��嶡��ڱ��ӵĺϳ�[J].��ѧԺѧ��,1992,20(6):153.
[22]	JUNG W Y.Alkylation of catechol with t-butyl alcohol overacidic zeolites[J].Applied Catalysis A:General,1999(187):225.
[23]	CLARENCE D,CHANG S D,HELLRING.Prepn of para-tert-butyl-phenol with high selectivity by reacting phenolwith butene or butanol over fairly large pore zeolite:US,5288927[P].1993-02-01.
[24]	�ž��,�﷢Ⱥ.��Ԧ·�ʯ�߻��ڱ��嶡��Ӧ[J].��Ĵ�ѧѧ��:��Ȼ��ѧ��,2002,22(2):109.
[25]	�Ⱦ��,��.��ӽ��֬�߻��ϳ�TBC[J].��ӽ��,1995,11(5):449.
[26]	LIEBIG H,ROTH W,KNAUL J.High purity 4-tert-butyl-catechol prodn by reacting catechol with isobutene inpresence of hydrogen fluoride,useful e.g.as stabiliser formonomers,insecticides and fuels:DE,1668960[P].1969-10-02.
[27]	JIMENEZ M,GARCIA C.Hydrogen peroxide-dependent 4-t-butylphenol hydroxylation by tyrosinase:A new catalyticactivity[J].Biochimica Biophysica Acta.1996,1297(33):33-