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Chemcial Industry and Engineering 2018, Vol. 35 Issue (3) :50-54    DOI: 10.13353/j.issn.1004.9533.20172000
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Crystallization Thermodynamics and Its Crystallization Process of Meso-Erythritol in Water
Wang Hairong1,2, Zhang Chuntao2, Liang Wendong2
1. School of Chemistry and Chemical Engineering, Wuhan University of Science & Technology, Wuhan 430081, China;
2. Key Laboratory of Coal Conversion and New Carbon Materials for Hubei Province, Wuhan 430081, China

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Abstract 

The solubilities of meso-Erythritol in water were experimentally measured from 283.15 K to 363.15 K at atmospheric pressure by employing the synthetic method. The experimental data were correlated by using the modified Apelblat equation and λh equation, the accuracy of which could meet the need of their industrial use. The dissolution enthalpy, dissolution entropy and molar Gibbs energy of the dissolution of meso-Erythritol in water were then calculated. The cooling crystallization of meso-Erythritol had been studied by using FBRM-PVM on the basis of the measured crystallization thermodynamics data. The experimental data and the correlation equations in this work can be used as essential data and models in the industrial manufacture process optimization and crystallizer design of meso-Erythritol.

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Articles by authors
Wang Hairong
Zhang Chuntao
Liang Wendong
Keywordsmeso-Erythritol;   crystallization thermodynamics;   cooling crystallization     
Received 2017-01-01;
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Wang Hairong, Zhang Chuntao, Liang Wendong.Crystallization Thermodynamics and Its Crystallization Process of Meso-Erythritol in Water[J]  Chemcial Industry and Engineering, 2018,V35(3): 50-54
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