Experimental Study on Phenol Hydroxylation with Fe-D72 Resin Catalyst

化学工业与工程

Chemcial Industry and Engineering

2017, Vol. 34

Issue (5) :49-54,60 DOI: 10.13353/j.issn.1004.9533.20161033

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Experimental Study on Phenol Hydroxylation with Fe-D72 Resin Catalyst

Feng Huisheng¹, Zhong Xin¹, He Lijuan², Sun Dezhang¹, Luo Binbin¹

1. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China;
2. Beijing Zhonghuan Engineering Project Management Co. Ltd, Beijing 100176, China

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Abstract

Fe-D72 resin was prepared by the ion exchange process between iron ions and D72 resin. It was applied to the phenol hydroxylation with H₂O₂. The effects of different reaction conditions such as the iron capacity of catalyst, reaction temperature, reaction time, catalyst dosage, molar ratio of H₂O₂to phenol were investigated. The orthogonal experiment was carried out to get the best optimized operating conditions. Under the conditions of iron capacity as 95.4 mg·g^-1, reaction temperature as 70 ℃, reaction time as 1 h, catalyst dosage as 0.1 g, molar ratio of H₂O₂ to phenol as 1∶1, 42.4% phenol conversion was obtained with benzenediol selectivity being 94.1%. The reusability of prepared catalyst illustrated that it could be recovered and reused without notable loss of activity.

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	Feng Huisheng
	Zhong Xin
	He Lijuan
	Sun Dezhang
	Luo Binbin

Keywords： ion exchange； D72 resin； phenol hydroxylation； reusability

Received 2016-03-18;

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Feng Huisheng, Zhong Xin, He Lijuan, Sun Dezhang, Luo Binbin.Experimental Study on Phenol Hydroxylation with Fe-D72 Resin Catalyst[J] Chemcial Industry and Engineering, 2017,V34(5): 49-54,60

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