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Chemcial Industry and Engineering 2017, Vol. 34 Issue (2) :35-38,61    DOI: 10.13353/j.issn.1004.9533.20151043
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Adsorption Desulfurization Performance of Groups of Halloysite Nanotubes
Ma Zhi, Liu Huanhuan, Zhu Weijia, Ding Tong, Qi Xiaozhou
Tianjin Key Laboratory of Applied Catalysis Science & Technology, School of Chemical Engineering & Technology, Tianjin University, Tianjin 300072, China

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Abstract 

The surface modification of natural Halloysite nanotubes by grafting with γ-aminopropyltriethoxysilane (APTES) was firstly got. So we modified the functional groups of Halloysite nanotubes (HNT) from hydroxyl groups (HNT-OH) to amino groups (HNT-NH2) and to carboxylic acids (HNT-COOH), which was found to have perfect performance on adsorption desulfurization, and the materials were characterized by SEM, FTIR, XRD and BET. The desulfurization rate of HNT-NH2 was 72.06%, which was 19.47% bigger than natural Halloysite nanotubes. But the rate of HNT-COOH was only 8.42% bigger than that of natural Halloysite nanotubes. The bigger the pore volume of the modified materials was, the bigger the desulfurization rate of functional materials was.

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Ma Zhi
Liu Huanhuan
Zhu Weijia
Ding Tong
Qi Xiaozhou
KeywordsHalloysite nanotubes;   organic modification;   adsorption desulfurization     
Received 2015-03-30;
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Ma Zhi, Liu Huanhuan, Zhu Weijia, Ding Tong, Qi Xiaozhou.Adsorption Desulfurization Performance of Groups of Halloysite Nanotubes[J]  Chemcial Industry and Engineering, 2017,V34(2): 35-38,61
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