Effect of Quaternary Ammonium Surfactants on Adsorption Desulfurization Performance of Kaolin Nanotubes

化学工业与工程

Chemcial Industry and Engineering

2016, Vol. 33

Issue (6) :14-18 DOI: 10.13353/j.issn.1004.9533.20141115

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Effect of Quaternary Ammonium Surfactants on Adsorption Desulfurization Performance of Kaolin Nanotubes

Cui Jingjing, Ma Zhi, Ding Tong, Qi Xiaozhou

Tianjin Key Laboratory of Applied Catalysis Science & Technology, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China

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Abstract

Kaolin nanotubes was prepared successfully using coal-based kaolin through intercalation reaction. The prepared kaolin nanotubues had good homogeneity and big length-diameter ratio, while their inside diameters vary from 8 nm to 25 nm, widths vary from 0.1 μm to 0.5 μm. Kaolin nanotubes were modified with three kinds of quaternary ammonium surfactants which are cetyltrimethylammonium chloride, cetyltrimethylammonium bromide and dodecyl trimethyl ammonium bromide. The effects of varieties and concentration of surfactants on the structure and adsorption desulfurization performance of kaolin nanotubes were studied. It was found that the desulfurization capacity of kaolin nanotubes is enhanced by the surfactant modification. Especially, the desulfurization rate of kaolin nanotubes modified with 0.5 mol/L of CTAC ethanol solution has significant growth from 40.5% to 60.3%.

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	Cui Jingjing
	Ma Zhi
	Ding Tong
	Qi Xiaozhou

Keywords： kaolin nanotube； surfactant； modification； adsorption desultfurization

Received 2014-05-13;

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Cui Jingjing, Ma Zhi, Ding Tong, Qi Xiaozhou.Effect of Quaternary Ammonium Surfactants on Adsorption Desulfurization Performance of Kaolin Nanotubes[J] Chemcial Industry and Engineering, 2016,V33(6): 14-18

[1] Levis S R, Deasy P B. Use of coated microtubular halloysite for the sustained release of diltiazem hydrochloride and propranolol hydrochloride[J]. Int J Pharm, 2003, 253:145-157
[2] Byrne R S, Deasy P B. Use of porous aluminosilicate pellets for drug delivery[J]. J Microencapsulation, 2005, 22:423-437
[3] Shchukin D G, Sukhorukov G B, Price R R. Halloysite nanotubes as biomimetic nanoreactors[J]. Small, 2005, 5:510-513
[4] Du M, Guo B, Jia D. Newly emerging applications of halloysite nanotubes:A review[J]. Polym Int, 2010, 59:574-582
[5] 马智, 王金叶, 高祥, 等. 埃洛石纳米管的应用研究现状[J]. 化学进展, 2012, 24(2/3):43-46 Ma Zhi,Wang Jinye,Gao Xiang,et al.Application of halloysite nanotubes[J].Progress in Chemistry, 2012, 24(2/3):43-46(in Chinese)
[6] Kuroda Y, Ito K, Itabashi K, et al. One-Step exfoliation of kaolinites and their transformation into nanoscrolls[J]. Langmuir, 2011, 27(5):2028-2035
[7] 龙海, 郑玉婴, 郭勇, 等. 高岭土纳米卷的制备与表征[J].无机化学学报, 2012, 28(6):1210-1216 Long Hai,Zheng Yuying,Guo Yong,et al.Preparation and characterization of kaolinite nanoscrolls[J].Chinese Journal of Inorganic Chemistry, 2012, 28(6):1210-1216(in Chinese)
[8] Matusik J, Gawel A, Bielanska E. The effect of structural order on nanotubes derived from kaolin-group minerals[J]. Clays and Clay Minerals, 2009, 57(4):452-464
[9] Matusik J, Wisla-Walsh E, Gawel A. Surface area and porosity of nanotubes obtained from kaolin minerals of different structural oeder[J]. Clays and Clay Minerals, 2011, 59(2):116-135
[10] Matusik J, Stodolak E, Bahranowski K. Synthesis of polylactide/clay composites using structurally different kaolinites and kaolinite nanotubes[J]. Applied Clay Science, 2011, 51:102-109
[11] 邓中文, 郑玉婴, 龙海, 等. TiO₂负载管状高岭土光催化剂的制备及其表征[J]. 功能材料, 2013, 44(6):874-877, 882 Deng Zhongwen, Zheng Yuying, Long Hai, et al.Preparation and characterization of TiO₂ supported tubular kaolinite[J]. Journal of Functional Materials, 2013, 44(6):874-877, 882(in Chinese)
[12] Huo Q, Margolese D I, Stucky G D. Surfactant control of phases in the synthesis of mesoporous silica-based materials[J]. Chem Mater, 1996, 8:1147-1160
[13] 王世荣, 李祥高, 刘东志. 表面活性剂化学[M]. 北京:化学工业出版社,2005 Wang Shirong, Li Xianggao, Liu Zhidong. Surfactant chemistry[M]. Beijing:Chemical Industry Press,2005(in Chinese)
[14] 李瑜, 李为民, 姚超, 等. 季铵盐改性凹凸棒土及处理含油废水[J]. 非金属矿, 2010, 33(1):58-60, 63 Li Yu, Li Weimin, Yao Chao, et al. Attapulgite modified by quaternary ammonium salt and its application to oily waste water[J]. Non-Metallic Mines, 2010, 33(1):58-60, 63(in Chinese)
[15] 王琪莹, 刘自力, 邹汉波, 等. 表面活性剂改性对Zn/Ti-PILCs吸附剂脱硫性能的影响[J]. 燃料化学学报, 2011, 39(3):203-206 Wang Qiying, Liu Zili, Zou Hanbo, et al.Effect of surfactant modification on the desulfurization performance of Zn/Ti-PILCs adsorbent[J]. Journal of Fuel Chemistry and Technology, 2011, 39(3):203-206(in Chinese)
[16] GB 380-77. 石油产品硫含量测定法(燃灯法)[S]. 1988 GB 380-77. Petroleum products-determination of sulphur-lamp method[S]. 1988(in Chinese)
[17] 张生辉. 高岭土/有机插层复合物的制备、表征及插层机理研究[D]. 北京:中国矿业大学, 2012 Zhang Shenghui. Study on the preparation, characteration and intercalation mechanism of kaolinite-organic intercalation compounds[D]. Beijing:China University of Mining & Technology, 2012(in Chinese)