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Chemcial Industry and Engineering 2016, Vol. 33 Issue (1) :10-14    DOI: 10.13353/j.issn.1004.9533.20151029
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Thermodynamic Analysis of Carbomate Preparation from Methyl Phenol Carbonate
Yang Yong1,3, Tang Jihai1, Chen Xian1, Fei Zhaoyang1,2, Cui Mifen1, Qiao Xu1,2
1. College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China;
2. State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China;
3. Life Science and Chemical Engineering School, Huaiyin Institute of Technology, Huaian 223003, China

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Abstract 

The reaction heats, the changes of Gibbs free energy and the equilibrium constants of methyl phenol carbonate with three amines for carbamates were calculated by group contribution method. The calculated results show that the change of Gibbs free energy from the reaction of MPC with 1,6-hexandiamine was the minimum while the equilibrium constant was the maximum, providing reference to future experimental study and industrial application.

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Articles by authors
Yang Yong
Tang Jihai
Chen Xian
Fei Zhaoyang
Cui Mifen
Qiao Xu
Keywordsmethyl phenyl carbonate;   carbamate;   equilibrium constant;   thermodynamic analysis     
Received 2015-03-16;
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Yang Yong, Tang Jihai, Chen Xian, Fei Zhaoyang, Cui Mifen, Qiao Xu.Thermodynamic Analysis of Carbomate Preparation from Methyl Phenol Carbonate[J]  Chemcial Industry and Engineering, 2016,V33(1): 10-14
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