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Chemcial Industry and Engineering 2015, Vol. 32 Issue (5) :98-102    DOI: 10.13353/j.issn.1004.9533.2015.05.012
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Catalytic Carbonization and Combustible Properties of Polypropylene Catalyzed by Ni-Base Bimetal with Activated Carbon
Gong Weiguang, Xu Yuanyuan, Zheng Baicun
Research & Development Center for Sports Material, East China University of Science and Technology, Shanghai 200237

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Abstract 

Six kinds of Ni-base catalysts were prepared by combustion method and then their catalytic carbonization and combustible properties for polypropylene were tested. The results showed that the catalytic activity of Ni-Al and Ni-Mg catalytic systems are better than single Ni catalyst,the residual char of PP are 43.7% and 41.8%, respectively, compact char layer mainly composed of carbon nanotubes was formed and the peak heat release speed(PHRR)was decreased dramatically. There was a little difference between Ni-Co and Ni catalytic system of residual char, but the formers of structure of char layer is superior to the latter. Catalytic carbonization of Ni-Cu, Ni-Zn and Ni-Fe system were less effective than Ni catalyst.

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Gong Weiguang
Xu Yuanyuan
Zheng Baicun
KeywordsNi-base bimetal catalyst;   activated carbon;   polypropylene;   carbonization;   combustible properties     
Received 2015-07-15;
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Gong Weiguang, Xu Yuanyuan, Zheng Baicun.Catalytic Carbonization and Combustible Properties of Polypropylene Catalyzed by Ni-Base Bimetal with Activated Carbon[J]  Chemcial Industry and Engineering, 2015,V32(5): 98-102
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