Sulfonic Acid Carbon Material Supported Ru Catalysts for Cellulose Hydrolysis and Hydrogenation
XIE Xian-Na,1,2 WANG Hua1, HAN Jin-Yu1, NIU Yu-Fei1
（1.Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China; 2.CNOOC Tianjin Chemical Research & Design Institute,Tianjin 300131, China）
Abstract Bifunctional catalysts of sulfonic acid carbon materials supported Ru were prepared, with different carbon source precursors, namely, cellulose derived carbon, actived carbon and mesoporous carbon materials CMK-3 under different sulfonic acid conditions. The structures of catalysts were characterized by FTIR spectrum, XRD, elemental analysis, thermogravimetric analysis and N2 physical adsorption-desorption. The catalytic performance of hydrogenation reactions of cellulose were studied. Results show that, compared with cellulose derived carbon, activated carbon and mesoporous CMK-3 sulfonic acid carbon materials possess good combination ability with —SO3H，high catalytic activity and good polyols selectivity. Under 170 ℃ for 10 h, hexitols can yield up to 84.0%. When recycled, catalytic activity of activated carbon sulfonic acid materials supported Ru catalyst decreases, but keeps on selectivity of polyols; mesoporous carbon sulfonic acid materials supported Ru catalyst has problems with the loss of S, and conversion rate remaines about the same, but the product selectivity is reduced.
XIE Xian-Na, WANG Hua, HAN Jin-Yu, NIU Yu-Fei.Sulfonic Acid Carbon Material Supported Ru Catalysts for Cellulose Hydrolysis and Hydrogenation[J] Chemcial Industry and Engineering, 2014,V31(4): 6-12
2014, Vol. 31 
