Abstract In the present work, the Pt-Co-La catalysts supported on pyrolytic waste tire char (PTC) were prepared by impregnation method. The loading of Pt is 0.2%, Pt-Co-La atomic ratio is 1∶1:x (x=1—4). The characterization of N2 adsorptiondesorption, H2-TPR and pulse CO chemisorption results showed that the addition of a moderate amount of La to the Pt-Co bimetallic catalyst was beneficial to reduce Pt and Co, and improve their dispersion. The activity of the catalysts for dehydrogenation of methylcyclohexane(MCH)at 300 ℃ was investigated. The results suggest that trimetallic catalysts 1Pt-1Co-xLa/PTC(x=1—3) exhibited the high activity, compared with Pt, Pt-Co and Pt-La supported on PTC.
About author: 杨迎(1987-),女,硕士研究生,现从事以废轮胎热解炭为载体的脱氢催化剂在有机液体储氢中的研究。
Cite this article:
YANG Ying, YE Hong-Li, ZHANG Cui, LIU Shuang-Xi.Dehydrogenation of Methylcyclohexane over Pt-Co-La Catalysts Supported on Pyrolytic Waste Tire Char[J] Chemcial Industry and Engineering, 2014,V31(1): 19-23