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Chemcial Industry and Engineering 2013, Vol. 30 Issue (3) :28-32    DOI:
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Mimic Enzyme Catalytic Reaction of MPc/SBA-15
 CHEN  Wei, PANG  Mei-Ling, DAN  Qiu-Jie, LI  Ting-Ting
College of Chemistry and Chemical Engineering

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Abstract α-Octo-Butoxy phthalocyanin cobalt (CoPc) and  α-octo-butoxy phthalocyanin copper (CuPc) were loaded on mesoporous molecular sieves SBA-15 by impregnation to obtain CoPc/SBA-15 and CuPc/SBA-15 catalysts. UV-Vis absorption spectra, infrared spectra (IR), N2 adsorption were used to characterize the target product. The experimental results indicated that both CoPc/SBA-15 and CuPc/SBA-15 exhibited good catalytic properties, the conversion rate of CuPc/SBA-15 to mercaptoethanol was greater than that of CoPc/SBA-15 to mercaptoethanol. The catalyst showed excellent activity in the reaction with kinetic characteristic of peroxidase. The reaction conformed with Michaelis kinetic equation. The Michaelis constant and maximum reaction rate were 27.23 mmol/L and 1.72×10-4 L/min, respectively, and the activation energy of the CuPc/SBA-15 calculated was 29.17 kJ/mol.
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Articles by authors
CHEN Wei
PANG Mei-Ling
DAN Qiu-Jie
LI Ting-Ting
Keywordsmetallophthalocyanines   catalytic oxidation   mercaptoethanol   reaction kinetics     
Received 2012-09-11;
Fund:

齐齐哈尔大学研究生创新科研项目(YJSCX2011-027X)。

Corresponding Authors: 陈伟,电话:(0452)2738220,E-mail: chenwei150080@163.com。     Email: chenwei150080@163.com
About author: 陈伟(1967-),男,教授,从事配合物功能材料的合成及性能研究。
Cite this article:   
CHEN Wei, PANG Mei-Ling, DAN Qiu-Jie, LI Ting-Ting.Mimic Enzyme Catalytic Reaction of MPc/SBA-15[J]  Chemcial Industry and Engineering, 2013,V30(3): 28-32
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