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Chemcial Industry and Engineering 2013, Vol. 30 Issue (2) :26-30    DOI:
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Influence of Nitric Acid Treatment on Active Carbon Structure and Activity of supported ruthenium catalyst
 WANG  Yan-Hui, JIANG  Hao-Xi, SONG  Yan-Kun
1.R&D Center for Petrochemical Technology, Tianjin University;2.Key Laboratory for Green Chemical Technology of Ministry of Education

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Abstract H2 pulse chemisorption, N2 adsorption and TPR-MS were adopted to test structure properties of active carbon (AC) treated with nitric acid. Effects of nitric acid treatment on AC pore structure and chemical composition were studied. It was indicated that the amount of oxygenfunctional group was considerably increased for the AC which was pretreated by nitric acid. As the support of Ru/AC catalyst, it was found that there was strong interaction between Ru species and oxygenfunctional groups which significantly influenced the dispersion of Ru and  apparently improved the catalytic activity of Ru/AC for hydrogenation of n-butanone.
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WANG Yan-Hui
JIANG Hao-Xi
SONG Yan-Kun
Keywordsactive carbon   nitric acid   ruthenium   dispersion   hydrogenation     
Received 2012-04-20;
Corresponding Authors: 宋彦坤,电话:13619360478,E-mail:yksong7786294@163.com。     Email: yksong7786294@163.com
About author: 王燕辉(1986-),女,硕士研究生,从事超临界流体技术与应用催化研究。
Cite this article:   
WANG Yan-Hui, JIANG Hao-Xi, SONG Yan-Kun.Influence of Nitric Acid Treatment on Active Carbon Structure and Activity of supported ruthenium catalyst[J]  Chemcial Industry and Engineering, 2013,V30(2): 26-30
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