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Chemcial Industry and Engineering 2013, Vol. 30 Issue (1) :53-58    DOI:
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Application of SPEEK Composite Membranes in Electrosynthesis of  Ammonium Persulfate
 NAN Hu , WANG  Yu-Xin
School of Chemical Engineering and Technology, State Key Laboratory of Chemical Engineering, Tianjin University

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Abstract The novel SPEEK composite membranes used in the electrosynthesis of ammonium persulfate were made to decrease energy consumption and improve current efficiency. By testing the membrane’s electrolytic properties, mechanical properties and corrosion resistance of the supporting layer, it is found that the corrosion resistance of polyester cloth was the best of all the measured materials. SPEEK composite membrane based on polyester cloth with 100 mesh counts exhibited the highest tensile strength; and the SPEEK composite membrane based on polyester cloth with 50 mesh counts obtained both the highest current efficiency and the lowest energy consumption. After all, the SPEEK composite membrane based on polyester cloth with 50 mesh counts is considered more appropriate to be applied in the electrosynthesis of ammonium persulfate, although its mechanical properties is not the best, the mechanical properties has been greatly improved compared with pure SPEEK membrane, and it also has a higher current efficiency and lower energy consumption.
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南Hu
WANG Yu-Xin
Keywordselectrosynthesis   ammonium persulfate   composite membrane     
Received 2012-03-30;
Corresponding Authors: 王宇新,电话:(022)27890515,E-mail:yxwang@tju.edu.cn。     Email: yxwang@tju.edu.cn
About author: 南湖(1985-),男,硕士研究生,研究方向为电解制备过硫酸铵工艺。
Cite this article:   
NAN Hu , WANG Yu-Xin.Application of SPEEK Composite Membranes in Electrosynthesis of  Ammonium Persulfate[J]  Chemcial Industry and Engineering, 2013,V30(1): 53-58
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