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Chemcial Industry and Engineering 2004, Vol. 21 Issue (6) :410-413    DOI:
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Synthesis and Spectral Properties of Meso-tetra(p-hexadecyloxynaphthyl) porphyrin
TAO Min-li~1, LIU Dong-zhi~1, ZHOU Xue-qin~2 (1.School of Chemical Engineering, Tianjin University, Tianjin 300072, China; 2.School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China)
(1.School of Chemical Engineering, Tianjin University, Tianjin 300072, China; 2.School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China

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Abstract A kind of novel compound meso-tetra(p-hexadecyloxynaphthyl) porphyrin 3 was synthesized from p-hydroxynaphthaldehyde and characterized by (()~1H) NMR, IR and UV-Vis spectra. The introduction of long carbon chain naphthyl group can enhance the conjugate degree of the porphyrin, and cause red-shift of the absorption spectra. The fluorescence spectrum exhibit that the maxium excitation wavelength red-shifts by 7 nm in 3 compared with that in tetraphenylporphyrin. The reaction condition of p-hydroxynaphthaldehyde and the corresponding long carbon chain ether were studied.
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Received 2004-11-15; published 2004-11-15
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TAO Min-li~1, LIU Dong-zhi~1, ZHOU Xue-qin~2 .Synthesis and Spectral Properties of Meso-tetra(p-hexadecyloxynaphthyl) porphyrin[J]  Chemcial Industry and Engineering, 2004,V21(6): 410-413
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