Interaction Between Anions and MMT

化学工业与工程

Chemcial Industry and Engineering

2009, Vol. 26

Issue (1) :10-14 DOI:

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Interaction Between Anions and MMT

HAO Hui,ZHENG Jun-ping,CHEN Chang-ce,YAO Kang-de(School of Materials Science and Engineering,Tianjin University,Tianjin 300072,China)

(School of Materials Science and Engineering,Tianjin University,Tianjin 300072,China

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Abstract The mechanism of interaction between anions and MMT was studied by analyzing the different intercalation effect of organic anions matter in different state of charges distribution.In order to ascertain the mechanism and the sites of interaction between anions and MMT,a combined characterization technique of FT-IR,XRD and NMR were used.The results indicate that carboxyl group is strongly interacted with MMT.The interactive sites between carboxyl matter and MMT is the carbonyl group(—CO) of the carboxyl anion group((—COO~-)),which interacts with the aluminium hydroxyl group or the aluminium ion.

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Received 2009-01-15; published 2009-01-15

Cite this article:

HAO Hui,ZHENG Jun-ping,CHEN Chang-ce,YAO Kang-de.Interaction Between Anions and MMT[J] Chemcial Industry and Engineering, 2009,V26(1): 10-14