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Chemcial Industry and Engineering 2016, Vol. 33 Issue (2) :41-44    DOI: 10.13353/j.issn.1004.9533.20141040
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Influences of Active Components Content on Cationic Polymerization for C9 Petroleum Resin
Wu Lihong1,2,3, Li Yonghong1,2,3
1. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China;
2. Key Laboratory for Green Chemical Technology of State Education Ministry, Tianjin 300072, China;
3. National Engineering Research Center for Distillation Technology, Tianjin 300072, China

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Abstract 

The cationic polymerizations of pure components simulated C9 fraction were carried out in the presence of various active components in the polymerization systems. The effects of active components content on the properties of C9 petroleum resins were investigated. The C9 petroleum resins with different dicyclopentadiene content were characterized by FI-IR. The results showed that the increasing content of indene and dicyclopentadiene both improved the softening point. However, dicyclopentadiene took part in the copolymerization and introduced unsaturated double bonds into C9 resin. The thermo-oxidative degradation of unstable double bonds contributed to the color of petroleum resins.

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Wu Lihong
Li Yonghong
KeywordsC9 petroleum resin;   active components;   color;   dicyclopentadiene;   cationic polymerization     
Received 2014-05-30;
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Wu Lihong, Li Yonghong.Influences of Active Components Content on Cationic Polymerization for C9 Petroleum Resin[J]  Chemcial Industry and Engineering, 2016,V33(2): 41-44
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