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Chemcial Industry and Engineering 2016, Vol. 33 Issue (2) :37-40    DOI: 10.13353/j.issn.1004.9533.20141034
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Photoluminescence Performance and Preparation of CdSe/PANI Composite Films by Potential Controlled Electrodeposition
Wang Hongzhi, Lu Jing, Li Jian, Yao Suwei, Zhang Weiguo
Sugiyama Laboratory of Surface Technology, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China

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Abstract 

With PANI as the carrier,CdSe/PANI composite films were prepared by potential controlled electrodeposition method. The morphology, crystal structure and optic properties of the films were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and luminescence spectrum. SEM images show that the grain size of CdSe in CdSe/PANI composite films is 150—200 nm,and the grain size increases with the increase of electroplating time. X-ray diffraction result showed that CdSe/PANI composite films contained two kinds of crystals and the crystal structure of CdSe/PANI composite films didn't alter with the changes of its thickness. The luminescence spectrum showed that photoluminescence properties of CdSe/PANI composite films were greater than those of the CdSe films and PANI films. Compared with CdSe film,the existence of PANI in composite films had a role of the carrier and significantly enhanced the photoluminescence properties of CdSe,and led to the photoluminescence emission peak position red-shifted obviously.

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Articles by authors
Wang Hongzhi
Lu Jing
Li Jian
Yao Suwei
Zhang Weiguo
KeywordsPANI;   CdSe;   electrodeposition;   composite film;   photoluminescence     
Received 2014-03-14;
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Wang Hongzhi, Lu Jing, Li Jian, Yao Suwei, Zhang Weiguo.Photoluminescence Performance and Preparation of CdSe/PANI Composite Films by Potential Controlled Electrodeposition[J]  Chemcial Industry and Engineering, 2016,V33(2): 37-40
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