Abstract As fractional crystallization has been developed successfully, the study of solid-liquid equilibrium becomes increasingly attractive. In this work, the solid-liquid equilibrium data and heat of mixing (excess enthalpy) of benzene-cyclohexane system were measured and a method for predicting solid-liquid epuilibrium of simple eutectic systems from excess enthalpy was proposed, The calculated results were compared with the experimental data, showing the validity of the proposed method.
Jin Ke-Xin TianJin University Department of Chemical Engineering Yao Yun-Bin Zhejiang Institute of Technology,Department of Chemical Engineering.Predicting Solid-Liquid Equilibrium of Benzene-Cyclohexane System From Excess Enthalpy[J] Chemcial Industry and Engineering, 1986,V3(3): 1-5