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��ѧ��ҵ�빤�� 2006, Vol. 23 Issue (3) :265-270    DOI:
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Review on Hydroformylation of Higher Olefins
MA Zhan-hua,LIU Xue-nuan,YANG Guo-hua(College of Chemistry and Chemical Engineering,China University of Petroleum,Shandong Dongying 257061,China)
(College of Chemistry and Chemical Engineering,China University of Petroleum,Shandong Dongying 257061,China

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Abstract�� Water-soluble rhodium-phosphine complexes have been successfully applied in lower olefin hydroformylation.For higher olefin that has poor solubility in water,the hydroformylation reaction rate is much less than short-chain alkenes.This review covers the recent advances in Rh-catalysed hydroformylation of higher olefin,most of investigations in this field focus on the synthesis of new effective phosphine ligands and new catalysis systems.In particular,the developments of new-style reaction system,such as water-soluble phosphine in two-phase catalysis system,the supported catalysts,fluorous biphase system,non-aqueous ionic liquids catalysis and hydroformylation in supercritical carbon dioxide were mainly introduced in this paper.
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Received 2006-05-15; published 2006-05-15
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��ռ��;��ѩů;�����;.��̼ϩ����������о���չ[J].  ��ѧ��ҵ�빤��, 2006,23(3): 265-270
MA Zhan-hua,LIU Xue-nuan,YANG Guo-hua.Review on Hydroformylation of Higher Olefins[J].  Chemcial Industry and Engineering, 2006,23(3): 265-270
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