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化学工业与工程
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��ѧ��ҵ�빤�� 1998, Vol. 15 Issue (4) :27-31    DOI:
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Study on the Catalyst for the Synthesis of Piperazine
Wang Duolu Xu Zhengshuang Chen Ligong Feng Yaqing Zhu Yuansheng Sun Chunguang Yu Yunyong
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Abstract�� This paper is concerned about the catalyst for the synthesis of piperazine with N (�� hydroxyl ethyl) ethylenediamine (HEDA) as raw material.A new supported copper catalyst with high reactivity and selectivity was developed.In the presence of Cu Cr Mn/�� Al 2O 3 catalyst and under hydrogen pressure at 180��,the reaction proceeded effectively to give piperazine in 2 hours with a yield as high as 88%,while the conversion was over 98%.
Keywords�� supported copper catalyst catalytic amination cyclization selectivity     
Received 1998-10-15;
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����»,����˫,������,������,ףԴ��,�ﴺ��,������.��຺ϳ��д߻������о�[J].  ��ѧ��ҵ�빤��, 1998,15(4): 27-31
Wang Duolu Xu Zhengshuang Chen Ligong Feng Yaqing Zhu Yuansheng Sun Chunguang Yu Yunyong .Study on the Catalyst for the Synthesis of Piperazine[J].  Chemcial Industry and Engineering, 1998,15(4): 27-31
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