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化学工业与工程
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��ѧ��ҵ�빤�� 2001, Vol. 18 Issue (2) :63-70    DOI:
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Study on the Condition of Phase Separation in Multicomponent Solution
WANG Hong bing, YANG Zhi cai, CUI Xian bao, QU Hong mei (Cemical Engineering Research Center, Tianjin University, Tianjjin 300072, China)
(Cemical Engineering Research Center, Tianjin University, Tianjjin 300072, China

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ժҪ ����ͨ�����͵�UNIQUAC���� ,����NEWTON RAPHSON�������˶�Ԫ����Ԫ����ԪҺҺƽ�����ݡ����з��� ,�����в��ֻ���������ֵĻ��ϵ������ͻ��ʱ ,�����ϵ�ͻ���ֲַ�����Ϊ�� ,������Ϊ���в��ֻ�����ֻ��ϵ����ͻ�����Ϊ����Ԫ��Һ������оݡ�
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Abstract�� In this paper, by calculation of the modified UNIQUAC equation, we have acquired the result of binary, ternary and quartery solution Liquid Liquid equilibrium data with Netwon Raphson method. When activity coefficient of some components with partly miscible solution have a increasation steeply, this solution will become two liquid phase. So the condition of phase separation for multicomponent solutions is that activity coefficient of some components have a increasation steeply at phase interface with partly miscible solution.
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Received 2001-03-15; published 2001-03-15
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�����,��־��,���ֱ�,����÷.����Ԫ��Һ����������̽��[J].  ��ѧ��ҵ�빤��, 2001,18(2): 63-70
WANG Hong bing, YANG Zhi cai, CUI Xian bao, QU Hong mei .Study on the Condition of Phase Separation in Multicomponent Solution[J].  Chemcial Industry and Engineering, 2001,18(2): 63-70
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