面向CO<sub>2</sub>分离的混合基质膜研究进展

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摘要 CO₂分离膜技术是有效减少温室气体排放和能源气体净化的重要手段。设计制备新型混合基质膜(Mixed matrix membranes,MMMs)是同时提高膜的渗透性和选择性的有效途径。MMMs在多种膜分离材料中表现出了优异的CO₂分离性能,并且其具有潜在的克服trade-off效应的前景,因此被研究者广泛关注。MMMs中的填充剂对其分离性能起到至关重要的作用。首先介绍了MMMs中CO₂的传递机制,从传统型填充剂和新型填充剂入手,总结了近年来MMMs中不同种类的填充剂在膜基质中起到的作用以及对CO₂分离性能影响的研究进展。最后,对MMMs用于CO₂分离未来的发展进行了展望。

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	俞江南
	李康
	陈飞
	王军
	李雪琴

关键词：混合基质膜填充剂 CO₂分离

Abstract： CO₂ separation membrane technology is an important strategy to effectively reduce greenhouse gas emissions and energy gas purification. The design of novel mixed matrix membranes (MMMs) is an effective way to improve their permeability and selectivity. MMMs show an excellent CO₂ separation performance in a variety of membrane materials, and they have potential prospects to overcome trade-off effect, and they have been widely attention by researchers. The filler plays an important role in MMMs for improving separation performance. This paper first introduces the transport mechanism of CO₂ in MMMs, and it starts with the traditional fillers and the new fillers. Furthermore, it summarizes the functions of different fillers in MMMs in the membrane matrix and the research progress of their impact on CO₂ separation performance in recent years. Finally, the future development of MMMs for CO₂ separation is prospected.

Keywords： mixed matrix membrane filler CO₂ separation

Received 2023-01-11;

Fund:第七师-石河子大学科技创新专项项目,高效二氧化碳捕集与第七师范围内CCUS前景评价(QS2022004)。

About author: 俞江南(1997-),女,硕士研究生,现从事气体分离膜的研究。

引用本文:

俞江南, 李康, 陈飞, 王军, 李雪琴.面向CO₂分离的混合基质膜研究进展[J]. 化学工业与工程, 2023,40(3): 74-83

YU Jiangnan, LI Kang, CHEN Fei, WANG Jun, LI Xueqin.Research progress of mixed matrix membranes for CO₂ separation[J]. Chemcial Industry and Engineering, 2023,40(3): 74-83

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