反渗透膜的研究进展与展望

摘要

反渗透具有低能耗、高效率等突出优点,是目前应用最为广泛的分离技术之一。反渗透膜的性能是影响反渗透过程效率的决定因素,反渗透膜的研制一直是国内外膜领域的研究热点。特别是近年来,石墨烯、碳纳米管等新型材料展现出优异的水传递行为,成为新型反渗透膜材料的研究热点。本论文回顾了反渗透膜的研制发展历程,介绍了不同单体通过界面聚合反应成膜的研究进展,综述了国内外新型混合基质膜和无机分子筛反渗透膜材料及其成膜研究,最后提出了新型反渗透膜的研究方向。

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	张雨山
	魏杨杨
	曹震
	张慧峰
	姚颖

关键词：反渗透；薄层复合膜；芳香聚酰胺膜；分子筛膜；混合基质膜

Abstract：

Reverse osmosis process features in higher efficacy and lower energy consumption and was widely applied in water treatment and desalination process. Reverse osmosis membranes plays a pivotal role in determining the reverse osmosis process performance. The development of novel membranes with better salt rejection, flux and antifouling ability has attracted intensive research effort. Some materials, such as graphene and carbon nanotube, exhibited extraordinary behavior in water transport, making them promising materials for next-generation reverse osmosis membranes. In this paper, the history of reverse osmosis membrane development was briefly reviewed. Different monomers available for reverse osmosis membrane preparation via interfacial polymerization process were summarized and their regarding membrane performances were analyzed. The newly developed mixed matrix membranes based on the incorporation of nanoparticles were introduced as well as the zeolite membranes for water desalination. At last, some research topics on reverse osmosis membrane were proposed.

Keywords： reverse osmosis； thin film composite membrane； polyamide membrane； zeolite membranes； mixed matrix membranes

Received 2015-07-01;

Fund:

国家自然科学基金(21276055),海洋行业公益性行业专项经费项目(201505006-3),中央级公益类科研院所基本科研业务费项目(K-JBYWF-2011-G12,K-JBYWF-2013-G8)。

Corresponding Authors: 张雨山,E-mail:yushanzhang@hotmail.com。 Email: yushanzhang@hotmail.com

About author: 张雨山(1962-),男,博士,研究员,博士生导师,主要从事海水利用技术和膜分离技术研究。

引用本文:

张雨山, 魏杨杨, 曹震, 张慧峰, 姚颖.反渗透膜的研究进展与展望[J]. 化学工业与工程, 2015,32(5): 8-19

Zhang Yushan, Wei Yangyang, Cao Zhen, Zhang Huifeng, Yao Ying.Progress and Prospect in the Development of Reverse Osmosis Membrane Technology[J]. Chemcial Industry and Engineering, 2015,32(5): 8-19

[1] Kim S J, Ko S H, Kang K H, et al. Direct seawater desalination by ion concentration polarization[J]. Nature Nanotechnology, 2010, 5(4): 297-301
[2] Wangnick K. IDA worldwide desalting plants inventory[R]. Produced by Wangnick Consulting for the International Desalination Association, Gnarrenburg, Germany, 2002
[3] 冯厚军, 谢春刚. 中国海水淡化技术研究现状与展望[J]. 化学工业与工程, 2010, 27(2): 103-109 Feng Houjun, Xie Chungang. Status and prospect of chinese seawater desalination technology[J]. Chemcial Industry and Engineering, 2010, 27(2): 103-109(in Chinese)
[4] Xu G, Wang J, Li C. Strategies for improving the performance of the polyamide thin film composite (PA-TFC) reverse osmosis (RO) membranes: Surface modifications and nanoparticles incorporations[J]. Desalination, 2013, 328: 83-100
[5] Mezher T, Fath H, Abbas Z, et al. Techno-Economic assessment and environmental impacts of desalination technologies[J]. Desalination, 2011, 266(1): 263-273
[6] Elimelech M, Phillip W A. The future of seawater desalination: Energy, technology, and the environment[J]. Science, 2011, 333(6 043): 712-717
[7] Kang G, Cao Y. Development of antifouling reverse osmosis membranes for water treatment: A review[J]. Water Research, 2012, 46(3): 584-600
[8] Cadotte J E, Petersen R J, Larson R E, et al. A new thin-film composite seawater reverse osmosis membrane[J]. Desalination, 1980, 32: 25-31
[9] Lee K P, Arnot T C, Mattia D. A review of reverse osmosis membrane materials for desalination—Development to date and future potential[J]. Journal of Membrane Science, 2011, 370(1): 1-22
[10] Mulder M. 膜技术基本原理[M]. 李琳译. 北京:清华大学出版社,1999
[11] 汪猛, 王湛, 李政雄. 膜材料及其制备[M]. 北京: 化学工业出版社, 2003
[12] Rustemeyer P. 1. History of CA and evolution of the markets[C]//Macromolecular Symposia, WILEY-VCH Verlag, 2004, 208(1): 1-6
[13] Fischer S, Thümmler K, Volkert B, et al. Properties and applications of cellulose acetate[C]//Macromolecular Symposia, WILEY-VCH Verlag, 2008, 262(1): 89-96
[14] Li D, Wang H. Recent developments in reverse osmosis desalination membranes[J]. Journal of Materials Chemistry, 2010, 20(22): 4 551-4 566
[15] Xu G R, Wang J, Li C. Strategies for improving the performance of the polyamide thin film composite (PA-TFC) reverse osmosis (RO) membranes: Surface modifications and nanoparticles incorporations[J]. Desalination, 2013, 328: 83-100
[16] 李国东, 王薇, 李凤娟, 等. 反渗透膜的研究进展[J]. 高分子通报, 2010 (7): 37-42 Li Guodong, Wang Wei, Li Fengjuan, et al. Development of hollow fiber reverse osmosis membrane[J]. Polymer Bulletin, 2010 (7): 37-42(in Chinese)
[17] Chen G, Li S, Zhang X, et al. Novel thin-film composite membranes with improved water flux from sulfonated cardo poly (arylene ether sulfone) bearing pendant amino groups[J]. Journal of Membrane Science, 2008, 310(1): 102-109
[18] Liu L, Yu S, Zhou Y, et al. Study on a novel polyamide-urea reverse osmosis composite membrane (ICIC-MPD): I. Preparation and characterization of ICIC-MPD membrane[J]. Journal of Membrane Science, 2006, 281(1): 88-94
[19] Liu L, Yu S, Wu L, et al. Study on a novel polyamide-urea reverse osmosis composite membrane (ICIC-MPD): II. Analysis of membrane antifouling performance[J]. Journal of Membrane Science, 2006, 283(1): 133-146
[20] Liu L, Yu S, Wu L, et al. Study on a novel antifouling polyamide-urea reverse osmosis composite membrane (ICIC-MPD): III. Analysis of membrane electrical properties[J]. Journal of Membrane Science, 2008, 310(1): 119-128
[21] Wang H, Li L, Zhang X, et al. Polyamide thin-film composite membranes prepared from a novel triamine 3, 5-diamino-N-(4-aminophenyl)-benzamide monomer and m-phenylenediamine[J]. Journal of Membrane Science, 2010, 353(1): 78-84
[22] Konagaya S, Watanabe O. Influence of chemical structure of isophthaloyl dichloride and aliphatic, cycloaliphatic, and aromatic diamine compound polyamides on their chlorine resistance[J]. Journal of Applied Polymer Science, 2000, 76(2): 201-207
[23] Yu S, Liu M, Lü Z, et al. Aromatic-Cycloaliphatic polyamide thin-film composite membrane with improved chlorine resistance prepared from m-phenylenediamine-4-methyl and cyclohexane-1, 3, 5-tricarbonyl chloride[J]. Journal of Membrane Science, 2009, 344(1): 155-164
[24] Yong Z, Sanchuan Y, Meihong L, et al. Polyamide thin film composite membrane prepared from m-phenylenediamine and m-phenylenediamine-5-sulfonic acid[J]. Journal of Membrane Science, 2006, 270(1): 162-168
[25] Kwak S Y, Yeom M O, Roh I J, et al. Correlations of chemical structure, atomic force microscopy (AFM) morphology, and reverse osmosis (RO) characteristics in aromatic polyester high-flux RO membranes[J]. Journal of Membrane Science, 1997, 132(2): 183-191
[26] Kim C K, Kim J H, Roh I J, et al. The changes of membrane performance with polyamide molecular structure in the reverse osmosis process[J]. Journal of Membrane Science, 2000, 165(2): 189-199
[27] Xie W, Geise G M, Freeman B D, et al. Polyamide interfacial composite membranes prepared from m-phenylene diamine, trimesoyl chloride and a new disulfonated diamine[J]. Journal of Membrane Science, 2012, 403: 152-161
[28] Li X, Cao Y, Yu H, et al. A novel composite nanofiltration membrane prepared with PHGH and TMC by interfacial polymerization[J]. Journal of Membrane Science, 2014, 466: 82-91
[29] Arthur S D. Structure-Property relationship in a thin film composite reverse osmosis membrane[J]. Journal of Membrane Science, 1989, 46(2): 243-260
[30] Liu M, Yu S, Qi M, et al. Impact of manufacture technique on seawater desalination performance of thin-film composite polyamide-urethane reverse osmosis membranes and their spiral wound elements[J]. Journal of Membrane Science, 2010, 348(1): 268-276
[31] Li L, Zhang S, Zhang X, et al. Polyamide thin film composite membranes prepared from isomeric biphenyl tetraacyl chloride and m-phenylenediamine[J]. Journal of Membrane Science, 2008, 315(1): 20-27
[32] Li L, Zhang S, Zhang X, et al. Polyamide thin film composite membranes prepared from 3, 4', 5-biphenyl triacyl chloride, 3, 3', 5, 5'-biphenyl tetraacyl chloride and m-phenylenediamine[J]. Journal of Membrane Science, 2007, 289(1): 258-267
[33] Huang X, Xu Z, Huang X, et al. Biomimetic surface modification on polyacrylonitrile-based asymmetric membranes via direct formation of phospholipid moieties[J]. Polymer, 2006, 47(9): 3 141-3 149
[34] Thom V, Jankova K, Ulbricht M, et al. Synthesis of photoreactive α-4-azidobenzoyl-ω-methoxy-poly (ethylene glycol) s and their end-on photo-grafting onto polysulfone ultrafiltration membranes[J]. Macromolecular Chemistry and Physics, 1998, 199(12): 2 723-2 729
[35] Wang J, Pan C, Huang N, et al. Surface characterization and blood compatibility of poly (ethylene terephthalate) modified by plasma surface grafting[J]. Surface and Coatings Technology, 2005, 196(1): 307-311
[36] Kang G, Liu M, Lin B, et al. A novel method of surface modification on thin-film composite reverse osmosis membrane by grafting poly (ethylene glycol)[J]. Polymer, 2007, 48(5): 1 165-1 170
[37] Zhai X, Meng J, Li R, et al. Hypochlorite treatment on thin film composite RO membrane to improve boron removal performance[J]. Desalination, 2011, 274(1): 136-143
[38] Wei X, Wang Z, Zhang Z, et al. Surface modification of commercial aromatic polyamide reverse osmosis membranes by graft polymerization of 3-allyl-5,5-dimethylhydantoin[J]. Journal of Membrane Science, 2010, 351(1): 222-233
[39] Kulkarni A, Mukherjee D, Gill W N. Flux enhancement by hydrophilization of thin film composite reverse osmosis membranes[J]. Journal of Membrane Science, 1996, 114(1): 39-50
[40] Zhao L, Ho W S W. Novel reverse osmosis membranes incorporated with a hydrophilic additive for seawater desalination[J]. Journal of Membrane Science, 2014, 455: 44-54
[41] Zhao L, Chang P, Yen C, et al. High-Flux and fouling-resistant membranes for brackish water desalination[J]. Journal of Membrane Science, 2013, 425: 1-10
[42] Zhao L, Chang P, Ho W. High-Flux reverse osmosis membranes incorporated with hydrophilic additives for brackish water desalination[J]. Desalination, 2013, 308: 225-232
[43] McCloskey B D, Park H B, Ju H, et al. A bioinspired fouling-resistant surface modification for water purification membranes[J]. Journal of Membrane Science, 2012, 413: 82-90
[44] Kim E S, Hwang G, El-Din M G, et al. Development of nanosilver and multi-walled carbon nanotubes thin-film nanocomposite membrane for enhanced water treatment[J]. Journal of Membrane Science, 2012, 394: 37-48
[45] Dong H, Zhao L, Zhang L, et al. High-Flux reverse osmosis membranes incorporated with NaY zeolite nanoparticles for brackish water desalination[J]. Journal of Membrane Science, 2015, 476: 373-383
[46] Chae H R, Lee J, Lee C H, et al. Graphene oxide-embedded thin-film composite reverse osmosis membrane with high flux, anti-biofouling, and chlorine resistance[J]. Journal of Membrane Science, 2015, 483: 128-135
[47] Bao M, Zhu G, Wang L, et al. Preparation of monodispersed spherical mesoporous nanosilica-polyamide thin film composite reverse osmosis membranes via interfacial polymerization[J]. Desalination, 2013, 309: 261-266
[48] Jeong B H, Hoek E M V, Yan Y, et al. Interfacial polymerization of thin film nanocomposites: A new concept for reverse osmosis membranes[J]. Journal of Membrane Science, 2007, 294(1): 1-7
[49] Lee S Y, Kim H J, Patel R, et al. Silver nanoparticles immobilized on thin film composite polyamide membrane: Characterization, nanofiltration, antifouling properties[J]. Polymers for Advanced Technologies, 2007, 18(7): 562-568
[50] 董航, 张林, 陈欢林, 等. 混合基质水处理膜: 材料, 制备与性能[J]. 化学进展, 2014, 26(12): 2 007-2 018 Dong Hang, Zhang Lin, Chen Huanlin, et al. Mixed-Matrix membranes for water treatment: Materials, synthesis and properties[J]. Progress in Chemstry, 2014, 26(12): 2 007-2 018(in Chinese)
[51] Izumi K, Takeo Y, Shinichi N. Appilcation of a zeolite a membrane to reverse osmosis process[J]. Journal of Chemical Engineering of Japan, 2000, 33(2): 333-336
[52] Lin J, Murad S. A computer simulation study of the separation of aqueous solutions using thin zeolite membranes[J]. Molecular Physics, 2001, 99(14): 1 175-1 181
[53] Li L, Dong J, Nenoff T M, et al. Desalination by reverse osmosis using MFI zeolite membranes[J]. Journal of Membrane Science, 2004,243(1/2): 401-404
[54] Khajavi S, Kapteijn F, Jansen J C. Synthesis of thin defect-free hydroxysodalite membranes: New candidate for activated water permeation[J]. Journal of Membrane Science, 2007, 299(1/2): 63-72
[55] Khajavi S, Jansen J C, Kapteijn F. Production of ultrapure water by desalination of seawater using a hydroxy sodalite membrane[J]. Journal of Membrane Science, 2010, 356(1/2): 52-57
[56] Malekpour A, Millani M R, Kheirkhah M. Synthesis and characterization of a NaA zeolite membrane and its applications for desalination of radioactive solutions[J]. Desalination, 2008, 225(1/3): 199-208
[57] Li X, Joseph E R, James K N, et al. NF/RO faujasite zeolite membrane-ammonia absorption solvent hybrid system for potential post-combustion CO₂ capture application[J]. Journal of Membrane Science, 2011, 366(1/2): 220-228
[58] Chowdhury S R, Lamare J, Valtchev V. Synthesis and structural characterization of EMT-type membranes and their performance in nanofiltration experiments[J]. Journal of Membrane Science, 2008, 314(1/2): 200-205
[59] Swenson P, Tanchuk B, Gupta A. Pervaporative desalination of water using natural zeolite membranes[J]. Desalination, 2012, 285: 68-72
[60] Lu J, Liu N, Li L, et al. Organic fouling and regeneration of zeolite membrane in wastewater treatment [J]. Separation and Purification Technology, 2010, 72(2): 203-207
[61] Li L, Lee R. Purification of produced water by ceramic membranes: Material screening, process design and economics[J]. Separation Science and Technology, 2009, 44(15): 3 455-3 484
[62] Pendergast M T M, Hoek E M V. A review of water treatment membrane nanotechnologies [J]. Energy & Environmental Science, 2011, 4(6): 1 946-1 971
[63] Li L, Dong J, Tina M N. Transport of water and alkali metal ions through MFI zeolite membranes during reverse osmosis[J]. Separation and Purification Technology, 2007, 53(1): 42-48
[64] Li L, Li N, Brian M, et al. Enhanced water permeation of reverse osmosis through MFI-type zeolite membranes with high aluminum contents[J]. Industry and Engineering of Chemistry Research, 2007, (46): 1 584-1 589
[65] Li L, Li N, Brian M, et al. Influence of counter ions on the reverse osmosis through MFI zeolite membranes: Implications for produced water desalination[J]. Desalination, 2008, 228(1/3): 217-225
[66] Swenson P, Tanchuk B, Bastida E. Water desalination and de-oiling with natural zeolite membranes-potential application for purification of SAGD process water[J]. Desalination, 2012, 286: 442-446
[67] Kazemimoghadam M, Mohammadi T. Synthesis of MFI zeolite membranes for water desalination[J]. Desalination, 2007, 206(1/3): 547-553
[68] Churl H C, Ka Y O, Si K K, et al. Pervaporative seawater desalination using NaA zeolite membrane: mechanisms of high water flux and high salt rejection[J]. Journal of Membrane Science, 2011, 371(1/2): 226-238
[69] Bo Z, Jun H K, Yong-Han N, et al. Temperature and pressure effects of desalination using a MFI-type zeolite membrane[J]. Membranes, 2013, (3): 155-168
[70] Covarrubias C, García R, Rriagada R, et al. Removal of trivalent chromium contaminant from aqueous media using FAU-type zeolite membranes[J]. Journal of Membrane Science, 2008, 312(1/2): 163-173
[71] Bo Z, Hong Z, Nicolas M, et al. Desalination of seawater ion complexes by MFI-type zeolite membranes: Temperature and long term stability[J]. Journal of Membrane Science, 2014, (453): 126-135
[72] David C, Jeffrey C G. Water desalination across nanoporous graphene[J]. Nano Letters, 2012, 12(7): 3 602-3 608
[73] Corry B. Designing carbon nanotube membranes for efficient water desalination[J]. J Physhem B, 2008, 112:1 427-1 434
[74] Surwade S P, Smirnov S N, Vlassiouk I V, et al. Water desalination using nanoporous single-layer graphene[J]. Nature Nanotechnology, 2015, 10(5): 459-464
[75] Hu Z, Chen Y, Jiang J. Zeolitic imidazolate framework-8 as a reverse osmosis membrane for water desalination: Insight from molecular simulation [J]. Journal of Chemical Physics, 2011, 134 (13):134 705-134 710
[76] Wei X, Wang Z, Chen J, et al. A novel method of surface modification on thin-film-composite reverse osmosis membrane by grafting hydantoin derivative[J]. Journal of Membrane Science, 2010, 346(1): 152-162
[77] Kim Y K, Lee S Y, Kim D H, et al. Preparation and characterization of thermally crosslinked chlorine resistant thin film composite polyamide membranes for reverse osmosis[J]. Desalination, 2010, 250(2): 865-867
[78] Koo J Y, Kim N. Composite polyamide reverse osmosis membrane and method of producing the same: US, 6015495[P]. 2000-01-18
[79] Hirose M, Ohara T, Ando M. High permeable composite reverse osmosis membrane: US, 6171497[P]. 2001-01-09
[80] Kuehne M A, Song R, Li N, et al. Flux enhancement in TFC RO membranes[J]. Environmental Progress, 2001, 20(1): 23-26
[81] Chau M M. Reverse osmosis; water deslination: US, 4950404[P]. 1990-08-21
[82] Kim S H, Kwak S Y, Sohn B H, et al. Design of TiO₂ nanoparticle self-assembled aromatic polyamide thin-film-composite (TFC) membrane as an approach to solve biofouling problem[J]. Journal of Membrane Science, 2003, 211(1): 157-165
[83] Safarpour M, Khataee A, Vatanpour V. Thin film nanocomposite reverse osmosis membrane modified by reduced graphene oxide/TiO₂ with improved desalination performance[J]. Journal of Membrane Science, 2015, 489: 43-54
[84] Jeong B H, Hoek E M V, Yan Y, et al. Interfacial polymerization of thin film nanocomposites: A new concept for reverse osmosis membranes[J]. Journal of Membrane Science, 2007, 294(1): 1-7
[85] Kong C, Shintani T, Tsuru T. "Pre-seeding"-Assisted synthesis of a high performance polyamide-zeolite nanocomposite membrane for water purification[J]. New Journal of Chemistry, 2010, 34(10): 2 101-2 104
[86] 芦瑛, 赵海洋, 张林, 等. 含氧化石墨烯混合基质反渗透复合膜的制备及性能研究[J]. 中国工程科学, 2014, 16(7): 84-88 Lu Ying, Zhao Haiyang, Zhang Lin, et al. Preparation and characterization of mixed matrix RO membrane of polyamide and GO[J]. Engineering Sciences, 2014, 16(7): 84-88(in Chinese)
[87] 瞿新营, 董航, 张林, 等. 沸石/聚酰胺反渗透复合膜的制备[J]. 化学工程, 2011, 39(2): 56-59 Qu Xinying, Dong Hang, Zhang Lin, et al. Preparation of zeolite/polyamide nanocomposite reverse osmosismembrane[J]. Chemical Engineering(China), 2011, 39(2): 56-59(in Chinese)
[88] Zhao Y, Qiu C, Li X, et al. Synthesis of robust and high-performance aquaporin-based biomimetic membranes by interfacial polymerization-membrane preparation and RO performance characterization[J]. Journal of Membrane Science, 2012, 423: 422-428
[89] Park J, Choi W, Kim S H, et al. Enhancement of chlorine resistance in carbon nanotube based nanocomposite reverse osmosis membranes[J]. Desalination and Water Treatment, 2010, 15(1/3): 198-204
[90] Yang H, Lin J, Huang C. Application of nanosilver surface modification to RO membrane and spacer for mitigating biofouling in seawater desalination[J]. Water Research, 2009, 43 (15): 3 777-3 786
[91] Kim I C, Ka Y H, Park J, et al. Preparation of fouling resistant nanofiltration and reverse osmosis membranes and their use for dyeing wastewater effluent[J]. Journal of Industrial and Engineering Chemistry, 2004, 10(1): 115-121
[92] Wu D, Liu X, Yu S, et al. Modification of aromatic polyamide thin-film composite reverse osmosis membranes by surface coating of thermo-responsive copolymers P (NIPAM-co-Am). I: Preparation and characterization[J]. Journal of Membrane Science, 2010, 352(1): 76-85
[93] Sarkar A, Carver P I, Zhang T, et al. Dendrimer-Based coatings for surface modification of polyamide reverse osmosis membranes[J]. Journal of Membrane Science, 2010, 349(1): 421-428
[94] Kim S G, Chun J H, Chun B H, et al. Preparation, characterization and performance of poly (aylene ether sulfone)/modified silica nanocomposite reverse osmosis membrane for seawater desalination[J]. Desalination, 2013, 325: 76-83
[95] Zhao L, Ho W S W. Novel reverse osmosis membranes incorporated with a hydrophilic additive for seawater desalination[J]. Journal of Membrane Science, 2014, 455: 44-54
[96] Kasemset S, Lee A, Miller D J, et al. Effect of polydopamine deposition conditions on fouling resistance, physical properties, and permeation properties of reverse osmosis membranes in oil/water separation[J]. Journal of Membrane Science, 2013, 425: 208-216
[97] Yu S, Yao G, Dong B, et al. Improving fouling resistance of thin-film composite polyamide reverse osmosis membrane by coating natural hydrophilic polymer sericin[J]. Separation and Purification Technology, 2013, 118: 285-293
[98] Nikkola J, Liu X, Li Y, et al. Surface modification of thin film composite RO membrane for enhanced anti-biofouling performance[J]. Journal of Membrane Science, 2013, 444: 192-200
[99] Zhou Y, Yu S, Gao C, et al. Surface modification of thin film composite polyamide membranes by electrostatic selfdeposition of polycations for improved fouling resistance[J]. Separation and Purification Technology, 2009, 66(2): 287-294
[100] Ishigami T, Amano K, Fujii A, et al. Fouling reduction of reverse osmosis membrane by surface modification via layer-by-layer assembly[J]. Separation and Purification Technology, 2012, 99: 1-7