中空棒状MOF及其衍生的磷酸盐类电池型电容性能的研究

摘要为获得具有更高比容量的超级电容器正极材料，在单一金属有机框架材料的基础上研究多元金属有机框架及其衍生物的电容性能，以不同的金属元素（Ni、Co）比例制备多元金属有机框架材料，进而得到衍生的纳米级中空棒状金属磷酸盐。得到金属元素比例n（Ni）：n（Co）=8：1时具有最大的比电容值895.29 F·g^-1。

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	虞圣盼
	黄成德

关键词：金属有机框架金属磷酸盐超级电容器纳米材料

Abstract： In order to obtain a supercapacitor positive electrode material with a higher specific capacity, the capacitance performance of polymetallic organic frameworks and their derivatives was studied on the basis of a single metal-organic framework material(MOF), and polymetallic organics were prepared with different proportions of metal elements (Ni, Co). The MOF material is further obtained as a nano-scale hollow rod-shaped metal phosphate. When the metal element ratio of Ni:Co is 8:1 in the raw material,the metal phosphate has the maximum specific capacitance value of 895.29 F·g^-1.

Keywords： metal organic framework； metal phosphate； supercapacitor； nanomaterial

Received 2020-01-10;

Fund:天津市自然科学基金（16JCYBJC21100）。

Corresponding Authors: 黄成德,E-mail:cdhuang@tju.edu.cn。 Email: cdhuang@tju.edu.cn

About author: 虞圣盼(1995-),男,硕士研究生,现从事超级电容器方面的研究。

引用本文:

虞圣盼, 黄成德.中空棒状MOF及其衍生的磷酸盐类电池型电容性能的研究[J]. 化学工业与工程, 2020,37(5): 53-63

Yu Shengpan, Huang Chengde.Capacitor Performance of Hollow Rod-Shaped Metal-Organic Framework and its Derived Metal Phosphate[J]. Chemcial Industry and Engineering, 2020,37(5): 53-63

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