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化学工业与工程 2014, Vol. 31 Issue (1) :28-32    DOI: 10.13353/j.issn.1004.9533.2014.01.006
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负载金属银纳米颗粒的石墨烯吡咯烷衍生物的制备、表征及应用
 彭小俊, 远洋, 郜源, 张凤宝
(天津大学化工学院,天津 300072)
Synthesis, Characterization and Application of the New Graphene-Pyrrolidine Materials with Ag Nanoparticles
 PENG  Xiao-Jun, YUAN  Yang, GAO  Yuan, ZHANG  Feng-Bao
(School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China)

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摘要 用环加成的方法对石墨烯进行功能化,制备多巯基的石墨烯基复合材料,并利用巯基易与金属结合的性质,在巯基上负载金属银纳米颗粒。通过TEM观测金属纳米颗粒的分布;通过XPS分析产物的元素含量、金属银纳米颗粒的负载方式以及金属银纳米颗粒的价态;并通过催化还原对硝基苯酚的反应,验证其催化活性。
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彭小俊
远洋
郜源
张凤宝
关键词石墨烯   环加成反应   巯基   金属银纳米颗粒   催化活性     
Abstract: Functionalized by cycloaddition reactions, the multi-sulfhygryl graphene-based nanomaterials were prepared. The nature of the sulfhygryl group made it easy to react with single metallic sliver nanoparticles. The distribution of the metal nanoparticles was available in TEM observation. XPS analysis showed the element content of the final product, the nucleation model and the valence state of single metallic silver. Through the catalytic reduction reaction of  p-nitrophenol, the catalytic property of final product was verified.
Keywordsgraphene   cycloaddition   sulfhydryl group   silver nanoparticle   catalytic activity     
Received 2013-05-16;
Corresponding Authors: 张凤宝,电话:(022)27408778,E-mail:fbzhang@tju.edu.cn。     Email: fbzhang@tju.edu.cn
About author: 彭小俊(1989-),女,现从事碳纳米材料方面的研究。
引用本文:   
彭小俊, 远洋, 郜源, 张凤宝.负载金属银纳米颗粒的石墨烯吡咯烷衍生物的制备、表征及应用[J].  化学工业与工程, 2014,31(1): 28-32
PENG Xiao-Jun, YUAN Yang, GAO Yuan, ZHANG Feng-Bao.Synthesis, Characterization and Application of the New Graphene-Pyrrolidine Materials with Ag Nanoparticles[J].  Chemcial Industry and Engineering, 2014,31(1): 28-32
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