[an error occurred while processing this directive]
化学工业与工程
 首页 |  在线投稿 |  期刊介绍 |  编 委 会 |  投稿指南 |  期刊订阅 |  下载中心 |  出版伦理 |  联系我们 |  English
化学工业与工程 2012, Vol. 29 Issue (2) :9-14    DOI:
化学反应与工艺 最新目录 | 下期目录 | 过刊浏览 | 高级检索 << | >>
苯乙烯-顺酐共聚物的合成优化及其降黏效果
张志强, 姜翠玉, 宋林花, 张琦
中国石油大学理学院
Synthesis of StyreneMaleic Anhydride Copolymer and Its  Effect on Viscosity Reduction
 ZHANG  Zhi-Qiang, JIANG  Cui-Yu, SONG  Lin-Hua, ZHANG  Qi
Academy of Science,China University of Petroleum

摘要
参考文献
相关文章
Download: PDF (421KB)   HTML ()   Export: BibTeX or EndNote (RIS)      Supporting Info
摘要 在偶氮二异丁腈(AIBN)引发下,以甲苯为溶剂,合成了苯乙烯(St)顺酐(MA)二元共聚物。探索了单体配比、反应温度、引发剂用量、溶剂用量等合成条件对共聚物相对分子质量的影响。并对不同相对分子质量的共聚物进行酯化改性,用于塔河稠油的降黏研究,试验发现特性黏数在85 mL/g左右,MA质量分数为30%时,降黏效果最好,降黏率为4408%。要得到上述产品的适宜条件为:反应温度为70 ℃,引发剂用量为油质量的02%,溶剂用量为单体总质量的60%,n(St)∶n(MA)为2∶1。
Service
把本文推荐给朋友
加入我的书架
加入引用管理器
Email Alert
RSS
作者相关文章
张志强
姜翠玉
宋林花
张琦
关键词苯乙烯   顺酐   共聚物   相对分子质量   降黏     
Abstract: The binary copolymer of styrene(St)maleic anhydride(MA) was synthesized with AIBN as initiator and toluene as solvent. The influences of polymerization temperature, initiator dosage, solvent dosage and ratio of styrene to maleic anhydride on polymer relative molecular mass were discussed. The different relative molecular mass copolymer were modified by esterification and used in the viscosity reduction of Tahe heavy oil. The experimental results showed that the copolymer with intrinsic viscosity about 85 mL/g and the content of MA at 30% had the best effect, with viscosity reduction rate of 44.08%. To get the above products,the suitable experimental condition was : reaction temperature was 70 ℃, initiator dosage was 0.2%, solvent dosage was 60%, n(St)∶nMA)=2∶1.
Keywordsstyrene   maleic anhydride   copolymer   relative molecular mass   viscosity reduction     
Received 2011-12-26;
Corresponding Authors: 姜翠玉     Email: cyjiang@upc.edu.cn
About author: 张志强(1986-),男,山东济南人,硕士研究生,研究方向:油田化学。
引用本文:   
张志强, 姜翠玉, 宋林花, 张琦.苯乙烯-顺酐共聚物的合成优化及其降黏效果[J].  化学工业与工程, 2012,29(2): 9-14
ZHANG Zhi-Qiang, JIANG Cui-Yu, SONG Lin-Hua, ZHANG Qi.Synthesis of StyreneMaleic Anhydride Copolymer and Its  Effect on Viscosity Reduction[J].  Chemcial Industry and Engineering, 2012,29(2): 9-14
Copyright 2010 by 化学工业与工程