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化学工业与工程 2011, Vol. 28 Issue (2) :40-44    DOI:
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小球藻对海水中Pb2+的生物吸附研究
寇希元,张晓青,张爱君,张雨山,王静
国家海洋局天津海水淡化与综合利用研究所,天津 300192
Biosorption of Pb2+ in Seawater by Chlorella Pyrenoidosa
KOU Xiyuan, ZHANG Xiaoqing, ZHANG Aijun, ZHANG Yushan, WANG Jing
Tianjin Institute of Seawater Desalination and Multipurpose Utilization, State Oceanic Administration, Tianjin 300192,China

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摘要 研究了小球藻对海水中Pb2+吸附的特性,探讨了吸附热力学和动力学。考察了吸附剂用量、pH值、温度、Pb2+的起始浓度和时间等对吸附的影响。研究表明,在试验浓度范围内,吸附剂的用量对吸附率的影响不大;pH值对吸附影响较大,小球藻吸附Pb2+的适宜pH值为4~6;小球藻对Pb2+吸附的吸附量与其浓度呈正相关;在25 ℃时,小球藻对Pb2+的吸附非常快,60 min达到吸附平衡,其动力学数据符合准二级动力学模型,对Pb2+的吸附可以用Freundlich等温方程来描述,对含铅污染的海水净化处理具有探索性及指导性意义
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寇希元
张晓青
张爱君
张雨山
王静
关键词生物吸附   小球藻   动力学   Pb2+     
Abstract: The process of biosorption of Pb2+ by chlorella pyrenoidosa, its adsorption thermodynamics and adsorption kinetics were investigated in this paper.The effects of biomass concentration,pH value,temperature,initial Pb2+ concentration and adsorption time on biosorption were studied respectively. Result showed that the adsorption rate did not fluctuate remarkably when the biomass concentration varied at the range of 05 g/L to 4 g/L.The biosorption was significantly affected by initial solution pH and the optimal pH value of biosorption of  Pb2+ by chlorella pyrenoidosa was 4—6. On the other hand,the adsorption quantity of Pb2+ by chlorella pyrenoidosa was positively correlated with the initial concentration of Pb2+. Kinetic studies revealed that the biosorption was rapid,the absorption reached its equilibrium within 60 min at 25 ℃.These experimental results could be accurately described by second order kinetic model.The Freundlich model fitted the experimental data quite well.This can give references to purification process of seawater contained lead.
Keywordsbiosorption   chlorella pyrenoidosa   kinetics   Pb2+     
Fund:

中央级公益性科研院所专项资金项目(KJBYWF2009T04);国家“十一五”科技支撑计划课题资助项目(2006BAB03A08)。

引用本文:   
寇希元, 张晓青, 张爱君, 张雨山, 王静.小球藻对海水中Pb2+的生物吸附研究[J].  化学工业与工程, 2011,28(2): 40-44
KOU Xi-Yuan, ZHANG Xiao-Qing, ZHANG Ai-Jun, ZHANG Yu-Shan, WANG Jing.Biosorption of Pb2+ in Seawater by Chlorella Pyrenoidosa[J].  Chemcial Industry and Engineering, 2011,28(2): 40-44
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