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化学工业与工程 2011, Vol. 28 Issue (2) :24-28    DOI:
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燃料电池PtRu/C催化剂CO容限能力的表征
赵黎华1,梁宝臣21,贾晓川1,张江萍1,曹丽静1,张寅豹1, 李翔1
1.中国天津出入境检验检疫局工业产品安全技术中心, 天津 300191; 2.天津理工大学生化学院, 天津 300191
Evaluation of CO Tolerant Ability of PtRu/C Catalysts for Fuel Cells
1.Technical Center for Safety of Industrial Products,  Tianjin EntryExit Inspection and Quarantine Bureau of P. R. China,
Tianjin 300191, China; 2.Department of Biochemical and Chemical Engineering, Tianjin University of Technology, Tianjin 300191, China

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摘要 采用反胶束法制备了质子交换膜燃料电池(PEMFC)用PtRu/C催化剂。反胶束体系由水相、环己烷、表面活性剂SBS和正辛醇组成,体系中n(水)/n(表面活性剂)为7,m(表面活性剂)/m(环己烷)为0115,还原剂为KHB4溶液。在PEMFC连续运行条件下对所制备的催化剂性能进行考察。分别以纯氢和含不同浓度CO的氢气为燃料气,测试PEMFC的Vt曲线和IV特性,以此来评价电催化剂的活性、稳定性和对CO的容限能力。试验结果与Johnson Matthey公司的同类产品进行了比较。
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赵黎华
梁宝臣
贾晓川
张江萍
曹丽静
张寅豹
李翔
关键词质子交换膜燃料电池   PtRu/C催化剂   电催化活性   CO容限能力     
Abstract: PtRu/C elecrtrocataylsts for PEMFC was prepared using reverse micelles method.The reverse micelles system was composed of water,cyclohexane,surfactant SBS and noctanol, the molar ratio of H2O to SBS and the mass ratio of SBS to cyclohexane were chosen as 7 and 0.115,respectively,and KBH4 solution was used as reductant.The performance of PtRu/C catalysts were investigated under a continue runing condition of a single PTMFC.The electrocatalytic activity,stability and CO tolerant ability of catalysts were evaluated by Vt curves and IV chariticristics of PEMFC.The results were compared with the commercial PtRu/C catalyst(JM Corporation).
Keywordsproton exchange membrane fuel cell(PEMFC)   PtRu/C catalysts   electrocatalytic activity   CO tolerant ability     
Fund:

国家质检总局科技计划项目(No2009IK097)和天津市科委重点基金项目(No07JCZDJC02400)

引用本文:   
赵黎华, 梁宝臣, 贾晓川, 张江萍, 曹丽静, 张寅豹, 李翔.燃料电池PtRu/C催化剂CO容限能力的表征[J].  化学工业与工程, 2011,28(2): 24-28
ZHAO Li-Hua, LIANG Bao-Chen, JIA Xiao-Chuan, ZHANG Jiang-Ping, CAO Li-Jing, ZHANG Yin-Bao, Li-Xiang.Evaluation of CO Tolerant Ability of PtRu/C Catalysts for Fuel Cells[J].  Chemcial Industry and Engineering, 2011,28(2): 24-28
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