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Chemcial Industry and Engineering 1987, Vol. 4 Issue (4) :14-21    DOI:
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A Review on the Active Phase of Hydrodesulfurization Catalysts
Li Yong-Dan Zhang Liu
(Chemical Engineering Department,Tian-Jin University

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Abstract In recent years, much insight has been got into the chemical Pro-perties of transition-metal sulfides, their structure and their hydro-desulfurization(HDS) behaviour, as well as the interrelationships between these characteristics. The suggested and proved Co-Mo-S structure model of commercial HDS catalysts reveals better under-standing of the active phase and the mechanism in the HDS process. The success in the study of the structure and its HDS activity of Chevrel Compounds has opened up a new way to catalyst optimiza-tion. This paper reviews the recent advances in HDS catalyst rese-arch. A great effort has been made to illustrate the relation between the development of theory and technology, The successful application of two novel techniques MES(Mossbauer emission spectroscopy) and EXAFS(Extended X-ray absorption fine structure) to the study of the HDS catalysts is also described.
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Received 1987-10-15; published 1987-10-15
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Li Yong-Dan Zhang Liu .A Review on the Active Phase of Hydrodesulfurization Catalysts[J]  Chemcial Industry and Engineering, 1987,V4(4): 14-21
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