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Chemcial Industry and Engineering 1992, Vol. 9 Issue (1) :12-19    DOI:
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Cracking Kinetics of Methyl Tert-Butyl Ether on Activated Carbon Catalyst
Gao Chong Luo Zhongyu Wang Shuqing
(Jilin Institute of Chemical Technology

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Abstract Under normal pressure and 265～295℃, the kinetics of cracking methyl tert-butyl ether (MTBE) into isobutene on activated Carbon catalyst was studied. Results show that the reaction is controlled by irreversible surface reaction which implies the adsorbed MTBE cracked into unadsorbed product. The kinetic equation is:(-r_A)=κP_A/(1+κ_AP_A)where κ=2.6167×10~9exp(-1.473×10~2/RT)κ_A=8.6829×10~6exp(-1.1661×10~2/RT)
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Keywords： kinetics cracking MTBE isobutene     
Received 1992-01-15; published 1992-01-15
Cite this article:   
Gao Chong Luo Zhongyu Wang Shuqing.Cracking Kinetics of Methyl Tert-Butyl Ether on Activated Carbon Catalyst[J]  Chemcial Industry and Engineering, 1992,V9(1): 12-19
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