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Chemcial Industry and Engineering 1993, Vol. 10 Issue (2) :1-8    DOI:
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The Study of Solid-Liquid Equilbrium for Nitrochlorobenzene system
Jin Kexin Chen Yongqiang Xie Chaogang
(Dept of Chem Eng,Tianjin Univ

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Abstract The binary and ternary solid-liquid equilibria (t-x) for nitrochlorobenzeneisomer systems had been determined by differential scanning calorimetry.Inaddition,using the equation of excess Gibbs energy G~E which was correlatedwith the topological index,the binary and ternary solid-liquid equilibria (t-x) for nitrochlorobenzene isomer systems were calculated.The G~E equation isG~E=RT where k_(ij) is an adjustabte parameter between two molecularity determinedby exeperiment.By this equation the maximum deviation between T_(cal) andT_(exp) is tess than 2K.
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Keywords： differential scanning calorimeter;;solid-liquid equilibrium;;topological index;;nitrochlorobenzene     
Received 1993-04-15; published 1993-04-15
Cite this article:   
Jin Kexin Chen Yongqiang Xie Chaogang .The Study of Solid-Liquid Equilbrium for Nitrochlorobenzene system[J]  Chemcial Industry and Engineering, 1993,V10(2): 1-8
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